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2-Methyl anthraquinone

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Name

2-Methyl anthraquinone

EINECS 201-539-6
CAS No. 84-54-8 Density 1.267 g/cm3
PSA 34.14000 LogP 2.77040
Solubility Soluble in water 1.234 mg/L @ 25°C. Melting Point 170-173 °C(lit.)
Formula C15H10O2 Boiling Point 407.8 °C at 760 mmHg
Molecular Weight 222.243 Flash Point 152.7 °C
Transport Information UN 3077 9/PG 3 Appearance Yellow to green-yellow fine powder
Safety 22-24/25-61 Risk Codes 51/53
Molecular Structure Molecular Structure of 84-54-8 (2-Methyl anthraquinone) Hazard Symbols HarmfulXn, IrritantXi
Synonyms

Anthraquinone,2-methyl- (6CI,8CI);2-Methylanthracene-9,10-dione;NSC607;Tectochinon;Tectoquinone;b-Methylanthraquinone;

Article Data 100

2-Methyl anthraquinone Synthetic route

85-44-9

phthalic anhydride

108-88-3

toluene

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
With bifunctional sulfonic acid-based HZSM-5 molecular sieve solid acid catalyst In ethyl acetate at 70℃; for 5h; Solvent; Temperature;92%
With H-beta zeolite at 249.84℃; for 5h; Autoclave;65.1%
With aluminium trichloride for 3h; Heating;29%
With aluminum (III) chloride Microwave irradiation;
3319-24-2, 55511-73-4

2-methyl-1,4,4a,9a-tetrahydroanthracene-9,10-dione

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
With potassium hydroxide In methanol at 45℃; Inert atmosphere; Schlenk technique;98%
With pyridine; thionyl chloride In benzene for 12h; Heating;52%
85-55-2

2-(4-toluoyl)benzoic acid

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
With sulfuric acid at 115℃; for 1h;85.31%
With sulfuric acid at 100℃; for 1h;75.2%
With sulfuric acid at 100℃; for 1h;75.2%
613-12-7

2-methylanthracene

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
With chromium(VI) oxide; 18-crown-6 ether In acetic acid at 50 - 55℃; for 0.5h;95%
With tert.-butylhydroperoxide; PhCl(PPh3)3 In benzene at 70℃; for 16h; Var. cat.: VO(acac)2;87%
With copper(II) nitrate In tetrachloromethane for 0.333333h; Heating;73%
948-67-4

2-methyl-9,10-dihydro anthracene

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
With dinitrogen monoxide; Ru(5,10,15,20-tetramesitylporphyrin)(O)2 In benzene at 200℃; under 7600 Torr;88%
With dinitrogen monoxide; dioxo(tetramesitylporphyrinato)ruthenium(VI) In benzene at 200℃; under 7600 Torr; for 20h;88%
42156-75-2

2-(p-toluoyl)benzoic acid chloride

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
With aluminum (III) chloride; trifluorormethanesulfonic acid In 1,2-dichloro-ethane at 55℃; for 2.5h;75.1%
107-86-8

3,3-dimethyl acrylaldehyde

130-15-4

[1,4]naphthoquinone

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
With benzoic acid; L-proline In toluene at 50℃; for 5h; Reagent/catalyst; Solvent; Time; Inert atmosphere; Enzymatic reaction;78%
With benzoic acid; L-proline In toluene at 50℃; for 5h; Catalytic behavior; Reagent/catalyst; Time; Solvent; Inert atmosphere;78%
83790-93-6

2-phenylethynyl-9,10-anthraquinone

107-15-3

ethylenediamine

A

936-49-2

2-phenyl-2-imidazoline

B

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
In pyridine for 5h; Reflux;A 93%
B 94%

1,4-dimethoxy-3-(2-methylallyl)-2-naphthaldehyde

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
Stage #1: 1,4-dimethoxy-3-(2-methylallyl)-2-naphthaldehyde With 1,1'-binaphthyl-2,2'-diyl hydrogenphosphate In chloroform at 20℃; Sealed tube;
Stage #2: In chloroform; water for 15h; Sealed tube; Irradiation;
97%
1696-17-9

N,N-diethylbenzamide

104-87-0

4-methyl-benzaldehyde

84-54-8

2-methylanthracene-9,10-dione

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium In diethyl ether 1.) -78 deg C, 1 h, 2.) -78 deg C -> RT, 12 h;15%

2-Methyl anthraquinone Chemical Properties

Molecular structure of 2-Methylanthraquinone (CAS NO.84-54-8) is:

Product Name: 2-Methylanthraquinone
CAS Registry Number: 84-54-8
IUPAC Name: 2-methylanthracene-9,10-dione
Molecular Weight: 222.2387 [g/mol]
Molecular Formula: C15H10O2
XLogP3: 3.9
H-Bond Donor: 0
H-Bond Acceptor: 2
Melting Point: 170-173 °C(lit.)
Molar Volume: 175.3 cm3
Surface Tension: 53 dyne/cm
Density: 1.267 g/cm3
Flash Point: 152.7 °C
Enthalpy of Vaporization: 65.97 kJ/mol
Boiling Point: 407.8 °C at 760 mmHg
Vapour Pressure: 7.36E-07 mmHg at 25°C
Product Categories: Intermediates of Dyes and Pigments;Anthraquinones, Hydroquinones and Quinones;Anthraquinones;Chloroanthraquine, etc.;C15 to C38;Carbonyl Compounds;Ketones

2-Methyl anthraquinone Safety Profile

Safty information about 2-Methylanthraquinone (CAS NO.84-54-8) is:
Hazard Codes: IrritantXi ;DangerousN
Risk Statements: 51/53 
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 22-24/25-61 
S22:Do not breathe dust. 
S24/25:Avoid contact with skin and eyes. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29146990 

2-Methyl anthraquinone Specification

 2-Methylanthraquinone , its cas register number is 84-54-8. It also can be called 2-Methyl-9,10-anthraquinone ; AI3-15182 ; CCRIS 5484 ; EINECS 201-539-6 ; NSC 607 ; Techtoquinone ; Tectochinon ; Tectoquinone ; beta-Methylanthraquinone ; 9,10-Anthracenedione, 2-methyl- ; Anthraquinone, 2-methyl- (8CI) .It is a yellow to green-yellow fine powder.

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