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3,3,3-Trifluoropropyltrimethoxysilane
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Name

3,3,3-Trifluoropropyltrimethoxysilane

 EINECS 207-059-3
CAS No. 429-60-7 Density 1.098 g/cm3
PSA 27.69000 LogP 1.81690
Solubility N/A Melting Point N/A
Formula C6H13F3O3Si Boiling Point 124.406 °C at 760 mmHg
Molecular Weight 218.248 Flash Point 29.04 °C
Transport Information UN 1993 3/PG 3 Appearance Colorless clear liquid
Safety 26-36 Risk Codes 10-36/37/38
Molecular Structure Molecular Structure of 429-60-7 ((3,3,3-TRIFLUOROPROPYL)TRIMETHOXYSILANE) Hazard Symbols IrritantXi, FlammableF
Synonyms

(3,3,3-Trifluoropropyl)trimethoxysilane;1,1,1-Trifluoro-3-(trimethoxysilyl)propane;AP Silane 75;AY 43-013;FAS 3;FAS3 (silane);KBM 7103;LS 1090;Q 3-9030;T 2847;TSL 8262;Trimethoxy(3,3,3-trifluoropropyl)silane;XC 95-418;Z 6333;

Article Data 4

3,3,3-Trifluoropropyltrimethoxysilane Synthetic route

67-56-1

methanol

592-09-6

3,3,3-trifluoropropyltrichlorosilane

429-60-7

3,3,3-trifluoropropyltrimethoxysilane

681-84-5

tetramethylorthosilicate

461-21-2

3,3,3-trifluoropropyl magnesium chloride

429-60-7

3,3,3-trifluoropropyltrimethoxysilane

2487-90-3

trimethoxysilane

116-15-4

perfluoropropylene

429-60-7

3,3,3-trifluoropropyltrimethoxysilane

Conditions
ConditionsYield
With caesium carbonate; triethylamine; [Rh{(Z)-CF=CF(CF3)}(PEt3)3] In hexane at 20℃; for 20h;
75-77-4

chloro-trimethyl-silane

429-60-7

3,3,3-trifluoropropyltrimethoxysilane

1,3,5,7,9,11,14-heptakis-(3,3,3-trifluoro-propyl)-3,7,14-tris-trimethylsilanyloxy-2,4,6,8,10,12,13,15,16-nonaoxa-1,3,5,7,9,11,14-heptasila-tricyclo[7.3.3.15,11]hexadecane

Conditions
ConditionsYield
Stage #1: 3,3,3-trifluoropropyltrimethoxysilane With sodium hydroxide In tetrahydrofuran; water for 5h; Heating;
Stage #2: chloro-trimethyl-silane With triethylamine In tetrahydrofuran at 20℃; for 3h;		100%
429-60-7

3,3,3-trifluoropropyltrimethoxysilane

hepta(3,3,3-trifluoropropyl)tricycloheptasiloxane trisodium silanolate

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran; water Inert atmosphere;100%
With sodium hydroxide; water In tetrahydrofuran for 5h; Heating / reflux;
With water; sodium hydroxide In tetrahydrofuran at 20℃; for 24h;
91-21-4

1,2,3,4-tetrahydroisoquinoline

3,3,3-Trifluoropropyl(1,2,3,4-tetrahydroisoquinolinyl)dimethoxysilane - A

3,3,3-Trifluoropropyl(1,2,3,4-tetrahydroisoquinolinyl)dimethoxysilane - A

429-60-7

3,3,3-trifluoropropyltrimethoxysilane

1068-55-9

isopropylmagnesium chloride

3,3,3-trifluoropropyl(1,2,3,4-tetrahydroisoquinolinyl)dimethoxysilane

Conditions
ConditionsYield
In tetrahydrofuran99%
635-46-1

1,2,3,4-tetrahydroisoquinoline

3,3,3-Trifluoropropyl(1,2,3,4-tetrahydroquinolinyl)dimethoxysilane - A

3,3,3-Trifluoropropyl(1,2,3,4-tetrahydroquinolinyl)dimethoxysilane - A

429-60-7

3,3,3-trifluoropropyltrimethoxysilane

1068-55-9

isopropylmagnesium chloride

3,3,3-trifluoropropyl(1,2,3,4-tetrahydroquinolinyl)dimethoxysilane

Conditions
ConditionsYield
In tetrahydrofuran99%
3,3,3-Trifluoropropyl(bis(2-ethylhexyl)aminodimethoxysilane - A

3,3,3-Trifluoropropyl(bis(2-ethylhexyl)aminodimethoxysilane - A

106-20-7

2-ethyl-N-(2-ethylhexyl)-1-hexanamine

429-60-7

3,3,3-trifluoropropyltrimethoxysilane

1068-55-9

isopropylmagnesium chloride

227768-97-0

(3,3,3-trifluoropropyl)(bis(2-ethylhexyl)amino)dimethoxysilane

Conditions
ConditionsYield
In tetrahydrofuran98%
3,3,3-Trifluoropropyl(2-trimethylsilylpyrrolidinyl)dimethoxysilane - A

3,3,3-Trifluoropropyl(2-trimethylsilylpyrrolidinyl)dimethoxysilane - A

429-60-7

3,3,3-trifluoropropyltrimethoxysilane

1068-55-9

isopropylmagnesium chloride

174363-70-3

2-(Trimethylsilyl)pyrrolidine

(3,3,3-trifluoropropyl)(2-trimethylsilylpyrrolidino)dimethoxysilane

Conditions
ConditionsYield
In tetrahydrofuran91%
3,3,3-Trifluoropropyl(2-trimethylsilylpiperidinyl)dimethoxysilane - A

3,3,3-Trifluoropropyl(2-trimethylsilylpiperidinyl)dimethoxysilane - A

429-60-7

3,3,3-trifluoropropyltrimethoxysilane

1068-55-9

isopropylmagnesium chloride

174363-71-4

2-(trimethylsilyl)piperidine

(3,3,3-trifluoropropyl)(2-trimethylsilylpiperidino)dimethoxysilane

Conditions
ConditionsYield
In tetrahydrofuran85%

3,3,3-Trifluoropropyltrimethoxysilane Specification

The 3,3,3-Trifluoropropyltrimethoxysilane, with the cas registry number of 429-60-7, is also known as Silane, trimethoxy(3,3,3-trifluoropropyl)- and 3-(Trimethoxysilyl)-1,1,1-trifluoropropane. It belongs to the product categories of Organics; Fluoro Silanes. Its EINECS number is 207-059-3. This chemical's molecular formula is C6H13F3O3Si and formula weight is 218.25. What's more, both its IUPAC name and systematic name are the same which is called Trimethoxy(3,3,3-trifluoropropyl)silane. This chemical is colorless clear liquid.

Physical properties about this chemical are: (1)ACD/LogP: 1.32; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.32; (4)ACD/LogD (pH 7.4): 1.32; (5)ACD/BCF (pH 5.5): 5.91; (6)ACD/BCF (pH 7.4): 5.91; (7)ACD/KOC (pH 5.5): 124.13; (8)ACD/KOC (pH 7.4): 124.13; (9)#H bond acceptors: 3; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 5; (12)Polar Surface Area: 27.69 Å2; (13)Index of Refraction: 1.363; (14)Molar Refractivity: 44.25 cm3; (15)Molar Volume: 198.7 cm3; (16)Surface Tension: 18.5 dyne/cm; (17)Density: 1.097 g/cm3; (18)Flash Point: 29 °C; (19)Enthalpy of Vaporization: 34.73 kJ/mol; (20)Boiling Point: 124.4 °C at 760 mmHg; (21)Vapour Pressure: 15.4 mmHg at 25°C; (22)Sensitive: Moisture Sensitive.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes and may catch fire in contact with air. It only needs brief contact with an ignition source and has a very low flash point or evolve highly flammable gases in contact with water. Secondly, it irritates to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact this chemical, please wear suitable protective clothing.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CO[Si](CCC(F)(F)F)(OC)OC;
(2)InChI: InChI=1S/C6H13F3O3Si/c1-10-13(11-2,12-3)5-4-6(7,8)9/h4-5H2,1-3H3;
(3)InChIKey: JLGNHOJUQFHYEZ-UHFFFAOYSA-N.

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