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4-(Chloromethyl)benzaldehyde

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Name

4-(Chloromethyl)benzaldehyde

EINECS N/A
CAS No. 73291-09-5 Density 1.200±0.06 g/cm3(Predicted)
PSA 17.07000 LogP 2.23790
Solubility N/A Melting Point 73 °C
Formula C8H7ClO Boiling Point 265.6±15.0 °C(Predicted)
Molecular Weight 154.596 Flash Point N/A
Transport Information N/A Appearance N/A
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 73291-09-5 (4-CHLOROMETHYLBENZALDEHYDE; >95%DISCONTINUED  10/25/01) Hazard Symbols N/A
Synonyms

p-Tolualdehyde,a-chloro- (6CI,7CI);4-Formylbenzyl chloride;NSC 617411;p-(Chloromethyl)benzaldehyde;

Article Data 28

4-(Chloromethyl)benzaldehyde Synthetic route

874-86-2

4-cyanobenzyl chloride

73291-09-5

4-chloromethylbenzaldehyde

Conditions
ConditionsYield
With diisobutylaluminium hydride In chlorobenzene96%
With hydrogenchloride; diethyl ether; tin(ll) chloride anschl. mit H2O;
With hydrogenchloride; tin(ll) chloride
16473-35-1

4-(hydroxymethyl)benzyl chloride

73291-09-5

4-chloromethylbenzaldehyde

Conditions
ConditionsYield
With pyridinium chlorochromate In dichloromethane at 20℃; for 2h;94%
With pyridinium chlorochromate In dichloromethane at 0℃;90%
With manganese(IV) oxide In dichloromethane at 20℃; for 24h;83%
1592-20-7

4-Vinylbenzyl chloride

73291-09-5

4-chloromethylbenzaldehyde

Conditions
ConditionsYield
With dihydrogen peroxide In water at 100℃; for 4h;92%
With [bis(acetoxy)iodo]benzene; [(2,2':6',2'-terpyridine)(Cl)RuII(9-oxidophenalenone)] In dichloromethane at 24.84℃; for 16h;
52889-83-5

1-(chloromethyl)-4-(methoxymethyl)benzene

73291-09-5

4-chloromethylbenzaldehyde

Conditions
ConditionsYield
With nitric acid In dichloromethane at 20℃; for 1h;91%
1592-20-7

4-Vinylbenzyl chloride

A

54589-56-9

4-chloromethylacetophenone

B

73291-09-5

4-chloromethylbenzaldehyde

Conditions
ConditionsYield
With water; copper(l) chloride In tetrahydrofuran at 20℃; for 48h; Reagent/catalyst; Wacker-Tsuji Olefin Oxidation;A 89%
B n/a
59138-96-4

1-bromomethyl-4-chloromethylbenzene

A

73291-09-5

4-chloromethylbenzaldehyde

B

623-27-8

terephthalaldehyde,

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; dimethyl selenoxide In 1,2-dichloro-ethane for 3h;A 77%
B 20%
52010-97-6

4-(hydroxylmethyl)benzaldehyde

73291-09-5

4-chloromethylbenzaldehyde

Conditions
ConditionsYield
With 1-pyrrolidinecarboxaldehyde; benzoyl chloride In 1,4-dioxane at 20 - 40℃; for 24.25h; Sealed tube;70%
With thionyl chloride; N,N-dimethyl-formamide In toluene at 0 - 20℃; for 16h;62%
With thionyl chloride In dichloromethane at 0 - 10℃; for 3h;45.5%
With 1-pyrrolidinecarboxaldehyde; benzoyl chloride In 1,4-dioxane at 20 - 40℃; for 24.25h;108.3 mg
142651-25-0

4-(1',3'-dioxolan-2'-yl)benzyl alcohol

73291-09-5

4-chloromethylbenzaldehyde

Conditions
ConditionsYield
With hydrogenchloride In water for 24h; Heating / reflux;68.4%
929972-98-5

(4-(chloromethyl)phenyl)(pyrrolidin-1-yl)methanone

73291-09-5

4-chloromethylbenzaldehyde

Conditions
ConditionsYield
Stage #1: (4-chloromethylphenyl)pyrrolidin-1-ylmethanone With chloromagnesium dimethylaminoborohydride In tetrahydrofuran at 25℃; for 0.5h; Inert atmosphere;
Stage #2: With acetaldehyde; acetic acid In tetrahydrofuran; pentane for 4h; Inert atmosphere;
60%
174311-81-0

4-<(triphenylmethoxy)methyl>benzyl chloride

73291-09-5

4-chloromethylbenzaldehyde

Conditions
ConditionsYield
With toluene-4-sulfonic acid In cyclohexane for 5h; Heating;43%

4-(Chloromethyl)benzaldehyde Chemical Properties

Molecule structure of 4-(Chloromethyl)benzaldehyde  (CAS NO.73291-09-5):

Molecular Weight: 154.59358 g/mol
Molecular Formula: C8H7ClO
Synonyms: α-Chloro-p-tolualdehyde  

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