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4-MORPHOLINENONYLIC ACID

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Name

4-MORPHOLINENONYLIC ACID

EINECS N/A
CAS No. 5299-64-9 Density 0.965g/cm3
PSA 29.54000 LogP 2.53370
Solubility N/A Melting Point N/A
Formula C13H25 N O2 Boiling Point 357.4°Cat760mmHg
Molecular Weight 227.39 Flash Point 169.9°C
Transport Information N/A Appearance N/A
Safety Poison by inhalation and intravenous routes. Human systemic effects by inhalation: lachrymation, deviated nasal septum, and cough. An eye and intense mucous membrane irritant. When heated to decomposition it emits toxic fumes of NOx. Risk Codes N/A
Molecular Structure Molecular Structure of 5299-64-9 (N-NONANOYLMORPHOLINE) Hazard Symbols N/A
Synonyms

Morpholine,4-(1-oxononyl)- (9CI); Morpholine, 4-nonanoyl- (7CI,8CI); 4-Nonanoylmorpholine;AI 318284; NSC 3150

Article Data 9

4-MORPHOLINENONYLIC ACID Chemical Properties

Product Name: 4-Morpholinenonylic (CAS NO.5299-64-9)


Molecular Formula: C13H25NO2
Molecular Weight: 227.34g/mol
Mol File: 5299-64-9.mol
Appearance: Liquid
Boiling point: 357.4 °C at 760 mmHg
Flash Point: 169.9 °C
Density: 0.965 g/cm3
Water Solubility: Insoluble
Surface Tension: 35.1 dyne/cm
Enthalpy of Vaporization: 60.27 kJ/mol
Vapour Pressure: 2.74E-05 mmHg at 25°C
XLogP3: 2.9
H-Bond Donor: 0
H-Bond Acceptor: 2

4-MORPHOLINENONYLIC ACID Uses

 4-Morpholinenonylic (CAS NO.5299-64-9) is a used as a solvent in lachrymatory formulations containing CR gas or CS gas. It is reported to be effective against dogs and starts being effective in concentrations of over 20-40 mg.min/m3. It is considered very safe, with high differences between effective and toxic concentrations. At one time it was reportedly used as food seasoning with no reported adverse effects. However, its effectiveness when used alone is rather low even in the highest permitted concentration, so it is almost always used in combination with CR gas or CS gas commonly referred to as tear gas. In that combination, this blend is effective even against dogs and people under influence of alcohol or drugs. Its effect usually lasts for 15-30 minutes.
MPK blends with CR gas or CS gas are common personal self-defense chemical agents in Russia and Ukraine, but is virtually unknown elsewhere.
4-Nonanoylmorpholine has been reported to have insect repellent properties in Aedes aegypti mosquitoes.

4-MORPHOLINENONYLIC ACID Toxicity Data With Reference

1.    

eye-rbt 500 µg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.
2.    

ihl-hmn TCLo:21 mg/m3/3M:PUL,EYE,NOSE

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),199.
3.    

ihl-rat LD50:23 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.
4.    

ihl-mus LD50:104 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.
5.    

ivn-mus LD50:18 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#08842 .
6.    

ivn-rbt LD50:21 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.
7.    

ihl-gpg LD50:6 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.

4-MORPHOLINENONYLIC ACID Safety Profile

Poison by inhalation and intravenous routes. Human systemic effects by inhalation: lachrymation, deviated nasal septum, and cough. An eye and intense mucous membrane irritant. When heated to decomposition it emits toxic fumes of NOx.

4-MORPHOLINENONYLIC ACID Specification

 4-Morpholinenonylic ,its CAS NO. is 5299-64-9,the synonyms is 1-(4-Morpholino)-1-nonanon ; 1-Nonanone, 1-(4-morpholino)- ; 4-(1-Oxononyl)-morpholin ; 4-(1-Oxononyl)morpholine ; 4-Nonanoyl-morpholin ; 4-Nonanoylmorpholine ; AI 318284 .

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