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Cas Database

Name	6-Deoxy-D-glucose	EINECS	231-622-2
CAS No.	7658-08-4	Density	1.41 g/cm³
PSA	90.15000	LogP	-2.19380
Solubility	H2O: 10 mg/mL, clear, colorless	Melting Point	146°
Formula	C6H12 O5	Boiling Point	399.1 °C at 760 mmHg
Molecular Weight	164.158	Flash Point	209.3 °C
Transport Information	N/A	Appearance	N/A
Safety	24/25	Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	6-Deoxy-D-glucose;6-Deoxyglucose; D-6-Deoxyglucose; D-Chinovose; D-Isorhamnose; D-Quinovose;Epirhamnose, D-; Glucomethylose; Isorhamnose; Isorhodeose; Quinovose	Article Data	148

6-Deoxy-D-glucose Synthetic route

: bayogenin {28-O-α-L-rhamnopyranosyl-(1->2)-[β-D-galactopyranosyl(1->3)]-[β-D-glucopyranosyl-(1->6)]-β-D-glucopyranosyl} ester

A: 7658-08-4
D-quionovose

B: 50-99-7
D-glucose

C: 59-23-4
D-Galactose

D: 465-00-9, 6989-24-8, 87392-68-5, 102519-34-6, 106293-97-4, 118711-55-0, 150821-16-2
bayogenin

Conditions

Conditions	Yield
Stage #1: bayogenin {28-O-α-L-rhamnopyranosyl-(1->2)-[β-D-galactopyranosyl(1->3)]-[β-D-glucopyranosyl-(1->6)]-β-D-glucopyranosyl} ester With sulfuric acid In 1,4-dioxane for 1h; Reflux; Stage #2: In 1,4-dioxane	A n/a B n/a C n/a D 71.7%

: desacylperennisoside X

A: 7658-08-4
D-quionovose

B: 50-99-7
D-glucose

C: 465-00-9, 6989-24-8, 87392-68-5, 102519-34-6, 106293-97-4, 118711-55-0, 150821-16-2
bayogenin

Conditions

Conditions	Yield
Stage #1: desacylperennisoside X With sulfuric acid In 1,4-dioxane for 1h; Reflux; Stage #2: In 1,4-dioxane	A n/a B n/a C 65.8%

: desacylperennisoside XI

A: 7658-08-4
D-quionovose

B: 50-99-7
D-glucose

C: 59-23-4
D-Galactose

D: 465-00-9, 6989-24-8, 87392-68-5, 102519-34-6, 106293-97-4, 118711-55-0, 150821-16-2
bayogenin

Conditions

Conditions	Yield
Stage #1: desacylperennisoside XI With sulfuric acid In 1,4-dioxane for 1h; Reflux; Stage #2: In 1,4-dioxane	A n/a B n/a C n/a D 61.4%

: desacyl-perennisoside VIII

A: 7658-08-4
D-quionovose

B: 3615-37-0
D-Fucose

C: 50-99-7
D-glucose

D: 465-00-9, 6989-24-8, 87392-68-5, 102519-34-6, 106293-97-4, 118711-55-0, 150821-16-2
bayogenin

Conditions

Conditions	Yield
Stage #1: desacyl-perennisoside VIII With sulfuric acid In 1,4-dioxane for 1h; Reflux; Stage #2: In 1,4-dioxane	A n/a B n/a C n/a D 52.2%

: desacylperennisoside IX

A: 7658-08-4
D-quionovose

B: 3615-37-0
D-Fucose

C: 50-99-7
D-glucose

D: 59-23-4
D-Galactose

E: 465-00-9, 6989-24-8, 87392-68-5, 102519-34-6, 106293-97-4, 118711-55-0, 150821-16-2
bayogenin

Conditions

Conditions	Yield
Stage #1: desacylperennisoside IX With sulfuric acid In 1,4-dioxane for 1h; Reflux; Stage #2: In 1,4-dioxane	A n/a B n/a C n/a D n/a E 50%

...Expand

: 20031-16-7, 24286-28-0, 24286-61-1, 29217-83-2, 35902-06-8, 106293-98-5
γ lactone of d-isorhamnonic acid

sodium amalgam: sodium amalgam

: 7658-08-4
D-quionovose

β-methyl-d-isorhamnoside: β-methyl-d-isorhamnoside

: 7658-08-4
D-quionovose

Conditions

Conditions	Yield
Hydrolysis;

methyl-<6-deoxy-α-D-glucopyranoside>: methyl-<6-deoxy-α-D-glucopyranoside>

: 7658-08-4
D-quionovose

Conditions

Conditions	Yield
With hydrogenchloride

O3,O5-benzylidene-O1,O2-isopropylidene-6-deoxy-α-D-glucofuranose: O3,O5-benzylidene-O1,O2-isopropylidene-6-deoxy-α-D-glucofuranose

: 7658-08-4
D-quionovose

Conditions

Conditions	Yield
With sulfuric acid

purginic acid: purginic acid

: 7658-08-4
D-quionovose

Conditions

Conditions	Yield
Hydrolysis;

6-Deoxy-D-glucose Chemical Properties

Structure of 6-Deoxy-D-glucose (CAS NO.7658-08-4):

Empirical Formula: C₆H₁₂O₅
Molecular Weight: 164.1565g/mol
IUPAC Name: (2R,3S,4R,5R)-2,3,4,5-tetrahydroxyhexanal
XLogP3-AA: -2.4
H-Bond Donor: 4
H-Bond Acceptor: 5
Rotatable Bond Count: 4
Tautomer Count: 10
Exact Mass: 164.068473
MonoIsotopic Mass: 164.068473
Topological Polar Surface Area: 98
Heavy Atom Count: 11
Formal Charge: 0
Complexity: 126
Index of Refraction: 1.53
Molar Refractivity: 36 cm³
Molar Volume: 116.4 cm³ Polarizability: 14.27×10^-24cm³
Surface Tension: 69.5 dyne/cm
Density: 1.41 g/cm³
Flash Point: 209.3 °C
Enthalpy of Vaporization: 75.11 kJ/mol
Boiling Point: 399.1 °C at 760 mmHg
Vapour Pressure: 5E-08 mmHg at 25°C
Canonical SMILES: CC(C(C(C(C=O)O)O)O)O
Isomeric SMILES: C[C@H]([C@H]([C@@H]([C@H](C=O)O)O)O)O
InChI: InChI=1S/C6H12O5/c1-3(8)5(10)6(11)4(9)2-7/h2-6,8-11H,1H3/t3-,4+,5-,6-/m1/s1
InChIKey: PNNNRSAQSRJVSB-JGWLITMVSA-N

6-Deoxy-D-glucose Safety Profile

WGK Germany of 6-Deoxy-D-glucose (CAS NO.7658-08-4): 3
F: 3-10

6-Deoxy-D-glucose Specification

6-Deoxy-D-glucose , its cas register number is 7658-08-4. It also can be called 6-Deoxyglucose ; Quinovose ; EINECS 231-622-2 . 6-Deoxy-D-glucose (CAS NO.7658-08-4) should be kept in a cool place.

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