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CAS No.: | 50-99-7 |
---|---|
Name: | D(+)-Glucose |
Article Data: | 1550 |
Molecular Structure: | |
Formula: | C6H12O6 |
Molecular Weight: | 180.158 |
Synonyms: | (+)-Glucose;Glucose;C*Dry GL 01934;CPC hydrate;Cartose;Cerelose;Cerelose2001;Clearsweet 95;Clintose L;Corn sugar;Dextropur;Dextrose;Dextrosol;Glucodin;Glucolin;D-Glucose;Glucosteril;Goldsugar;Grape sugar;Hi-Mesh;Maxim Energy Gel;Meritose;Meritose 200;Roclys C 30725;Roferose ST;Staleydex 111;Staleydex 130;Staleydex 333;Staleydex 95M;Sugar, grape;Tabfine 097(HS);Tackidex 30L75;Vadex;Dextrose Anhydrous Food Grade;Glucose anhydrouse; |
EINECS: | 200-075-1 |
Density: | 1.581 g/cm3 |
Melting Point: | 150-152 °C(lit.) |
Boiling Point: | 527.112 °C at 760 mmHg |
Flash Point: | 286.664 °C |
Solubility: | Soluble in water |
Appearance: | White crystalline powder |
Hazard Symbols: | Xn, Xi |
Risk Codes: | 36/37/38-63-62-46-36/38-21 |
Safety: | 26-36/37-24/25-53-25 |
PSA: | 118.22000 |
LogP: | -3.37880 |
D-glucose
Conditions | Yield |
---|---|
With lithium chloride In N,N-dimethyl-formamide at 120℃; for 8h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; | 99% |
With hydrogenchloride; water for 3h; Reactivity; Ionic liquid; | 94% |
Tonsil Supreme 110F, impregnated gallium sulphate In water at 20 - 110℃; for 0.35h; Product distribution / selectivity; | 75% |
1,2-O-benzylidene-α-D-glucofuranose
D-glucose
Conditions | Yield |
---|---|
With ammonium formate; palladium on activated charcoal In methanol for 0.666667h; Product distribution; Heating; at various types of sugars; | 97% |
Cellobiose
D-glucose
Conditions | Yield |
---|---|
With water at 120℃; for 1h; Autoclave; | 96% |
With sulfuric acid In water at 130℃; for 6h; pH=4; Kinetics; Catalytic behavior; pH-value; Temperature; Inert atmosphere; Sealed tube; | 91.1% |
With phosphotungstic acid hydrate; water at 160℃; for 0.5h; Reagent/catalyst; Temperature; | 37.6% |
Conditions | Yield |
---|---|
With sodium carbonate In water at 25℃; for 0.333333h; pH:8-11; | A n/a B 95% |
With glycosidase Inert atmosphere; Enzymatic reaction; |
Conditions | Yield |
---|---|
With water at 150℃; for 3h; Autoclave; | 95% |
Conditions | Yield |
---|---|
With hydrogenchloride; water for 4h; Reactivity; Ionic liquid; | A 6% B 93% |
With carbon based mesoporous Sibunit-4-ox In water for 5h; | A n/a B 45% |
With water; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride at 160℃; for 2.66667h; Product distribution / selectivity; | A 7% B 32% |
A
D-glucose
B
(2S,3R)-3,7-dimethyl-6-octene-1,2,3-triol
Conditions | Yield |
---|---|
With β-glucosidase In water at 37℃; for 96h; Enzymatic reaction; | A n/a B 93% |
Conditions | Yield |
---|---|
With cellulase from Aspergillus niger at 40℃; for 144h; pH=4.6; | A n/a B 92% |
Cellobiose
A
ethanol
B
D-glucose
Conditions | Yield |
---|---|
With β-glucosidase from Pseudomonas lutea BG8 In aq. buffer at 30℃; for 16h; pH=5; Enzymatic reaction; | A 91.42% B n/a |
Cellobiose
D-glucose
Conditions | Yield |
---|---|
With H3N*2H(1+)*TeW6O21(2-); water at 130℃; for 4h; Reagent/catalyst; Autoclave; | 90.5% |
With sodium acetate buffer; recombinant yeast exo-β-1,3-glucanase at 30℃; for 0.0833333h; pH=5.5; Kinetics; | |
With mesoporous Ta3W7 oxide In water at 99.84℃; for 3h; |
USP26, USP28 / BP2000, BP2003
Glucose, its cas register number is 50-99-7. It also can be called Anhydrous dextrose; Blood sugar; Cartose; Cerelose; D-(+)-Glucose. Glucose is a simple monosaccharide found in plants. Glucose exists in several different molecular structures, but all of these structures can be divided into two families of mirror-images.
Physical properties about Glucose are: (1)ACD/LogP: -3.29; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -3.29; (4)ACD/LogD (pH 7.4): -3.29; (5)ACD/BCF (pH 5.5): 1.00 ; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 1.00 ; (8)ACD/KOC (pH 7.4): 1.00; (9)#H bond acceptors: 6; (10)#H bond donors: 5; (11)#Freely Rotating Bonds: 10; (12)Index of Refraction: 1.573; (13)Molar Refractivity: 37.542 cm3; (14)Molar Volume: 113.931 cm3; (15)Polarizability: 14.883 10-24cm3; (16)Surface Tension: 92.0839996337891 dyne/cm; (17)Density: 1.581 g/cm3; (18)Flash Point: 286.664 °C; (19)Enthalpy of Vaporization: 92.224 kJ/mol; (20)Boiling Point: 527.112 °C at 760 mmHg
Preparation of Glucose: In plants and some prokaryotes, glucose is a product of photosynthesis. In animals and fungi, glucose results from the breakdown of glycogen, a process known as glycogenolysis. Glucose is produced commercially via the enzymatic hydrolysis of starch.
Uses of Glucose: Glucose is critical in the production of proteins and in lipid metabolism. In plants and most animals, it is also a precursor for vitamin C (ascorbic acid) production. It is modified for use in these processes by the glycolysis pathway. It is also used as a precursor for the synthesis of several important substances. In industry, Glucose is used as a precursor to make vitamin C in the Reichstein process, to make citric acid, gluconic acid, bio-ethanol, polylactic acid, sorbitol.
When you are using this chemical, please be cautious about it as the following:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
1. Wear suitable protective clothing and gloves;
2. Avoid contact with skin and eyes;
3. Avoid exposure - obtain special instruction before use;
4. Avoid contact with eyes;
You can still convert the following datas into molecular structure:
(1)InChI=1S/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h1,3-6,8-12H,2H2/t3-,4+,5+,6+/m0/s1;
(2)InChIKey=GZCGUPFRVQAUEE-SLPGGIOYSA-N;
(3)SmilesOC[C@H]([C@H]([C@@H]([C@H](C=O)O)O)O)O;
The toxiciy data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
dog | LDLo | oral | 8gm/kg (8000mg/kg) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 150, 1955. | |
mouse | LD50 | intraperitoneal | 18gm/kg (18000mg/kg) | Proceedings of the Society for Experimental Biology and Medicine. Vol. 35, Pg. 98, 1936. | |
mouse | LD50 | intravenous | 9gm/kg (9000mg/kg) | Arzneimittel-Forschung. Drug Research. Vol. 18, Pg. 666, 1968. | |
rabbit | LDLo | intravenous | 12gm/kg (12000mg/kg) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 150, 1955. | |
rabbit | LDLo | oral | 20gm/kg (20000mg/kg) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 150, 1955. | |
rat | LD50 | oral | 25800mg/kg (25800mg/kg) | GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" BEHAVIORAL: COMA LUNGS, THORAX, OR RESPIRATION: CYANOSIS | "Toxicity of Pure Foods," Boyd, E.M., Cleveland, OH, CRC Press, 1973Vol. -, Pg. 39, 1973. |