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9-Decenal

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Name

9-Decenal

EINECS 254-624-5
CAS No. 39770-05-3 Density 0.829 g/cm3
PSA 17.07000 LogP 3.10200
Solubility insoluble in water Melting Point -16°C (estimate)
Formula C10H18O Boiling Point 220.2 °C at 760 mmHg
Molecular Weight 154.252 Flash Point 83.5 °C
Transport Information N/A Appearance colorless to pale yellow liquid
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 39770-05-3 (9-Decenal) Hazard Symbols N/A
Synonyms

Costenal;

Article Data 31

9-Decenal Synthetic route

13019-22-2

9-Decen-1-ol

39770-05-3

9-decenal

Conditions
ConditionsYield
With oxalyl dichloride; dimethyl sulfoxide; triethylamine In dichloromethane at -60 - 20℃; for 0.333333h;100%
With Bu4N In 1,2-dichloro-ethane at 50℃; for 9h;99%
With aluminum oxide; pyridinium chlorochromate In dichloromethane at 20℃; for 3h;97%
85721-25-1

2-(oct-7-en-1-yl)oxirane

39770-05-3

9-decenal

Conditions
ConditionsYield
With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran; hexane at 20℃; for 12h;78%

1-[(trimethylsilyl)oxy]-1,10-undecadiene

A

39770-05-3

9-decenal

B

127087-61-0

9,10-epoxydecenal

C

10,11-epoxyundecanal

D

2-oxo-10-undecen-1-ol

Conditions
ConditionsYield
With tris(cetylpyridinium) 12-tungstophosphate; dihydrogen peroxide In dichloromethane at 20℃; for 16h; oxidative cleavage; Further byproducts given;A 52%
B n/a
C n/a
D n/a
112-38-9

10-undecenoic acid

39770-05-3

9-decenal

Conditions
ConditionsYield
(i) LDA, HMPT, THF, (ii) O2, (iii) Pb(OAc), AcOH; Multistep reaction;
Conditions
ConditionsYield
With lithium amide; ammonia In diethyl ether
112-38-9

10-undecenoic acid

A

34456-31-0

2D-Hydroxyundec-10-en-saeure

B

39770-05-3

9-decenal

Conditions
ConditionsYield
With phosphate buffer; α-oxidase of peas (Pisum sativum); oxygen; Triton X-100 at 4℃; for 22h; Yield given. Yields of byproduct given;
85721-25-1

2-(oct-7-en-1-yl)oxirane

A

39770-05-3

9-decenal

B

35194-30-0

9-decen-2-one

Conditions
ConditionsYield
With iron(III) tetraphenylporphyrin triflate In 1,4-dioxane Rearrangement; Heating;A 94 % Spectr.
B 6 % Spectr.
1502-06-3

cyclodecanone

39770-05-3

9-decenal

Conditions
ConditionsYield
Photolysis;
4117-07-1

deca-2c,9-dien-1-ol

39770-05-3

9-decenal

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: MnO2 / diethyl ether
2: LiNH2, liq. NH3 / diethyl ether
View Scheme
39770-05-3

9-decenal

1099-45-2

ethyl (triphenylphosphoranylidene)acetate

182280-18-8

(E)-ethyl dodeca-2,11-dienoate

Conditions
ConditionsYield
In benzene for 10h; Heating;95%
In dichloromethane at 20℃; for 12h;80%

9-Decenal Specification

The 9-Decenal has the CAS registry number 39770-05-3. Its EINECS registry number is 254-624-5. This chemical's molecular formula is C10H18O and molecular weight is 154.2493. Its systematic name is called dec-9-enal.

Physical properties of 9-Decenal: (1)ACD/LogP: 3.58; (2)ACD/LogD (pH 5.5): 3.58; (3)ACD/LogD (pH 7.4): 3.58; (4)ACD/BCF (pH 5.5): 311.94; (5)ACD/BCF (pH 7.4): 311.94; (6)ACD/KOC (pH 5.5): 2122.57; (7)ACD/KOC (pH 7.4): 2122.57; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 8; (10)Index of Refraction: 1.432; (11)Molar Refractivity: 48.28 cm3; (12)Molar Volume: 186 cm3; (13)Surface Tension: 27.9 dyne/cm; (14)Density: 0.829 g/cm3; (15)Flash Point: 83.5 °C; (16)Enthalpy of Vaporization: 45.66 kJ/mol; (17)Boiling Point: 220.2 °C at 760 mmHg; (18)Vapour Pressure: 0.115 mmHg at 25°C.

Preparation of 9-Decenal: this chemical can be prepared by dec-9-en-1-ol. This reaction is a kind of Swern oxidation. It will need reagents oxalyl chloride, DMSO and solvent CH2Cl2. The reaction time is 4 hours with reaction temperature of -78 °C.

9-Decenal can be prepared by dec-9-en-1-ol

Uses of 9-Decenal: it can be used to produce 2-non-8-enyl-[1,3]dioxolane with ethane-1,2-diol at temperature of 120 °C. This reaction will need catalyst p-toluenesulphonic acid and solvent benzene with reaction time of 8 hours. The yield is about 86%.

9-Decenal can be used to produce 2-non-8-enyl-[1,3]dioxolane with ethane-1,2-diol

You can still convert the following datas into molecular structure:
(1)SMILES: O=CCCCCCCC\C=C
(2)InChI: InChI=1/C10H18O/c1-2-3-4-5-6-7-8-9-10-11/h2,10H,1,3-9H2
(3)InChIKey: AKMSQWLDTSOVME-UHFFFAOYAZ

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