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AMIPROFOS-METHYL

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AMIPROFOS-METHYL

EINECS 252-829-4
CAS No. 36001-88-4 Density 1.275g/cm3
PSA 118.21000 LogP 4.71560
Solubility N/A Melting Point ~65 °C
Formula C11H17 N2 O4 P S Boiling Point 389.9°Cat760mmHg
Molecular Weight 304.307 Flash Point 189.6°C
Transport Information N/A Appearance N/A
Safety A poison by ingestion. Low toxicity by skin contact. When heated to decomposition it emits toxic vapors of NOx, SOx, and POx. Risk Codes 22
Molecular Structure Molecular Structure of 36001-88-4 (AMIPROFOS METHYL) Hazard Symbols HarmfulXn
Synonyms

Phosphoramidothioicacid, (1-methylethyl)-, O-methyl O-(4-methyl-2-nitrophenyl) ester (9CI);Amiprofos-methyl;Amiprophos-methyl;BAY-NTN 6867;BAY-NTN 80;NSC 313446;NTN6867;NTN 80;O-(2-Nitro-4-methylphenyl) O-methylN-isopropylphosphoramidothioate;O-Methyl O-4-methyl-2-nitrophenylN-isopropylphosphoramidothioate;Tokunol M;

Article Data 2

AMIPROFOS-METHYL Chemical Properties

Product Name: Amiprofos-methyl (CAS NO.36001-88-4)


Molecular Formula: C11H17N2O4PS
Molecular Weight: 304.3g/mol
Mol File: 36001-88-4.mol
Einecs: 252-829-4
Appearance: White or light yellow crystal
Melting Point: -65 °C
Boiling point: 389.9 °C at 760 mmHg
Flash Point: 189.6 °C
Density: 1.275 g/cm3
Surface Tension: 50.1 dyne/cm
Enthalpy of Vaporization: 63.93 kJ/mol
Vapour Pressure: 2.76E-06 mmHg at 25°C
XLogP3: 3.2
H-Bond Donor: 1
H-Bond Acceptor: 5

AMIPROFOS-METHYL Uses

Organophosphorus herbicides. Control in paddy field and dry land Amiprofos-methyl (CAS NO.36001-88-4) can be a variety of annual weeds such as barnyard grass, amaranth, quinoa, crickets, grass, look good wheat, cattle, blankets, Monochoria grass, grass and so steadily for rice, tomatoes, lettuce, cabbage, peanuts , sugar cane, onions, carrots, cucumbers and other crops. Spraying volume 1.25 ~ 5.0kg/hm2.

AMIPROFOS-METHYL Production

To 25.5g o-cresol and 27.5g O-methyl-thio-phosphorus dichloride completely dissolved, add 30mL acetone, in the 20 ~ 30 °C  under 7.2g sodium hydroxide was added dropwise dubbed in 25% of the lye. Canada will continue after completion of mixing 1h. Reaction solution changed from orange-red orange, add 120mL benzene, dropwise 28.3mL isopropylamine, dripping continue after completion of stirring 1h, separating the organic layer, washed to neutral with steamed to the solvent the product was light yellow 38.0g, yield 70%, mp63 ~ 64 °C.

AMIPROFOS-METHYL Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 540mg/kg (540mg/kg)   Shokubutsu Boeki. Vol. 32, Pg. 488, 1978.
mouse LD50 skin > 4gm/kg (4000mg/kg)   Shokubutsu Boeki. Vol. 32, Pg. 488, 1978.
rat LD50 oral 309mg/kg (309mg/kg)   "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 212, 1977.
rat LD50 skin > 5gm/kg (5000mg/kg)   Shokubutsu Boeki. Vol. 32, Pg. 488, 1978.

AMIPROFOS-METHYL Safety Profile

A poison by ingestion. Low toxicity by skin contact. When heated to decomposition it emits toxic vapors of NOx, SOx, and POx.
Safety Information of Amiprofos-methyl (CAS NO.36001-88-4):
Hazard Codes: Xn
Risk Statements: 22
22:  Harmful if swallowed 
Safety Statements: 36
36:  Irritating to the eyes

AMIPROFOS-METHYL Specification

 Amiprofos-methyl ,its CAS NO. is 36001-88-4,the synonyms is Amiprofos methyl ; o-Methyl o-(2-nitro-p-tolyl) n-isopropyl-phosphoramidothionate ; Amiprophosmethyl ; Bayntn6867 ; Bayntn80 ; n-Isopropyl-phosphoramidothioicacio-methylo-(2-nitro-p-tolyl)ester ; Ntn6867 ; Ntn80 .

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