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Cas Database |
| Name |
Ammonium perfluorooctanoate |
EINECS | 223-320-4 |
| CAS No. | 3825-26-1 | Density | 1.745g/cm3 |
| PSA | 40.54000 | LogP | 4.76900 |
| Solubility | N/A | Melting Point |
163-165(dec.) |
| Formula | C8H F15 O2 . H3 N | Boiling Point | 188°Cat760mmHg |
| Molecular Weight | 431.101 | Flash Point | 62.1°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Confirmed carcinogen. Poison by inhalation. Moderately toxic by ingestion. An eye and skin irritant. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of F− and NH3. | Risk Codes | R22;R36/38; |
| Molecular Structure |
|
Hazard Symbols | Toxic by inhalation and skin contact. TLV: 0.01 mg/m3. |
| Synonyms |
Octanoicacid, pentadecafluoro-, ammonium salt (8CI,9CI);Ammonium pentadecafluorooctanoate;Ammonium perfluorocaprylate;Ammonium perfluorooctanoate;DS 101;FC 1015;FC143;FX 1006;Fluorad FC 143;Perfluorooctanoic acid ammonium salt;Unidyne DS101; |
Article Data | 1 |
Ammonium perfluorooctanoate Synthetic route
- 3825-26-1
ammonium perfluorooctanoate
| Conditions | Yield |
|---|---|
| In diethyl ether complex (0.07 mmol) dissolved in ethanol/trifluorotoluene (1/1 (v/v)), C7F15COONH4 (0.5 mmol) added, stirred at room temp. for 4 h, evapd.; dissolved (n-perfluorooctane), washed (water), dried (MgSO4, vac.), elem. anal.; | 68% |
Ammonium perfluorooctanoate Chemical Properties
Molecular Formula: C8H4F15NO2
Molar mass: 431.1 g/mol
EINECS: 223-320-4
Flash Point: 62.1 °C
Boiling Point: 188 °C at 760 mmHg
Vapour Pressure: 0.274 mmHg at 25°C
Melting point: 163-165(dec.)
Solubility: H2O: 0.1 g/mL, clear, colorless
Product categories of Ammonium perfluorooctanoate (3825-26-1): Fluorochemical Surfactants;Organics;Functional Materials
Structure of Ammonium perfluorooctanoate (3825-26-1):
H-Bond Donor: 2
H-Bond Acceptor: 18
Systematic Name: Ammonia; 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid
SMILES: FC(F)(C(F)(F)C(=O)O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.N
InChI: InChI=1/C8HF15O2.H3N/c9-2(10,1(24)25)3(11,12)4(13,14)5(15,16)6(17,18)7(19,20)8(21,22)23;/h(H,24,25);1H3
InChIKey: YOALFLHFSFEMLP-UHFFFAOYAF
Std. InChI: InChI=1S/C8HF15O2.H3N/c9-2(10,1(24)25)3(11,12)4(13,14)5(15,16)6(17,18)7(19,20)8(21,22)23;/h(H,24,25);1H3
Std. InChIKey: YOALFLHFSFEMLP-UHFFFAOYSA-N
Ammonium perfluorooctanoate Toxicity Data With Reference
| 1. | skn-rbt 500 mg MOD | TXAPA9 Toxicology and Applied Pharmacology. 81 (1985),348. | ||
| 2. | eye-rbt 500 mg/24 H MOD | AIHAAP American Industrial Hygiene Association Journal. 41 (1980),576. | ||
| 3. | orl-rat LD50:430 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 41 (1980),576. | ||
| 4. | ihl-rat LC50:980 mg/m3/4 H | FCTOD7 Food and Chemical Toxicology. 24 (1986),1325. | ||
| 5. | skn-rat LD50:7 g/kg | TXAPA9 Toxicology and Applied Pharmacology. 81 (1985),348. | ||
| 6. | skn-rbt LD50:4300 mg/kg | TXAPA9 Toxicology and Applied Pharmacology. 81 (1985),348. |
Ammonium perfluorooctanoate Consensus Reports
Reported in EPA TSCA Inventory.
Ammonium perfluorooctanoate Safety Profile
Confirmed carcinogen. Poison by inhalation. Moderately toxic by ingestion. An eye and skin irritant. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of F− and NH3.
Hazard Codes: Xn.gif){kind=small}
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Risk Statements:
20: Harmful by inhalation
22: Harmful if swallowed
36: Irritating to the eyes
38: Irritating to the skin
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
Ammonium perfluorooctanoate Standards and Recommendations
ACGIH TLV: 0.01 mg/m3; Animal Carcinogen
Ammonium perfluorooctanoate Specification
Ammonium perfluorooctanoate (3825-26-1) also can be called Perfluoroammonium octanoate ; Fluorad FC 143 ; Ammonium pentadecafluorooctanoate and Ammonium perfluorocaprylate .
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