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Conditions | Yield |
---|---|
With sodium hydrogen sulfate; sulfuric acid at 200℃; for 19h; Reagent/catalyst; Temperature; | 99% |
With chlorosulfonic acid; 1,1,2,2-tetrachloroethane |
Conditions | Yield |
---|---|
With hydrogen at 120℃; under 30003 - 37503.8 Torr; for 0.75h; Reflux; | 97% |
With Raney nickel at 90 - 120℃; under 6000.6 - 9750.98 Torr; | 4200 kg |
Conditions | Yield |
---|---|
With chlorosulfonic acid In 1,2-dichloro-benzene at 135℃; for 1h; Product distribution; Kinetics; Mechanism; E(activ), oth. temperatures; | A 3.2% B 96.8% |
With sulfur trioxide In 1,2-dichloro-ethane at 5℃; Rate constant; Thermodynamic data; Product distribution; oth. temperature, E(activ.), var. ratios of reactants; | |
With sulfuric acid In 1,2-dichloro-benzene at 180℃; Kinetics; Thermodynamic data; Equilibrium constant; variation of molar ratio and temperature, Ea, ΔGo, ΔHo, ΔSo; | |
With sulfuric acid In 1,2-dichloro-benzene at 24.9℃; Thermodynamic data; Mechanism; Activation Free Energy, Enthalpy, Entropy of sulfonation and desulfonation; |
Conditions | Yield |
---|---|
With (2,2':6',2''-terpyridine)(pyridine-2-carboxylate)iron(II)chloride; sodium hydroxide In water; acetonitrile | 95% |
2-nitrothiophenol
A
bis(2-nitrophenyl)disulfide
B
2-amino-1-benzenesulfonic acid
Conditions | Yield |
---|---|
With water In 1,4-dioxane at 87℃; for 8h; | A 7% B 87% |
In 1,4-dioxane; water at 87℃; for 6.25h; | A 20.4% B 16.7% |
With water In 1,4-dioxane at 81 - 87℃; Rate constant; Mechanism; Product distribution; various water conc; different reaction times; |
Conditions | Yield |
---|---|
With chloramine-B; sodium hydroxide; palladium dichloride In water; acetonitrile at 80℃; pH=12; | 85% |
With [RuCl(P(C6H5)3)2(O(C6H4)NCH(C4H3N))]; sodium hydroxide In water; acetonitrile at 39.84℃; Kinetics; Concentration; Solvent; Temperature; |
3-amino-benzenesulfonic acid, monosodium salt
A
2-amino-1-benzenesulfonic acid
B
aniline
C
4-aminobenzene sulfonic acid
Conditions | Yield |
---|---|
With disodium hydrogenphosphate; sodium dihydrogenphosphate In methanol for 0.0166667h; Product distribution; Mechanism; Irradiation; effect of solvent and pH; | A 15.6% B 37.2% C 39.3% |
With perchloric acid; NaH2PO4-Na2HPO4 buffer; sodium chloride In water for 0.0166667h; Product distribution; Mechanism; Irradiation; | A 2.80 % Turnov. B 6.43 % Turnov. C 7.02 % Turnov. |
Conditions | Yield |
---|---|
With sulfuric acid; acetic acid |
Conditions | Yield |
---|---|
With phosphorus; hydrogen iodide at 110℃; im Druckrohr; | |
With sodium hydroxide; zinc |
4-bromo-3-sulfo-benzoic acid
2-amino-1-benzenesulfonic acid
Conditions | Yield |
---|---|
With ammonia at 180℃; im Rohr; |
The molecular structure of Aniline-2-sulfonic acid (CAS NO.88-21-1):
IUPAC Name: 2-Aminobenzenesulfonic acid
Molecular Weight: 173.18968 g/mol
Molecular Formula: C6H7NO3S
Density: 1.512 g/cm3
Melting Point: 300 °C
Index of Refraction: 1.629
Molar Refractivity: 40.71 cm3
Molar Volume: 114.4 cm3
Surface Tension: 67.5 dyne/cm
Water Solubility: sparingly soluble
XLogP3: 0.4
H-Bond Donor: 2
H-Bond Acceptor: 4
Rotatable Bond Count: 1
Exact Mass: 173.014664
MonoIsotopic Mass: 173.014664
Topological Polar Surface Area: 80.4
Heavy Atom Count: 11
Canonical SMILES: C1=CC=C(C(=C1)N)S(=O)(=O)O
InChI: InChI=1S/C6H7NO3S/c7-5-3-1-2-4-6(5)11(8,9)10/h1-4H,7H2,(H,8,9,10)
InChIKey: ZMCHBSMFKQYNKA-UHFFFAOYSA-N
EINECS: 201-810-9
Product Categories: Intermediates of Dyes and Pigments
Aniline-2-sulfonic acid (CAS NO.88-21-1) is used as dyes intermediates.
1. | mma-sat 6667 µg/plate | EMMUEG Environmental and Molecular Mutagenesis. 11 (Suppl 12)(1988),1. |
Reported in EPA TSCA Inventory.
Hazard Codes: C
Risk Statements: 34
R34:Causes burns.
Safety Statements: 26-36/37/39-45-28A
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S28:After contact with skin, wash immediately with plenty of soap-suds.
RIDADR: UN 2585 8/PG 3
WGK Germany: 3
RTECS: DB4727700
HazardClass: 8
PackingGroup: III
Aniline-2-sulfonic acid (CAS NO.88-21-1) is also named as 1-Aminobenzene-2-sulfonic acid ; 2-Aminobenzenesulfonic acid ; AI3-52212 ; Aniline-2-sulfonic acid ; Aniline-o-sulfonic acid ; Aniline-o-sulphonic acid ; Anilino-o-sulfonic acid ; Anilino-o-sulphonic acid ; CCRIS 4575 ; NSC 147 ; Orthanilic acid ; o-Aminobenzenesulfonic acid ; o-Aminophenylsulfonic acid ; o-Sulfanilic acid . Aniline-2-sulfonic acid (CAS NO.88-21-1) is light brown powder. It is soluble in water. Aniline-2-sulfonic acid is an amino acid. It reacts weakly with both acids and bases. Flash point data for Aniline-2-sulfonic acid are not available, however it is probably combustible.