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Azoxystrobin

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Name

Azoxystrobin

EINECS N/A
CAS No. 131860-33-8 Density 1.34 g/cm3
PSA 103.56000 LogP 4.09318
Solubility 6mg/L in water,Slightly soluble in n-hexane, n-octanol, soluble in methanol, toluene, acetone,ethyl acetate, acetonitrile, dichloromethane. Melting Point 118 - 119oC
Formula C22H17N3O5 Boiling Point 581.3 °C at 760 mmHg
Molecular Weight 403.394 Flash Point 305.3 °C
Transport Information UN 2811 Appearance white crystalline
Safety 22-45-60-61 Risk Codes 23-50/53
Molecular Structure Molecular Structure of 131860-33-8 (Azoxystrobin) Hazard Symbols ToxicT,DangerousN
Synonyms

Benzeneaceticacid, 2-[[6-(2-cyanophenoxy)-4-pyrimidinyl]oxy]-a-(methoxymethylene)-,methyl ester, (E)-;Amistar;

Article Data 50

Azoxystrobin Synthetic route

2-[2-[6-(2-cyanophenoxy)pyrimidin-4-yloxy]phenyl]-3,3-dimethoxypropionic acid methyl ester

131860-33-8

azoxystrobin

Conditions
ConditionsYield
With dimethyl sulfate at 110℃; under 375.038 Torr; for 1.75h;

Azoxystrobin Chemical Properties

IUPAC Name: Methyl (E)-2-[2-[6-(2-cyanophenoxy)pyrimidin-4-yl]oxyphenyl]-3-methoxyprop-2-enoate
Synonyms of Azoxystrobin (CAS NO.131860-33-8): Amistar ; Bankit ; Heritage ; Methyl (E)-2-(2-(6-(2-cyanopheoxy)pyrimidin-4-yloxy)phenyl)-3-methoxypropenoate ; Quadris ; Benzeneacetic acid, 2-((6-(2-cyanophenoxy)-4-pyrimidinyl)oxy)-alpha-(methoxymethylene)-, methyl ester, (E)- ; Benzeneacetic acid, 2-((6-(2-cyanophenoxy)-4-pyrimidinyl)oxy)-alpha-(methoxymethylene)-, methyl ester, (alphaE)-
CAS NO: 131860-33-8
Molecular Formula: C22H17N3O5
Molecular Weight: 403.39
Molecular Structure:
H bond acceptors: 8
H bond donors: 0
Freely Rotating Bonds: 8
Polar Surface Area: 103.56 Å2
Index of Refraction: 1.626
Molar Refractivity: 106.24 cm3
Molar Volume: 300.1 cm3
Surface Tension: 66.5 dyne/cm
Density: 1.34 g/cm3
Flash Point: 305.3 °C
Enthalpy of Vaporization: 86.93 kJ/mol
Boiling Point: 581.3 °C at 760 mmHg
Vapour Pressure: 1.67E-13 mmHg at 25°C
Storage temp: 0-6°C
SMILES: O=C(OC)\C(=C\OC)c3ccccc3Oc2ncnc(Oc1c(C#N)cccc1)c2
InChI: InChI=1/C22H17N3O5/c1-27-13-17(22(26)28-2)16-8-4-6-10-19(16)30-21-11-20(24-14-25-21)29-18-9-5-3-7-15(18)12-23/h3-11,13-14H,1-2H3/b17-13+
InChIKey: WFDXOXNFNRHQEC-GHRIWEEIBD
Std. InChI: InChI=1S/C22H17N3O5/c1-27-13-17(22(26)28-2)16-8-4-6-10-19(16)30-21-11-20(24-14-25-21)29-18-9-5-3-7-15(18)12-23/h3-11,13-14H,1-2H3/b17-13+
Std. InChIKey: WFDXOXNFNRHQEC-GHRIWEEISA-N
Product Categories of Azoxystrobin (CAS NO.131860-33-8): A-BPesticides;AntibioticsAlphabetic;A;Alpha sort;AR to AZ;Fungicides;Pesticides&Metabolites

Azoxystrobin History

 Azoxystrobin was discovered during research on Oudemansiella mucida and Strobilurus tenacellus, which are small white or brown coloured mushrooms which is not bigger than a few centimeters, and these mushrooms attracted attention of scientists because of their remarkable ability to defend themselves. Their defense mechanism is based on the secretion of two substances, strobilurin A and oudemansin A which allow them to keep their competitors at a distance and even destroy them when in range.

Azoxystrobin Uses

 Azoxystrobin (CAS NO.131860-33-8) is known as antifungal. It is presently the only counteragent that has the ability to protect against the 4 big groups of fungal diseases: Ascomycota: Septoria ;Deuteromycota: Pyricularia (rice harvesting) ;Basidiomycota: Stripe rust ;Oomycota: Water mould (grape harvesting).

Azoxystrobin Safety Profile

Hazard Codes: ToxicTDangerousN
Risk Statements: 23-50/53
R23: Toxic by inhalation.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 22-45-60-61
S22: Do not breathe dust. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60: This material and its container must be disposed of as hazardous waste. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 2811
Moderately toxic by inhalation. When heated to decomposition it emits toxic vapors of NOx.

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