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Barium chromate

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Name

Barium chromate

EINECS 233-660-5
CAS No. 10294-40-3 Density 4.5 g/mL at 25 °C(lit.)
PSA 80.26000 LogP -0.47520
Solubility Insoluble in water. Soluble in strong acids. Melting Point 210 °C (dec.)(lit.)
Formula BaCrO4 Boiling Point N/A
Molecular Weight 253.32 Flash Point N/A
Transport Information UN 1479 5.1/PG 2 Appearance yellow powder
Safety 53-36/37-45-60-61 Risk Codes 49-8-20/22-43-50/53
Molecular Structure Molecular Structure of 10294-40-3 (Barium chromate) Hazard Symbols OxidizingO, ToxicT, DangerousN
Synonyms

Bariumchromate(VI) (6CI);Barium chromate (1:1);Barium chromate(BaCrO4);Barium chromium oxide (BaCrO4);Baryta yellow;C.I. 77103;C.I.Pigment Yellow 31;Lemon Yellow;Lemon Yellow (inorganic pigment);Lemonchrome;Permanent yellow;Pigment Yellow 31;Ultramarine yellow;

 

Barium chromate Chemical Properties

Detail of BARIUM CHROMATE(VI)(10294-40-3).
Molecular Structure:

Name:BARIUM CHROMATE(VI)
CAS Number:10294-40-3
Molecular Formula:BaCrO4
Molecular Weight:255.36
Melting Point:210oC (dec.)
Appearance:yellow powder
Properties:Heavy, pale-yellow, crystalline powder; darkens on heating.  
density:4.5 g/mL at 25oC(lit.)
Merck:14,972
NIST Chemistry Reference:10294-40-3(NIST)
EPA Substance Registry System:10294-40-3(EPA Substance)
Synonyms of  BARIUM CHROMATE(VI)(10294-40-3):BARIUM CHROMATE;Barium chromate (1:1);Barium chromate oxide;bariumchromate(1:1);bariumchromate(vi);bariumchromateoxide;Bariumchromeyellow902;Baryta yellow

Barium chromate Uses

BARIUM CHROMATE(VI)(10294-40-3) can be used for the production of safety matches, pottery, glass, paint, etc.

Barium chromate Production

The production of  BARIUM CHROMATE(VI)(10294-40-3).
Barium chloride barium chromate can be formed with the precipitation reaction, the reaction equation is as follows:
BaCl2 + Na2CrO4 → BaCrO4 ↓ +2 NaCl
Operation method:Production of barium chromate is based on barium chloride [BaCl2.2H2O]: sodium dichromate [Na2Cr2O7 .2H2O]: sodium hydroxide [NaOH] = 244:149:40, raw materials and the water should be avoided include sulfate, so as to avoid forming insoluble barium sulfate mixed in the finished product in the lower levels of barium chromate. Sodium hydroxide before the reaction with sodium dichromate sodium chromate, sodium hydroxide should be exactly the amount of added sodium dichromate in and acidity, should prevent more alkaline. Sodium chromate can be diluted to the relative density of 1.11 solution, and test whether the existence of sulfate, if sulfuric acid pole can pre-join a small dose of barium chloride to precipitate barium sulfate is generated by clarification or filtration to remove. Barium chloride solution into the sodium chromate solution, constantly stirring, producing chromic acid barium precipitation, until the filtrate was precipitated with water colors, by adding barium chloride solution until the precipitation does not produce. Pigment paste obtained can be used filter press filtration, and washing to the washing water contains only a very small amount of chlorine in the root so far.
Production of barium potassium chromate is used by dry to powder, barium carbonate powder, mixing with potassium dichromate after the converter in the calcination, the reaction equation is as follows:
BaCO3 + K2Cr2O7 → BaCrO4 .K2CrO4 + CO2
Operation method: the ratio of potassium dichromate with the barium carbonate 1.2:1.72, pre-need milling crushed, then mixed, for brick kiln calcination to start calcination temperature 350 ℃, calcined phase up to 650 ~ 700 ℃, semi-finished products through the cooling after calcination.After crushing and  packaging ,it is made.

Barium chromate Toxicity Data With Reference

1.   

sce-ham:ovr 100 µg/L

   MUREAV    Mutation Research, 156 (1985),219.

Barium chromate Consensus Reports

IARC Cancer Review: Group 1 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man , 7 (1987),p. 165.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man , 2 (1973),p. 100.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man , 23 (1980),p. 205.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. Barium and its compounds are on the Community Right-To-Know List.

Barium chromate Safety Profile

Confirmed human carcinogen. A poison. Mutation data reported. Reacts vigorously with reducing materials. See also BARIUM COMPOUNDS (soluble) and CHROMIUM COMPOUNDS. Used in pyrotechnics and as an explosive initiator.
Analytical Methods:
For occupational chemical analysis use NIOSH: Chromium Hexavalent 7024.
Safety Information of BARIUM CHROMATE(VI)(10294-40-3).
Hazard Codes:O,T,N
Risk Statements:49-8-20/22-43-50/53
Safety Statements:53-36/37-45-60-61
RIDADR:UN 1479 5.1/PG 2
WGK Germany:3
RTECS:CQ8760000
HazardClass:5.1
PackingGroup:III
Hazardous Substances Data:10294-40-3(Hazardous Substances Data)

Barium chromate Standards and Recommendations

OSHA PEL: TWA 0.1 mg (C3O3)m3; 0.5 mg(Ba)/m3
ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen; 0.05 mg(Cr)/m3; Confirmed Human Carcinogen
DFG MAK: 0.5 mg(Ba)/m3
NIOSH REL: TWA 0.001 mg(Cr(VI))/m3

Barium chromate Analytical Methods

For occupational chemical analysis use NIOSH: Chromium Hexavalent 7024.
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