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Barium oxalate

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Name

Barium oxalate

EINECS 208-216-9
CAS No. 516-02-9 Density 2.66 g/mL at 25 °C(lit.)
PSA 52.60000 LogP -0.99860
Solubility soluble in water Melting Point 400 °C (dec.)(lit.)
Formula BaC2O4 Boiling Point 365.1 °C at 760 mmHg
Molecular Weight 225.35 Flash Point 188.8 °C
Transport Information UN 1564 6.1/PG 3 Appearance white powder
Safety 28 Risk Codes 20/22-320/22
Molecular Structure Molecular Structure of 516-02-9 (Barium oxalate) Hazard Symbols HarmfulXn
Synonyms

Bariumoxalate (6CI,7CI);Oxalic acid, barium salt (1:1) (8CI);Barium oxalate (1:1);Barium oxalate (BaC2O4);

Article Data 78

Barium oxalate Synthetic route

Hg(b),Ba(0.298) (W%)

Hg(b),Ba(0.298) (W%)

124-38-9

carbon dioxide

516-02-9

barium oxalate

Conditions
ConditionsYield
In neat (no solvent) treatment of Ba amalgam with CO2 at ambient temp., complete exclusion of O2 and atmospheric moisture;;52.04%
In neat (no solvent) treatment of Ba amalgam with CO2 at ambient temp., complete exclusion of O2 and atmospheric moisture;;52.04%
124-38-9

carbon dioxide

516-02-9

barium oxalate

Conditions
ConditionsYield
With Ba-amalgam52%
62-76-0

sodium oxalate

516-02-9

barium oxalate

Conditions
ConditionsYield
With BAS
BaC2O4+2 H2O

BaC2O4+2 H2O

BaC2O4+0.5 H2O

BaC2O4+0.5 H2O

516-02-9

barium oxalate

Conditions
ConditionsYield
at 140 - 150℃;
62-76-0

sodium oxalate

barium carbonate

A

3812-32-6

carbonate(2-)

B

516-02-9

barium oxalate

Conditions
ConditionsYield
In not given effect of 0.1 M-Na2C2O4-solution on BaCO3 at 16-18°C for 2 h forms an equilibrium under formation of BaC2O4 and CO3(2-); examination of the equilibrium dependent on time;;

barium(II) oxide

516-02-9

barium oxalate

Conditions
ConditionsYield
With oxalic acid In methanol pptn.;
With oxalic acid In methanol pptn.;
144-62-7

oxalic acid

barium(II) hydroxide

516-02-9

barium oxalate

Conditions
ConditionsYield
In not given mixing of Ba(OH)2-solution with dild. oxalic acid-solution forms BaC2O4; crystallisation after 5 min.; examination of the reaction;;
In water titration of Ba(OH)2-solution with oxalic acid in aq. solution pptn. BaC2O4; examination of the decrease of the electric conductivity of the reaction solution;;
In water Ba(OH)2:HOOCCOOH=0.98:1.125 (molar ratio);

barium oxalate hemihydrate

516-02-9

barium oxalate

Conditions
ConditionsYield
140-150°C;
140-150°C;
In neat (no solvent, solid phase) byproducts: H2O; dehydrated in a N2 stream in a tube furnace;

barium dioxalatodioxygenosmate * BaC2O4 * 6 H2O

144-62-7

oxalic acid

516-02-9

barium oxalate

Conditions
ConditionsYield
In water partly decompn.;;
In water partly decompn.;;

potassium tris(oxalato)chromate(III)

barium(II) hydroxide

A

chromium(III) oxide * x H2O

B

516-02-9

barium oxalate

Conditions
ConditionsYield
In water pptn.;;
In water pptn.;;

Barium oxalate Specification

The Ethanedioic acid,barium salt (1:1), with CAS registry number 516-02-9, has the systematic name of barium ethanedioate. This chemical is a kind of white powder. And this chemical should be stored in cool, dry place in tightly. And you should ensure good ventilation/exhaustion at the workplace. The main use of this chemical is for manufacturing of fireworks.

Physical properties of Ethanedioic acid,barium salt (1:1): (1)ACD/LogP: -1.19; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -5.7; (4)ACD/LogD (pH 7.4): -5.94; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 4; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 74.6 Å2; (13)Enthalpy of Vaporization: 67.15 kJ/mol; (14)Vapour Pressure: 2.51E-06 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
The Ethanedioic acid,barium salt (1:1) is harmful by inhalation and if swallowed. In case of insufficient ventilation, wear suitable respiratory equipment.

You can still convert the following datas into molecular structure:
(1)SMILES: [Ba+2].[O-]C(=O)C([O-])=O
(2)InChI: InChI=1/C2H2O4.Ba/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2
(3)InChIKey: GXUARMXARIJAFV-NUQVWONBAK
(4)Std. InChI: InChI=1S/C2H2O4.Ba/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2
(5)Std. InChIKey: GXUARMXARIJAFV-UHFFFAOYSA-L

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