Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Bathophenanthroline

Related Products

Hot Products

Name

Bathophenanthroline

EINECS 216-767-1
CAS No. 1662-01-7 Density 1.21 g/cm3
PSA 25.78000 LogP 6.11700
Solubility Soluble in benzene, chloroform and dilute inorganic acid, slightly soluble in ethanol and aether, insoluble in water Melting Point 218-220 °C(lit.)
Formula C24H16N2 Boiling Point 543.108 °C at 760 mmHg
Molecular Weight 332.404 Flash Point 242.111 °C
Transport Information N/A Appearance white to faintly yellow crystalline powder
Safety 22-24/25-36-26 Risk Codes 20/21/22-36/37/38
Molecular Structure Molecular Structure of 1662-01-7 (Bathophenanthroline) Hazard Symbols HarmfulXn
Synonyms

1,10-Bathophenanthroline;4,7-Diphenyl-1,10-diazaphenanthrene;4,7-Diphenyl-1,10-phenanthroline;4,7-Diphenyl-o-phenanthroline;BPhen;DPA;NSC 637659;

Article Data 8

Bathophenanthroline Synthetic route

936-59-4

3-chloropropiophenone

95-54-5

1,2-diamino-benzene

1662-01-7

bathophenanthroline

Conditions
ConditionsYield
With hydrogenchloride; hydrogen iodide In water at 100℃; for 0.333333h; Reagent/catalyst; Temperature;76.4%
55484-55-4

4-phenyl-8-aminoquinoline

936-59-4

3-chloropropiophenone

1662-01-7

bathophenanthroline

Conditions
ConditionsYield
With phosphoric acid; orthoarsenic acid
936-59-4

3-chloropropiophenone

1662-01-7

bathophenanthroline

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: arsenic acid; aqueous sulfuric acid
2: SnCl2+2 H2O; ethanol
3: syrupy H3PO4; H3aso4
View Scheme
25771-65-7

4-phenyl-8-nitroquinoline

1662-01-7

bathophenanthroline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: SnCl2+2 H2O; ethanol
2: syrupy H3PO4; H3aso4
View Scheme
88-74-4

2-nitro-aniline

1662-01-7

bathophenanthroline

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: arsenic acid; aqueous sulfuric acid
2: SnCl2+2 H2O; ethanol
3: syrupy H3PO4; H3aso4
View Scheme

[Co(4,7-diphenyl-1,10-phenanthroline)2(diflunisal)][hexafluorophosphate]

A

1662-01-7

bathophenanthroline

B

22494-42-4

2',4'-difluoro-4-hydroxybiphenyl-3-carboxylic acid

Conditions
ConditionsYield
In aq. phosphate buffer at 37℃; for 24h; Time;
bis-(dimethyl(phenyl)silylmethyl)(cycloocta-1,5-diene)platinum(II)

bis-(dimethyl(phenyl)silylmethyl)(cycloocta-1,5-diene)platinum(II)

1662-01-7

bathophenanthroline

bis-(dimethyl(phenyl)silylmethyl)(4,7-diphenyl-1,10-phenanthroline)platinum(II)

Conditions
ConditionsYield
In toluene Ar atmosphere; stirring (60°C, 28 d); removal of excess of ligand on washing with aq. FeSO4, concn., pptn. on addn. of hexane; elem. anal.;99%
14494-93-0, 23751-62-4, 106678-35-7

bis(triphenylphosphino)copper(I) nitrate

1662-01-7

bathophenanthroline

603-35-0

triphenylphosphine

1262033-35-1

(4,7-diphenyl-1,10-phenanthroline)bis(triphenylphosphine)copper(I) nitrate

Conditions
ConditionsYield
In chloroform at 20℃; for 1h; Schlenk technique;99%
1662-01-7

bathophenanthroline

2-methyl-4,7-diphenyl-1,10-phenanthroline

Conditions
ConditionsYield
With methyllithium In tetrahydrofuran at 0℃; for 0.25h; Inert atmosphere;99%

MoO2Br2(NCCH3)2

1662-01-7

bathophenanthroline

((C6H5)2C12H6N2)MoO2(Br)2

Conditions
ConditionsYield
In tetrahydrofuran N2; stirred for 1 h; cncd., pptd. (ether), ppt. washed (diethyl ether), dried (vac.); elem. anal.;98%

Bathophenanthroline Specification

The 1,10-Phenanthroline,4,7-diphenyl-, with the CAS registry number 1662-01-7, is also known as 1,10-Bathophenanthroline. It belongs to the product categories of Analytical Chemistry; Chelating Reagents; Electroluminescence; Functional Materials; Highly Purified Reagents; Other Categories; Phenanthrolines; Refined Products by Sublimation; White crystalline powder; Organic Amine. Its EINECS number is 216-767-1. This chemical's molecular formula is C24H16N2 and molecular weight is 332.40. What's more, its systematic name is 4,7-Diphenyl-1,10-phenanthroline. Its classification codes are: (1)Enzyme Inhibitors; (2)Indicators and reagents; (3)Mutation data; (4)Uncoupling agents. This chemical is used as a determination ferrous reagent. It is stable at common pressure and temperature, and it should be sealed and stored in a cool and dry place. Moreover, it should be protected from oxides.

Physical properties of 1,10-Phenanthroline,4,7-diphenyl- are: (1)ACD/LogP: 6.161; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 6.08; (4)ACD/LogD (pH 7.4): 6.16; (5)ACD/BCF (pH 5.5): 23389.81; (6)ACD/BCF (pH 7.4): 28283.67; (7)ACD/KOC (pH 5.5): 44172.85; (8)ACD/KOC (pH 7.4): 53415.15; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 25.78 Å2; (13)Index of Refraction: 1.71; (14)Molar Refractivity: 107.304 cm3; (15)Molar Volume: 274.682 cm3; (16)Polarizability: 42.539×10-24cm3; (17)Surface Tension: 55.57 dyne/cm; (18)Density: 1.21 g/cm3; (19)Flash Point: 242.111 °C; (20)Enthalpy of Vaporization: 79.064 kJ/mol; (21)Boiling Point: 543.108 °C at 760 mmHg; (22)Vapour Pressure: 0 mmHg at 25°C.

Preparation of 1,10-Phenanthroline,4,7-diphenyl-: this chemical can be prepared by 2-nitrochlorobenzene and beta-Chloropropiophenone by heating. This reaction will need reagents arsenic acid, sodium hydroxide and solvent dilute sulphuric acid.

1,10-Phenanthroline,4,7-diphenyl- can be prepared by 2-nitrochlorobenzene and beta-Chloropropiophenone by heating

Uses of 1,10-Phenanthroline,4,7-diphenyl-: it can be used to produce 2,9-bis-(4-methoxy-phenyl)-4,7-diphenyl-[1,10]phenanthroline. The yield is about 80%.

1,10-Phenanthroline,4,7-diphenyl- can be used to produce 2,9-bis-(4-methoxy-phenyl)-4,7-diphenyl-[1,10]phenanthroline

When you are using this chemical, please be cautious about it as the following:
This chemcial is irritating to eyes, respiratory system and skin. It is harmful by inhalation, in contact with skin and if swallowed. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. You should not breathe dust. When using it, you must avoid contact with eyes and wear suitable protective clothing.

You can still convert the following datas into molecular structure:
(1)SMILES: c1ccc(cc1)c2ccnc3c2ccc4c3nccc4c5ccccc5
(2)Std. InChI: InChI=1S/C24H16N2/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18/h1-16H
(3)Std. InChIKey: DHDHJYNTEFLIHY-UHFFFAOYSA-N 

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 1662-01-7