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2-Methyl-3-(benzylthio)-1-propene is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

101561-50-6

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101561-50-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 101561-50-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,1,5,6 and 1 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 101561-50:
(8*1)+(7*0)+(6*1)+(5*5)+(4*6)+(3*1)+(2*5)+(1*0)=76
76 % 10 = 6
So 101561-50-6 is a valid CAS Registry Number.

101561-50-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-methylprop-2-enylsulfanylmethylbenzene

1.2 Other means of identification

Product number -
Other names benzyl 2-methylprop-2-en-1-yl sulfide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:101561-50-6 SDS

101561-50-6Relevant articles and documents

Method of manufacturing compds. Allylnaphthol

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Paragraph 0030-0032; 0037, (2018/06/26)

PROBLEM TO BE SOLVED: To provide a production method of an allyl compound of carrying out the dehydration allylation of a substrate having S, C or N which is a nucleophilic atom, especially S under the presence of a catalyst system consisting of a catalyst precursor having a specific structure and a specific ligand. SOLUTION: The production method of allyl compounds comprises as follow. A catalyst precursor chosen from Formula (1) and Formula (2) and a ligand are mixed, or a catalyst precursor, an allyl alcohol, and a ligand are mixed, then allyl alcohols and a substrate are blended and made to react. The ligand is quinaldic acid or picolinic acid, and the substrate is thiols, thiocarboxylic acids or the like. [Ru(C5H5)(CH3CN)3]PF6(1). [Ru[C5(CH3)5](CH3CN)3]PF6(2). COPYRIGHT: (C)2012,JPOandINPIT

An efficient and odorless synthesis of thioethers using 2-[Bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as thiol equivalents

Yu, Haifeng

, p. 367 - 371 (2012/04/23)

Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides 1 as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 1 commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. It is noteworthy that only a very faint odor of thiols can be perceived during both the reaction and the workup. Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 2-[bis(alkylthio)methylene] -3-oxo-N-o-tolylbutanamides commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. Copyright

Highly efficient catalytic dehydrative S-allylation of thiols and thioic S-acids

Tanaka, Shinji,Pradhan, Prasun Kanti,Maegawa, Yusuke,Kitamura, Masato

supporting information; experimental part, p. 3996 - 3998 (2010/07/06)

A SH-selective allylation method using [CpRu(2-quinolinecarboxylato) (η3-C3H5)]PF6 has been realized in various solvents including aqueous media to give allyl sulfides and allyl S-thioates, demonstrating the potential applicability to lipopeptide chemistry.

Palladium-catalyzed insertion reactions of trimethylsilyldiazomethane

Greenman, Kevin L,Carter, David S,Van Vranken, David L

, p. 5219 - 5225 (2007/10/03)

Palladium(II) salts catalyze the Kirmse reaction of allylsulfides with trimethylsilyldiazomethane (TMSD) to give homoallylsulfides. Similarly, TMSD can intercept ArPdX intermediates generated during Stille couplings to give benzhydryl derivatives. The yie

REACTIONS OF PHOSPHORUS PENTACHLORIDE WITH ALLYL ARYL ETHERS, SULFIDES, AND NAPHTHALENE DERIVATIVES

Anisimova, E. A.,Mitrasov, Yu. N.,Kormachev, V. V.

, p. 356 - 360 (2007/10/03)

Conditions for phosphorylation of allyl aryl and aryl methylallyl ethers and sulfides, as well as alkenyl- and alkoxynaphthalenes, have been developed.

Synthesis of dithioetherdithiols, potential technetium complexing agents

Alagui, A.,Apparu, M.,Pasqualini, R.,Vidal, M.

, p. 286 - 295 (2007/10/02)

The following dithioetherdithiols : 2,10-dimethyl-4,8-dithiaundecane-2,10-dithiol 1, 5-butyl-3,7-dithianonane-1,9-dithiol 2 and 4,4,6,6-tetramethyl-3,7-dithianonane-1,9-dithiol 3 have been synthesized.These compounds are very attractive as potential precu

Stereoselective formation of allylic sulfides via two sequential [3,3]-sigmatropic rearrangements of allylic xanthates and its mechanistic aspects

Harano,Ohizumi,Misaka,Yamashiro,Hisano

, p. 619 - 624 (2007/10/02)

O-(2-Alkenyl) S-alkyl dithiocarbonates (allylic xanthates) were pyrolyzed to give 2-alkenyl alkyl sulfides (allylic sulfides) via the corresponding allylically isomeric S-(2-alkenyl) S-alkyl dithiocarbonates. The reaction follows the first-order rate law

A CONVENIENT AND STEREOSELECTIVE SYNTHESIS OF ALLYLIC SULFIDES

Harano, Kazunobu,Ohizumi, Norihide,Hisano, Takuzo

, p. 4203 - 4206 (2007/10/02)

The fractional distillation of O-(2-alkenyl or 2-cycloalkenyl) S-alkyl dithiocarbonates (xanthates) affords 2-alkenyl or 2-cycloalkenyl alkyl sulfides.The reaction involves the -sigmatropic rearrangement of the xanthates to produce S-(2-alkenyl or 2-cycloalkenyl) S-alkyl dithiocarbonates followed by extrusion of carbon oxysulfide to give 2-alkenyl or 2-cycloalkenyl alkyl sulfides.

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