104548-30-3

Basic information

• Product Name: OXONE TETRABUTYLAMMONIUM SALT
• Synonyms: OXONE tetrabutylammonium salt,Tetrabutylammonium OXONE, Tetrabutylammonium persulfate triple salt;OXONE tetrabutylammonium salt technical, ~1.6% active oxygen basis;Tetrabutylammonium hydrogen monopersulfate;Tetrabutylammonium peroxomonosulfate;OXONE(R) tetrabutylammonium salt technical, ~1.6% active oxygen basis;OXONE TETRABUTYLAMMONIUM SALT;TETRABUTYLAMMONIUM OXONE;TETRABUTYLAMMONIUM PERSULFATE TRIPLE SALT
• CAS NO: 104548-30-3
• Molecular Formula: C₁₆H₃₆N*HO₅S
• Molecular Weight: 856.22
• Mol File: 104548-30-3.mol

Chemical Properties

• Melting Point: 144-146 °C
• Appearance: /
• BRN: 5199887
• CAS DataBase Reference: OXONE TETRABUTYLAMMONIUM SALT(CAS DataBase Reference)
• NIST Chemistry Reference: OXONE TETRABUTYLAMMONIUM SALT(104548-30-3)
• EPA Substance Registry System: OXONE TETRABUTYLAMMONIUM SALT(104548-30-3)

Safety Data

• Hazard Codes: C
• Statements: 22-34-52
• Safety Statements: 26-36/37/39-45
• RIDADR: UN3263 8/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 104548-30-3(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
OXONE TETRABUTYLAMMONIUM SALT is used as a reagent for the oxidation of Hantzsch 1,4-Dihydropyridines catalyzed by manganese(III) Schiff Base complexes. This application is crucial in the synthesis of various organic compounds and pharmaceuticals.
Used in Pharmaceutical Industry:
OXONE TETRABUTYLAMMONIUM SALT is used as a reagent for the epoxidation of alkenes, which is an essential step in the synthesis of various pharmaceutical compounds, including antibiotics and other therapeutic agents.
Used in Petrochemical Industry:
OXONE TETRABUTYLAMMONIUM SALT is used as a reagent for the oxidation of sulfides and olefins, which are key processes in the production of various petrochemical products and intermediates.
Used in Fine Chemicals Industry:
OXONE TETRABUTYLAMMONIUM SALT is used as a reagent for the oxidation of alcohols, which is an important reaction in the synthesis of fine chemicals, fragrances, and flavor compounds.
Used in Dye and Pigment Industry:
OXONE TETRABUTYLAMMONIUM SALT is used as a reagent for the oxidation of aromatic amines, which is a critical step in the synthesis of azoxy arenes, a class of compounds used as intermediates in the production of dyes and pigments.

Upstream product

• 32503-27-8 tetra(n-butyl)ammonium hydrogensulfate 

Downstream Products

• 737802-41-4 (manganese(IV)tetraphenylporphyrin)(imidazole)(O) 
• 1370547-02-6 [Mn(meso-tetrakis(pentafluorophenyl)porphyrinato)(acetato)2]^(1-) 
• 100-52-7 benzaldehyde 
• 65-85-0 benzoic acid 

Relevant articles and documents

Catalytic epoxidation of cis-stilbene and naphthalene by tetra-n-butylammonium hydrogen monopersulfate in the presence of manganese(III) tetraarylporphyrins and various anionic co-catalysts

The epoxidation of cis-stilbene by n-Bu4NHSO5 was studied in the presence of two different manganese porphyrin complexes, [MnTPFPP(Cl) and MnTPP(Cl)], and various n-Bu4NX (X = OAc, F, Cl, Br, OCN, NO3, BF4). In general direct correlation was found between stereoselectivity of the epoxidation reaction and the nucleophilic properties of these anionic co-catalysts. Also epoxidation of naphthalene was carried out in high yield and good selectivity by n-Bu4NHSO 5 in the presence of MnTPFPP(Cl) in association with n-Bu 4NOAc or n-Bu4NF co-catalysts.

Effects of methoxy-substituted metalloporphyrins in catalytic alkene epoxidation by n-Bu 4NHSO 5

TPPMnOAc and four different kinds of manganese tetraphenylporphyrin acetates were synthesized using different numbers of methoxy substituents in various positions of the phenyl rings. These porphyrins were used as catalysts in the epoxidation of various alkenes with tetra-n-butylammonium hydrogen monopersulfate (n-Bu 4NHSO 5) as the oxidant and imidazole as the axial base. The following order of catalytic activity was obtained: TPPMnOAc ≥ T(2,3-OMeP) PMnOAc > T(4-OMeP) PMnOAc > T(3,4-OMeP) PMnOAc > T(2,4,6-OMeP) PMnOAc. By studying the UV-vis spectra in the reaction solution, the stability of the applied methoxy porphyrins and the effect of this factor on obtained yields were investigated. Lower catalytic activity in some of the methoxy porphyrins emphasized steric effects and special hydrogen bonding among the reaction elements. However, the stability of T(2,3-OMeP) PMnOAc under our reaction condition was considerable and high activity was observed. By adding small amounts of alcohol to the reaction solution, the effect of the solvent mixture was previewed and steps were taken to identify the active intermediate of the catalyst in these conditions. Copyright

Tetra-n-butylammonium Oxone. Oxidations under Anhydrous Conditions

Tetra-n-butylammonium Oxone, readily prepared as a white solid from commercially available Oxone, performs oxidations in anhydrous methylene chloride.Under these conditions, sulfides are oxidized to sulfones in the presence of amines, ketones, esters, car