116941-51-6Relevant articles and documents
Synthesis of asymmetric triarylbenzenes by using SOCl2-C 2H5OH reagent
Hu, Zhiguo,Liu, Jun,Li, Gongan,Dong, Zhibing,Li, Wei
, p. 581 - 583 (2004)
A simple and efficient method for synthesis of asymmetric branched functionalized triarylbenzenes is presented. The dypnone reacting with different substituted acetophenones, corresponding asymmetric 1,3,5-triarylbenzenes were obtained in the presence of catalytic amounts of sulfurous oxychloride in anhydrous ethanol.
DBU-Mediated Construction of 1,3,5-Trisubstituted Benzenes via Annulation of α,β-Unsaturated Carboxylic Acids and α-Cyano-β-methylenones
Zhang, Chun-Lin,Zhang, Zhao-Fei,Xia, Zi-Hao,Han, You-Feng,Ye, Song
, p. 12507 - 12513 (2018)
A DBU-mediated synthesis of 1,3,5-trisubstituted benzenes was developed via the [2 + 4] annulation of in situ activated α,β-unsaturated carboxylic acids and α-cyano-β-methylenones. The dual role of DBU as Br?nsted base and nucleophilic Lewis base is the key for the success of the reaction.
N-Heterocyclic Carbene-Catalyzed Construction of 1,3,5-Trisubstituted Benzenes from Bromoenals and α-Cyano-β-methylenones
Zhang, Chun-Lin,Ye, Song
, p. 6408 - 6411 (2016)
A direct and efficient approach to 1,3,5-trisubstituted benzenes has been developed via N-heterocyclic carbene-catalyzed [2 + 4] annulation of α-bromoenals and α-cyano-β-methylenones. The reaction worked well for both aryl- and alkylenones.
A halogen substituted of compounds of preparation method
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, (2018/07/06)
The invention discloses a type 1 shown compound preparation method, comprises the following steps: (1) condensation reaction: (2) Cyclization reaction: (3) The substitution reaction: (4) Coupling reaction: (5) Reduction reaction: (6) The diazotization reaction: Wherein X is selected from F, Cl, Br, I.
A halogen substituted of compounds of preparation method
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Paragraph 0055; 0079; 0081; 0082, (2018/07/15)
The invention discloses a type 1 shown of compounds of halogen substituted preparation method, comprises the following steps: (1) condensation reaction: (2) Cyclization reaction: (3) The substitution reaction: (4) Coupling reaction: (5) Reduction reaction: (6) The diazotization reaction: Wherein X is selected from F, Cl, Br, I.
A 1, 3, 5 - three-benzenes synthetic method of the compound
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Paragraph 0033; 0034; 0035, (2017/04/29)
The invention discloses a synthetic method for a 1,3,5-triarylbenzene compound. The method comprises the following steps: dissolving a chalcone derivative and inorganic alkali in dimethyl sulfoxide, carrying out reaction at 40 to 80 DEG C in the air for 3 to 8 hours, and carrying out separation and purification so as to obtain the 1,3,5-triarylbenzene compound, wherein a molar ratio of the chalcone derivative to the inorganic alkali is 1: 1-6; every mole of the chalcone derivative requires 4 to 8 mL of dimethyl sulfoxide; and the chalcone derivative has a general structural formula described in the specification, wherein Ar1 and Ar2 are aryl groups. The synthetic method for the 1,3,5-triarylbenzene compound provided by the invention has the following advantages of easily-available raw materials, simple operation, mild reaction conditions, no need of any transition metal catalyst, strong reaction specificity, strong applicability to a basic-group-contained substrate, no generation of waste products like halogen or boric acid, and simple, convenient and green after-treatment.
LIGHT EMITTING ELEMENT MATERIAL AND LIGHT EMITTING ELEMENT
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Paragraph 0158; 0161, (2020/06/02)
An organic thin film light emitting element which has achieved a good balance between high luminous efficiency and durability is provided by a light emitting element material that contains a compound having a specific carbazole skeleton.
New routes for synthesis of branched functionalized benzenoid compounds by using tetrachlorosilane-ethanol reagent
Elmorsy, Saad S.,Khalil, Abdel Galel. M.,Girges,Salama, Tarek A.
, p. 1071 - 1074 (2007/10/03)
The successive reactions of some cyclic ketones with aryl methyl ketones mediated by tetrachlorosilane-ethanol, provide an attractive and convenient route to branched functionalized benzenoid compounds. Selective unsymmetrical branched triarylbenzenes have synthesized by inducing the reaction of ketones with dypnones in quantitative yields.
Pyrylium Compounds. 38. About the Ring Transformation of 2,4,6-Triarylthiopyrylium Salts by Acetic Acid Anhydride to Arylbenzenes and Thiobenzophenones
Zimmermann, Thomas,Fischer, Gerhard W.
, p. 35 - 43 (2007/10/02)
2,4,6-Triarylthiopyrylium salts 5 react in the presence of an appropriate condensing agent (sodium acetate, carbonate, methoxide, tert-butoxide or potassium acetate) with acetic acid anhydride to yield arylbenzenes 3 and thiobenzophenones 6.This ring transformation represents the first example of the conversion of the =S(+)- moiety into the thiocarbonyl group >C=S.Under the same conditions 3,5-dimethyl-2,4,6-triphenylthiopyrylium perchlorate (13) forms via -sigmatropic rearrangement the thiobenzophenone 15.The structure of the new compounds 6 was proved by spectroscopic methods as well as by degradation reactions.Thus, hydrogen peroxide converts 6a to the known benzophenone 4.Alkaline saponification gives the 2-hydroxy-benzophenone 8, whereas heating with hydrochloric acid causes a selective cleavage of the acetoxy group to the 2-hydroxy-thiobenzophenone 7.
Pyrylium Compounds. 37. Arylbenzenes from 2,4,6-Triarylpyrylium Salts and Carboxylic Acid Anhydrides
Zimmermann, Thomas,Fischer, Gerhard W.
, p. 975 - 984 (2007/10/02)
Refluxing 2,4,6-triarylpyrylium salts 1 with excess carboxylic acid anhydrides (RCH2CO)2O (2a : R = H, 2b : R = Me) in the presence of condensing agents like sodium or potassium acetate, sodium carbonate or methoxide, triethylamine or pyridine results in 1,3,5-triarylbenzenes 3 (R = H, Me).Under similar conditions, phenylacetic acid anhydride (2c), generated in situ from sodium phenylacetate and excess 2a or 2b, yields 1,2,3,5-tetraarylbenzenes 3 (R = Ph).Thus, the reaction 1 + 2 --> 3 represents a new and simple method for replacing the pyrylium heteroatom =O(1)- by the =CR- moiety (R = H, Me, Ph).The structure of the arylbenzenes 3 was proved by spectroscopic methods, by comparison with literature data or by independent synthesis.As by-products 2-acyloxy-benzophenones 10 are formed.Reaction of 3,5-dimethyl-2,4,6-triphenylpyrylium perchlorate (11) with acetic acid anhydride/sodium acetate (or sodium phenylacetate) takes another course leading to 2-acetoxy-3,5-dimethyl-4,6-diphenyl-benzophenone (15), whereas treatment of 11 with propionic acid anhydride/sodium acetate follows the reaction scheme 1 + 2 --> 3 giving 1,3,5-trimethyl-2,4,6-triphenylbenzene (16).The mechanisms of the different pyrylium ring transformations are discussed.