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Alanine, N-[(4-chlorophenyl)methylene]-, ethyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 117470-83-4 Structure
  • Basic information

    1. Product Name: Alanine, N-[(4-chlorophenyl)methylene]-, ethyl ester
    2. Synonyms:
    3. CAS NO:117470-83-4
    4. Molecular Formula: C12H14ClNO2
    5. Molecular Weight: 239.702
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 117470-83-4.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Alanine, N-[(4-chlorophenyl)methylene]-, ethyl ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: Alanine, N-[(4-chlorophenyl)methylene]-, ethyl ester(117470-83-4)
    11. EPA Substance Registry System: Alanine, N-[(4-chlorophenyl)methylene]-, ethyl ester(117470-83-4)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 117470-83-4(Hazardous Substances Data)

117470-83-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 117470-83-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,7,4,7 and 0 respectively; the second part has 2 digits, 8 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 117470-83:
(8*1)+(7*1)+(6*7)+(5*4)+(4*7)+(3*0)+(2*8)+(1*3)=124
124 % 10 = 4
So 117470-83-4 is a valid CAS Registry Number.

117470-83-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name alanine ethyl ester-p-chlorobenzyl shiff base

1.2 Other means of identification

Product number -
Other names 2-{[1-(4-Chloro-phenyl)-meth-(E)-ylidene]-amino}-propionic acid ethyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:117470-83-4 SDS

117470-83-4Relevant articles and documents

Palladium-Catalyzed Highly Chemoselective Intramolecular C-H Aminocarbonylation of Phenethylamines to Six-Membered Benzolactams

Taneda, Hiroshi,Inamoto, Kiyofumi,Kondo, Yoshinori

, p. 2712 - 2715 (2016/06/15)

A palladium-catalyzed highly selective intramolecular C-H aminocarbonylation of Br-functionalized phenethylamines in the presence of CO was achieved while leaving the C-Br bond unreacted to afford six-membered benzolactams with good to high yields. The re

PROCESS FOR PRODUCING AMINO ACID AND DERIVATIVE THEREOF WITH OPTICALLY ACTIVE QUATERNARY AMMONIUM SALT HAVING AXIAL ASYMMETRY

-

Page/Page column 98-99, (2008/06/13)

A method of synthesizing an optically active amino acid and a derivative thereof in a two-phase system consisting of a water-immiscible medium and an alkaline aqueous solution using as a phase-transfer catalyst an optically active quaternary ammonium salt

SYNTHESIS OF α-METHYLHISTIDINE BY CATALYTIC PHASE-TRANSFER ALKYLATIONS

O'Donnell, Martin J.,Rusterholz, David B.

, p. 1157 - 1166 (2007/10/02)

α-Methylhistidine was prepared by two complementary routes using a catalytic phase-transfer alkylation procedure.Construction of the product was achieved either by alkylation of an alanine Schiff base ester with an imidazole-containing electrophile or by

Acidities of Glycine Schiff Bases and Alkylation of Their Conjugate Bases

O'Donnell, Martin J.,Bennett, William D.,Bruder, Willian A.,Jacobsen, William N.,Knuth, Keith,et al.

, p. 8520 - 8525 (2007/10/02)

Equilibrium acidities in Me2SO are reported for six ketimines of the type Ph2C=NCH(R)CO2Et and five aldimines, ArCH=NCH(R)CO2Et.Changing R in the ketimine from H to Ph increased the pKa by 2.2 units.This surprising acidity decrease for Ph substitution points to a substantial increase in steric effect, as do the increases in pKa of 3.8 and 4.2 units observed for the replacement of hydrogen by Me and PhCH2, respectively.Phase-transfer alkylation of the Ph2C=NCH2CO2Et ketimine gave over 90 percent of monoalkylate whereas, under similar conditions, the aldimine 4-ClC6H4CH=NCH2CO2Et gave a mixture of mono- and dialkylate.The difference is that the pKa of the monoalkylated aldimine is essentially the same as that of the parent, which leads to rapid equilibration with the parent anion and consequent dialkylation.The rates of alkylation in Me2SO of these parent and monoalkylated anions did not differ greatly, showing that the relative pKHAs of the parent acid and its monoalkyl derivative, rather tham the relative rates of the mono- and dialkylation reactions, is the principal factor that determines the extent of the competition between monoalkylation and dialkylation.

α-METHYL AMINO ACIDS BY CATALYTIC PHASE-TRANSFER ALKYLATIONS

O'Donnell, Martin J.,LeClef, Brigitte,Rusterholz, David B.,Ghosez, Leon,Antoine, Jean-Pierre,Navarro, Mirtha

, p. 4259 - 4262 (2007/10/02)

The α-methyl amino acids, α-methyl p-chlorophenylalanine, α-methyl p-tyrosine, α-methyl m-tyrosine and α-methyl DOPA have been prepared in good yields from amino ester hydrochlorides.The key step in the method is the catalytic phase-transfer alkylation of Schiff base derivatives of monoalkyl amino acids.

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