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Benzeneacetic acid, 2-bromo-5-methoxy-, methyl ester is a complex aromatic homomonocyclic compound with the molecular formula C10H11BrO3. It features a benzene ring with alternating double and single bonds, a bromo group, a methoxy group, and a methyl ester functional group. Benzeneacetic acid, 2-bromo-5-methoxy-, methyl ester is known for its reactivity in various chemical reactions, making it a versatile component in the field of chemical research.

117565-90-9

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117565-90-9 Usage

Uses

Used in Chemical Research:
Benzeneacetic acid, 2-bromo-5-methoxy-, methyl ester is used as a chemical intermediate for its ability to participate in a wide range of chemical reactions. Its presence of a benzene ring, bromo, and methoxy groups allows for further functionalization and synthesis of more complex molecules.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, Benzeneacetic acid, 2-bromo-5-methoxy-, methyl ester is used as a building block for the synthesis of various drug molecules. Its reactivity and structural features make it a valuable component in the development of new therapeutic agents.
Used in Material Science:
Benzeneacetic acid, 2-bromo-5-methoxy-, methyl ester is employed as a precursor in the synthesis of advanced materials, such as polymers and composites, due to its potential to form covalent bonds with other molecules. This contributes to the development of materials with improved properties, such as enhanced stability and functionality.
Used in Agrochemical Industry:
In the agrochemical industry, Benzeneacetic acid, 2-bromo-5-methoxy-, methyl ester is used as a starting material for the synthesis of various agrochemicals, including pesticides and herbicides. Its reactivity and structural features enable the creation of compounds with targeted effects on specific pests or weeds.

Check Digit Verification of cas no

The CAS Registry Mumber 117565-90-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,7,5,6 and 5 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 117565-90:
(8*1)+(7*1)+(6*7)+(5*5)+(4*6)+(3*5)+(2*9)+(1*0)=139
139 % 10 = 9
So 117565-90-9 is a valid CAS Registry Number.

117565-90-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl 2-(2-bromo-5-methoxyphenyl)acetate

1.2 Other means of identification

Product number -
Other names Methyl 2-bromo-5-methoxyphenylacetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:117565-90-9 SDS

117565-90-9Relevant articles and documents

N-SUBSTITUTED TETRAHYDROTHIENOPYRIDINE DERIVATIVES AND USES THEREOF

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Paragraph 00190; 00157, (2020/01/11)

A compound of Formula (I) is provided that has been shown to be useful for treating a disease caused by a viral infection: (I) wherein R1, R2, R3, A, L, m, n, p and q are as defined herein.

Chiral Magnesium Bisphosphate-Catalyzed Asymmetric Double C(sp3)-H Bond Functionalization Based on Sequential Hydride Shift/Cyclization Process

Mori, Keiji,Isogai, Ryo,Kamei, Yuto,Yamanaka, Masahiro,Akiyama, Takahiko

, p. 6203 - 6207 (2018/05/23)

Described herein is a chiral magnesium bisphosphate-catalyzed asymmetric double C(sp3)-H bond functionalization triggered by a sequential hydride shift/cyclization process. This reaction consists of stereoselective domino C(sp3)-H bond functionalization: (1) a highly enantio- and diastereoselective C(sp3)-H bond functionalization by chiral magnesium bisphosphate (first [1,5]-hydride shift), and (2) a highly diastereoselective C(sp3)-H bond functionalization by an achiral catalyst (Yb(OTf)3, second [1,5]-hydride shift).

Role of ortho -substituents on rhodium-catalyzed asymmetric synthesis of β-lactones by intramolecular C-H insertions of aryldiazoacetates

Fu, Liangbing,Wang, Hengbin,Davies, Huw M.L.

supporting information, p. 3036 - 3039 (2014/06/23)

A rhodium-catalyzed asymmetric synthesis of β-lactones via intramolecular C-H insertion into the ester group of aryldiazoacetates has been developed. The β-lactones were synthesized in high yields and with high levels of diastereo- and enantioselectivity.

Total synthesis of (-)-Haouamine B pentaacetate and structural revision of haouamine B

Momoi, Yuichi,Okuyama, Kei-Ichiro,Toya, Hiroki,Sugimoto, Kenji,Okano, Kentaro,Tokuyama, Hidetoshi

supporting information, p. 13215 - 13219 (2015/01/09)

The enantiocontrolled total synthesis of (-)-haouamine B pentaacetate was accomplished via an optically active indane-fused β-lactam, which was prepared by a newly developed Friedel-Crafts reaction. Subsequent cleavage of the β-lactam and an intramolecular McMurry coupling reaction provided the core indane-fused tetrahydropyridine, which led to the elucidation of the structure, as proposed by Trauner and Zuba.

Facile synthesis of 4,5,6a,7-tetrahydrodibenzo[de,g]chromene heterocycles and their transformation to phenanthrene alkaloids

Kapadia, Nirav,Harding, Wayne

supporting information, p. 8914 - 8920 (2013/09/23)

Oxa-Pictet-Spengler cyclization and microwave-assisted C-H arylation have been implemented as key steps in the synthesis of new isochroman heterocycles containing a 4,5,6a,7-tetrahydrodibenzo[de,g]chromene motif. These isochromans may be easily transformed to phenanthrene alkaloids via acidic cleavage of the isochroman ring and standard synthetic manipulations thereafter. The route described is attractive in that it provides access to two biologically interesting scaffolds in simple and high yielding synthetic steps.

Synthesis of a mitochondria-targeted spin trap using a novel Parham-type cyclization

Quin, Caroline,Trnka, Jan,Hay, Alison,Murphy, Michael P.,Hartley, Richard C.

experimental part, p. 8154 - 8160 (2009/12/26)

A new cyclic nitrone spin trap, [4-(3′,3′-dibutyl-2′-oxy-3′H-isoindol-5′-yloxy)butyl]triphenylphosphonium bromide (MitoSpin), bearing a lipophilic cation has been prepared by a route that involves a novel Parham-type lithiation-cyclization of an isocyanat

Total synthesis of haouamine A: the indeno-tetrahydropyridine core

Burns, Noah Z.,Jessing, Mikkel,Baran, Phil S.

experimental part, p. 6600 - 6610 (2011/02/25)

A full account of synthetic efforts toward the indeno-tetrahydropyridine core of haouamine A is presented. Initial failed strategies led to the unexpected discovery of a mild abnormal Chichibabin pyridine synthesis and provided knowledge and inspiration f

Total synthesis of (±)-haouamine A

Baran, Phil S.,Burns, Noah Z.

, p. 3908 - 3909 (2007/10/03)

The first total synthesis of the highly complex and potent anticancer agent haouamine A is reported through an eight-step sequence. Brevity of the sequence and complete control of chemo-, position-, and stereoselectivity (both planar and axial chirality) were possible through the invention of chemistry specifically tailored for the problems at hand, namely a cascade annulation proceeding via a hitherto unknown chemical entity for the indeno-tetrahydropyridine ring system as well as a pyrone-assisted stitching of the daunting bent-aromatic ring. Copyright

Regioselective aryl radical cyclisation. Part 2. Synthesis of octahydro-1H-dibenzo[a,d]cycloheptenes through 7-endo ring closure

Ghosh, Ajit K.,Mukhopadhyaya, Jayanta K.,Ghatak, Usha Ranjan

, p. 2747 - 2755 (2007/10/03)

A simple convergent synthesis of trans- and cis-octahydro-1H-dibenzo[a,d]cycloheptenes 15a-c and 16a-c and 20a-c and 21a-c through implementation of a regioselective 7-endo-trig-aryl radical cyclisation of the respective 2-(o-bromoarylethyl)-1-methylenecy

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