118468-30-7

Basic information

• Product Name: Benzene, 1-(chloromethyl)-4-(dodecyloxy)-
• Synonyms: .4-dodecyloxybenzyl chloride;.4-dodecanoxybenzyl chloride;.p-(dodecyloxy)benzyl chloride;(4)12G0-CH2Cl;.4-dodecyloxy(benzyl chloride);.p-(n-dodecan-1-yloxy)benzyl chloride
• CAS NO: 118468-30-7
• Molecular Formula: C19H31ClO
• Molecular Weight: 310.908
• Mol File: 118468-30-7.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(chloromethyl)-4-(dodecyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(chloromethyl)-4-(dodecyloxy)-(118468-30-7)
• EPA Substance Registry System: Benzene, 1-(chloromethyl)-4-(dodecyloxy)-(118468-30-7)

Safety Data

• Hazardous Substances Data: 118468-30-7(Hazardous Substances Data)

Upstream product

• 623-05-2 (4-hydroxyphenyl)methanol 
• 143-15-7 1-dodecylbromide 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 40654-49-7 methyl 4-(dodecyloxy)benzoate 
• 2312-15-4 p-dodecyloxybenzoic acid 
• 61440-63-9 p-(dodecyloxy)benzyl alcohol 

Downstream Products

• 134408-55-2 2-(4-Dodecyloxy-benzyloxy)-5-hexyloxy-cyclohepta-2,4,6-trienone 
• 134408-54-1 2-(4-Dodecyloxy-benzyloxy)-5-octyloxy-cyclohepta-2,4,6-trienone 
• 134408-53-0 2-(4-Dodecyloxy-benzyloxy)-5-undecyloxy-cyclohepta-2,4,6-trienone 
• 526221-02-3 3,4,5-tris(4'-dodecyloxybenzyloxy)-1-nitrobenzene 

Relevant articles and documents

Solvent-free thiophene-based electrolytes: synthesis of new liquid-crystalline ionic conductors for batteries: part I

New liquid crystalline thiophene esters, thiophene-3-yl 3,4,5-tris(n-dodecan-1-yloxy)benzoate (ThBz1) and thiophene-3-yl 3,4,5-tris[4-(n-dodecan-1-yloxy)benzyloxy]benzoate (ThBz2), were synthesized for use in lithium-ion batteries as safe, new solvent-fre

Rational Design of Supramolecular Dynamic Protein Assemblies by Using a Micelle-Assisted Activity-Based Protein-Labeling Technology

The self-assembly of proteins into higher-order superstructures is ubiquitous in biological systems. Genetic methods comprising both computational and rational design strategies are emerging as powerful methods for the design of synthetic protein complexes with high accuracy and fidelity. Although useful, most of the reported protein complexes lack a dynamic behavior, which may limit their potential applications. On the contrary, protein engineering by using chemical strategies offers excellent possibilities for the design of protein complexes with stimuli-responsive functions and adaptive behavior. However, designs based on chemical strategies are not accurate and therefore, yield polydisperse samples that are difficult to characterize. Here, we describe simple design principles for the construction of protein complexes through a supramolecular chemical strategy. A micelle-assisted activity-based protein-labeling technology has been developed to synthesize libraries of facially amphiphilic synthetic proteins, which self-assemble to form protein complexes through hydrophobic interaction. The proposed methodology is amenable for the synthesis of protein complex libraries with molecular weights and dimensions comparable to naturally occurring protein cages. The designed protein complexes display a rich structural diversity, oligomeric states, sizes, and surface charges that can be engineered through the macromolecular design. The broad utility of this method is demonstrated by the design of most sophisticated stimuli-responsive systems that can be programmed to assemble/disassemble in a reversible/irreversible fashion by using the pH or light as trigger.

Polycatenar Ligand Control of the Synthesis and Self-Assembly of Colloidal Nanocrystals

Hydrophobic colloidal nanocrystals are typically synthesized and manipulated with commercially available ligands, and surface functionalization is therefore typically limited to a small number of molecules. Here, we report the use of polycatenar ligands d

Effect of central linkages on mesophase behavior of imidazolium-based rod-like ionic liquid crystals

Two series of phenylbenzylether and benzanilide based rod-like imidazolium bromides and their nonionic precursors, the 1-phenyl-1H-imidazoles have been synthesized and the influence of the number and length of the alkyl chain(s) and the structure of the linking group in the aromatic core (-CH2O-, -COO-, -CONH-) on their mesophase self-assembly in ionic liquid crystalline phases were studied by POM, DSC and XRD. Upon decreasing the length of the N-terminal chain or by enlarging the number and length of the C-terminal chains, the sequence smectic (SmA)-hexagonal columnar (Colhex)-micellar cubic (CubI/Pm3n) was found for the ether based imidazolium salts; while only SmA and Colhex phases were observed for the related amides. The influence of the polarity of the central linkages, namely -CH 2O- and -CONH-, on the mesophase structure and stability is discussed and compared with related -COO- connected ILC.

Amphiphilic dendritic dipeptides and their self-assembly into helical pores

An amphiphilic dendritic dipeptide, comprises a dipeptide(s) comprising one or more of a naturally occurring or synthetic amino acids and a dendron. These are suitable for use in various formulations, films, coatings, membranes and sensors, among other ap

Self-assembly of semifluorinated Janus-dendritic benzamides into bilayered pyramidal columns

(Figure Presented) Two faces: Semifluorinated Janus-dendritic benzamides self-assemble into supramolecular bilayered pyramidal columns with diameters over twofold greater than those of columns generated from twin-dendritic benzamides (see model). The Janu

Helical porous protein mimics self-assembled from amphiphilic dendritic dipeptides

This manuscript reports the synthesis and the self-assembly of (4-3,4,5-3,5)nG2-CH2-Boc-L-Tyr-L-Ala-OMe dendritic dipeptides (n = 12, 16). These dendritic dipeptides self-assemble both in solution and in solid states into helical por

A new, lipophilic p-alkoxybenzyl ether protecting group and its use in the synthesis of a disaccharide.

[formula: see text] In contrast to major advances in the chemical synthesis of oligosaccharides, the methods of purification of the intermediates are essentially the same as they were decades ago. Here, the synthesis of p-(dodecyloxy)benzyl chloride is de

Smectic Bimetallomesogens: Synthesis and Mesomorphic Properties in Oxygen-Bridged Dicopper and Divanadyl Complexes

The synthesis and mesomorphic properties of a homologous series of N-(3-hydroxypropyl)-4-alkoxylsalicylaldimine, N-(3-hydroxypropyl)-4-(4′-alkoxybenzoxy)salicylaldimine, and their dicopper(II) and dioxovanadium(VI) complexes are reported. Copper complexes

Arylmethylphosphonates and phosphonic acids useful as anti-inflammatory agents

This invention provides a new use of acids, esters, and salts of arylmethylphosphonates of Formula I, STR1 or phosphonic acid derivatives of Formula II STR2 as anti-inflammatory and anti-arthritic agents. Representative compounds include 4-dodecyloxybenzylphosphonic acid dimethyl ester, (2-naphthalenylmethyl)phosphonic acid dimethyl ester, and ([1,1 '-biphenyl]-2-ylmethyl)phosphonic acid dimethyl ester. The invention also provides novel acids, esters, and salts of arylmethylphosphonic acid, phosphonic acid and derivatives.