120494-26-0Relevant articles and documents
Concerning the reaction of anti-benzene dioxide with various nucleophiles
Esser, Thomas,Farkas, Frederic,Mangholz, Sissi,Sequin, Urs
, p. 3709 - 3720 (2007/10/02)
trans-3,4:5,6-Diepoxycyclohex-1-ene (anti-benzene dioxide) (5) was brought into reaction with several S, O, and C nucleophiles. S and O nucleophiles gave the bis-adducts stemming from independent reaction of the two epoxy functions. C nucleophiles, on the
CONCERNING THE REACTIVITY OF 1,2:3,4-DIEPOXIDES TOWARDS NUCLEOPHILES
Esser, Thomas,Sequin, Urs
, p. 4405 - 4406 (2007/10/02)
anti-Benzenedioxide reacts with various nucleophiles to give the products resulting from the attack at both epoxy functions.With butyllithium, however, the formation of a product with a central epoxide is observed.This product is not the result of an epoxide migration but rather of the attack of the nucleophile at the double bond.