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CAS

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129101-19-5

(R,R,R)-2-AZABICYCLO[3.3.0]OCTANE-3-CARBOXYLIC ACID, BENZYL ESTER is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 129101-19-5 Structure

  • Basic information

    1. Product Name: (R,R,R)-2-AZABICYCLO[3.3.0]OCTANE-3-CARBOXYLIC ACID, BENZYL ESTER
    2. Synonyms: (2R,3aR,6aR)-Octahydro-cyclopenta[b]pyrrole-2-carboxylic Acid PhenylMethyl Ester;(R,R,R)-2-AZABICYCLO[3.3.0]OCTANE-3-CARBOXYLIC ACID, BENZYL ESTER
    3. CAS NO:129101-19-5
    4. Molecular Formula: C15H19NO2
    5. Molecular Weight: 245.32
    6. EINECS: N/A
    7. Product Categories: Aromatics Compounds;Aromatics;Chiral Reagents;Intermediates & Fine Chemicals;Pharmaceuticals
    8. Mol File: 129101-19-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 360.323°C at 760 mmHg
    3. Flash Point: 171.717°C
    4. Appearance: /
    5. Density: 1.129g/cm3
    6. Vapor Pressure: 0mmHg at 25°C
    7. Refractive Index: 1.549
    8. Storage Temp.: N/A
    9. Solubility: Chloroform, Ethyl Acetate
    10. CAS DataBase Reference: (R,R,R)-2-AZABICYCLO[3.3.0]OCTANE-3-CARBOXYLIC ACID, BENZYL ESTER(CAS DataBase Reference)
    11. NIST Chemistry Reference: (R,R,R)-2-AZABICYCLO[3.3.0]OCTANE-3-CARBOXYLIC ACID, BENZYL ESTER(129101-19-5)
    12. EPA Substance Registry System: (R,R,R)-2-AZABICYCLO[3.3.0]OCTANE-3-CARBOXYLIC ACID, BENZYL ESTER(129101-19-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 129101-19-5(Hazardous Substances Data)

129101-19-5 Usage

Chemical Properties

Thick Yellow Oil

Uses

In intermediate in the synthesis of Ramipril

Check Digit Verification of cas no

The CAS Registry Mumber 129101-19-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,9,1,0 and 1 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 129101-19:
(8*1)+(7*2)+(6*9)+(5*1)+(4*0)+(3*1)+(2*1)+(1*9)=95
95 % 10 = 5
So 129101-19-5 is a valid CAS Registry Number.
InChI:InChI=1/C15H19NO2/c17-15(18-10-11-5-2-1-3-6-11)14-9-12-7-4-8-13(12)16-14/h1-3,5-6,12-14,16H,4,7-10H2/t12-,13-,14-/m1/s1

129101-19-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (all-R)-2-Azabicyclo[3.3.0]octan-3-oic acid benzyl ester p-toluenesulfonate

1.2 Other means of identification

Product number -
Other names (R,R,R)-2-Azabicyclo[3.3.0]octane-3-carboxylic Acid Benzyl Ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:129101-19-5 SDS

129101-19-5Relevant articles and documents

PROCESS FOR THE PREPARATION OF RAMIPRIL

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Page/Page column 50, (2016/01/01)

An enantioselective process for the production of (2S,3aS,6aS)-cyclopenta[b]pyrrole-2-carboxylic acid and its conversion into Ramipril is provided.

Expeditious synthesis of ramipril: An angiotensin converting enzyme (ACE) inhibitor

Malakondaiah, Golla China,Gurav,Reddy, Lekkala Amarnath,Babu, Karrothu Srihari,Bhaskar, Bolugoddu Vijaya,Reddy, Padi Pratap,Bhattacharya, Apurba,Anand, Ramasamy Vijaya

, p. 1737 - 1744 (2008/09/21)

We document an efficient and cost-effective synthesis of ramipril 1 utilizing (i) an environmentally benign process for the esterification of racemic 2-aza-bicyclo-[3.3.0]-octane-3-carboxylic acid hydrochloride 2 using boric acid as a catalyst and (ii) a robust resolution process for the synthesis of 3a by means of inexpensive and recyclable L-(+)-mandelic acid as key steps. Copyright Taylor & Francis Group, LLC.

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