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3-Methyltetrahydrofuran, often abbreviated as 3-MeTHF, is an organic heterocyclic compound with the chemical formula C5H10O. It features a five-membered ring structure composed of four carbon atoms and one oxygen atom. 3-Methyltetrahydrofuran is recognized for its polarity, thermal stability, and its capacity to dissolve both inorganic and organic substances, making it a valuable solvent. Additionally, it is utilized as a component in lithium-ion battery electrolytes and can be synthesized from renewable resources, contributing to its environmentally favorable profile.

13423-15-9

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13423-15-9 Usage

Uses

Used in Solvent Applications:
3-Methyltetrahydrofuran is used as a solvent due to its polarity and ability to dissolve a wide range of substances, making it suitable for various industrial processes.
Used in Lithium-Ion Battery Electrolytes:
3-Methyltetrahydrofuran is used as a component in lithium-ion battery electrolytes, contributing to the performance and efficiency of these energy storage systems.
Used in Renewable Resource Synthesis:
3-Methyltetrahydrofuran is used in the synthesis of compounds from renewable resources, highlighting its potential for sustainable chemical production.

Check Digit Verification of cas no

The CAS Registry Mumber 13423-15-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,4,2 and 3 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 13423-15:
(7*1)+(6*3)+(5*4)+(4*2)+(3*3)+(2*1)+(1*5)=69
69 % 10 = 9
So 13423-15-9 is a valid CAS Registry Number.
InChI:InChI=1/C5H10O/c1-5-2-3-6-4-5/h5H,2-4H2,1H3/t5-/m1/s1

13423-15-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-METHYLTETRAHYDROFURAN

1.2 Other means of identification

Product number -
Other names 3-Methyloxolane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13423-15-9 SDS

13423-15-9Related news

Unraveling the high reactivity of 3-METHYLTETRAHYDROFURAN (cas 13423-15-9) over 2-methyltetrahydrofuran through kinetic modeling and experiments07/27/2019

The progress in catalysis research has recently led to new conversion pathways of cellulosic biomass to a range of tetrahydrofurans, which are potentially viable as biofuels. However, combustion behavior of these tetrahydrofurans is not well understood. Considering this as the main focus, the pr...detailed

13423-15-9Relevant articles and documents

The tris(trimethylsilyl)silane/thiol reducing system: A tool for measuring rate constants for reactions of carbon-centered radicals with thiols

Chatgilialoglu, Chryssostomos

, p. 2387 - 2398 (2006)

An extension of the well-known 'free-radical-clock' methodology is described that allows one to determine the rate constants of carbon-centered radicals with a variety of thiols by using the tris(trime-thylsilyl)silane/thiol couple as a reducing system. A

A sustainable process for the production of 2-methyl-1,4-butanediol by hydrogenation of biomass-derived itaconic acid

Liu, Xiaoran,Wang, Xicheng,Liu, Qiang,Xu, Guoqiang,Li, Xuemin,Mu, Xindong

, p. 88 - 93 (2016)

Pd-ReOx/C catalysts with different Re contents were prepared and employed to catalyze the aqueous hydrogenation of itaconic acid in this study. The Pd-ReOx/C catalysts were characterized by XRD, TEM, BET, NH3-TPD and H2-TPR. Results showed that the addition of ReOx species in supported Pd catalysts promoted the direct conversion of itaconic acid to 2-methyl-1,4-butanediol. The promoting effect was ascribed to the interaction between Pd and ReOx species, as has been proved by the characterizations. A 2-methyl-1,4-butanediol yield of above 80% could be obtained over Pd-3ReOx/C under the reaction condition of 180 °C, 4 MPa H2.

Chemoselective and Tandem Reduction of Arenes Using a Metal–Organic Framework-Supported Single-Site Cobalt Catalyst

Antil, Neha,Kumar, Ajay,Akhtar, Naved,Begum, Wahida,Chauhan, Manav,Newar, Rajashree,Rawat, Manhar Singh,Manna, Kuntal

supporting information, p. 1031 - 1040 (2022/01/19)

The development of heterogeneous, chemoselective, and tandem catalytic systems using abundant metals is vital for the sustainable synthesis of fine and commodity chemicals. We report a robust and recyclable single-site cobalt-hydride catalyst based on a porous aluminum metal–organic framework (DUT-5 MOF) for chemoselective hydrogenation of arenes. The DUT-5 node-supported cobalt(II) hydride (DUT-5-CoH) is a versatile solid catalyst for chemoselective hydrogenation of a range of nonpolar and polar arenes, including heteroarenes such as pyridines, quinolines, isoquinolines, indoles, and furans to afford cycloalkanes and saturated heterocycles in excellent yields. DUT-5-CoH exhibited excellent functional group tolerance and could be reusable at least five times without decreased activity. The same MOF-Co catalyst was also efficient for tandem hydrogenation–hydrodeoxygenation of aryl carbonyl compounds, including biomass-derived platform molecules such as furfural and hydroxymethylfurfural to cycloalkanes. In the case of hydrogenation of cumene, our spectroscopic, kinetic, and density functional theory (DFT) studies suggest the insertion of a trisubstituted alkene intermediate into the Co–H bond occurring in the turnover limiting step. Our work highlights the potential of MOF-supported single-site base–metal catalysts for sustainable and environment-friendly industrial production of chemicals and biofuels.

METHOD FOR REDUCTION OF ORGANIC MOLECULES

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Paragraph 0050; 0052; 0053; 0054; 0055, (2018/02/06)

A method for the reduction organic molecules comprising a Ruthenium-Triphosphine complex with aromatic ligands at the phosphors which are ortho or meta substituted.

Aqueous-phase hydrogenation of biomass-derived itaconic acid to methyl-γ-butyrolactone over Pd/C catalysts: Effect of pretreatments of active carbon

Li, Sha,Wang, Xicheng,Liu, Xiaoran,Xu, Guoqiang,Han, Sheng,Mu, Xindong

, p. 92 - 96 (2015/07/27)

The effect of active carbon pretreatment on the catalytic performance of Pd/C catalysts in the hydrogenation of itaconic acid was studied. The catalysts were prepared by deposition-precipitation and characterized by XRD, BET, NH3-TPD, TEM and F

Synthesis of 3-substituted tetrahydrofuran and 4-substituted tetrahydropyran derivatives by cyclization of dicarboxylic acids with InBr 3/TMDS

Pehlivan, Leyla,Metay, Estelle,Delbrayelle, Dominique,Mignani, Gerard,Lemaire, Marc

supporting information; scheme or table, p. 4689 - 4693 (2012/09/22)

An efficient reduction followed by cyclization of diacid compounds with the InBr3/TMDS system is reported. This system allows the formation of five- and six-membered ring ethers substituted in the 3- or 4-position. Copyright

Mechanism of the hydrogenolysis of ethers over silica-supported rhodium catalyst modified with rhenium oxide

Koso, Shuichi,Nakagawa, Yoshinao,Tomishige, Keiichi

scheme or table, p. 221 - 229 (2011/07/06)

The Rh-ReOx/SiO2 (Re/Rh = 0.5) exhibited high activity in the hydrogenolysis of ethers with an OH group. The CO bond neighboring CH2OH group was selectively dissociated: The hydrogenolysis of tetrahydro-5-methyl-2-furfuryl alcohol and 2-isopropoxyethannol gave 1,5-hexanediol and ethanol + isopropanol, respectively. This tendency suggests the regioselective CO dissociation mechanism via anion intermediate formed by the attack of hydride and the subsequent protonation of the anion.

Selective and flexible transformation of biomass-derived platform chemicals by a multifunctional catalytic system

Geilen, Frank M. A.,Engendahl, Barhel,Harwardt, Andreas,Marquardt, Wolfgang,Klankermayer, Juergen,Leitner, Walter

supporting information; experimental part, p. 5510 - 5514 (2010/09/16)

(Figure Presented) A sustainable supply chain: The controlled transformation of the biomassderived platform compounds levulinic acid (LA) and itaconic acid (IA) into the corresponding lactones, diols, or cyclic ethers (see picture) by using a multifunctional molecular catalyst is described.

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