14239-68-0

Basic information

• Product Name: Cadmium diethyldithiocarbamate
• Synonyms: ai3-26109;bis(diethylcarbamodithioato-S,S’)-,(T-4)-Cadimium;bis(diethyldithiocarbamate)cadmium;bis(diethyldithio-carbamate)cadmium;bis(diethyldithiocarbamato)-cadmiu;Bis(diethyldithiocarbamato)cadmium;Cadmate;Cadmium bis(N,N-diethyldithiocarbamate)
• CAS NO: 14239-68-0
• Molecular Formula: C₁₀H₂₀CdN₂S₄
• Molecular Weight: 408.95
• EINECS: 238-113-4
• Product Categories: Organometallics
• Mol File: 14239-68-0.mol

Chemical Properties

• Melting Point: 63-69°C (dec.)
• Boiling Point: 94.3°C
• Flash Point: 60.5 °C
• Appearance: /
• Density: 1,48 g/cm3
• CAS DataBase Reference: Cadmium diethyldithiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: Cadmium diethyldithiocarbamate(14239-68-0)
• EPA Substance Registry System: Cadmium diethyldithiocarbamate(14239-68-0)

Safety Data

• Statements: 20/21/22-51/53
• Safety Statements: 22-26-28-45
• RIDADR: 2570
• TSCA: Yes
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 14239-68-0(Hazardous Substances Data)

Usage

Uses

Cadmium Diethyldithiocarbamate can be used for a photocatalytic hydrogen production promoter.

Safety Profile

Confirmed human carcinogenwith experimental tumorigenic data. Mutation datareported. When heated to decomposition it emits verytoxic fumes of NOx and SOx.

InChI:InChI=1/2C5H11NS2.Cd/c2*1-3-6(4-2)5(7)8;/h2*3-4H2,1-2H3,(H,7,8);/q;;+2/p-2/rC10H20CdN2S4/c1-5-12(6-2)9(14)16-11-17-10(15)13(7-3)8-4/h5-8H2,1-4H3

Upstream product

• 75-15-0 carbon disulfide 
• 109-89-7 diethylamine 
• 7440-43-9 cadmium 
• 1518-58-7 diethylammonium diethyldithiocarbamate 
• 10108-64-2 cadmium(II) chloride 
• 97-77-8 disulfiram 
• 148-18-5 sodium N,N-diethyldithiocarbamate 
• 16110-84-2 Cd(ipxa)2 
• 125697-79-2 {Ph₃PCH₂Ph}{edtc} 
• 20624-25-3 sodium diethyldithiocarbamate trihydrate 

Downstream Products

• 14239-51-1 bis(N,N-diethyldithiocarbamato)mercury(II) 
• 16986-83-7 cadmium(II) propionate 
• 14267-17-5 nickel(II) diethyldithiocarbamate 
• 176434-82-5 tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S')cadmium(II) 
• 176434-81-4 tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S')cadmium(II) 

Relevant articles and documents

Preparation of CdS-doped glasses from gels containing diethyldithiocarbamatocadmium

CdS-doped SiO2 glasses were prepared via silica gels containing diethyldithiocarbamatocadmium Cd(S2CN(C2H5)2)2. Heat treatment of the gels gave transparent yellow SiO2 glasses do

The use of single-source precursors for the solution-liquid-solid growth of metal sulfide semiconductor nanowires

(Figure Presented) All wired up! High-quality colloidal PbS and CdS nanowires were grown from Bi nanoparticles by the solution-liquid-solid (SLS) mechanism. The single-source-precursor strategy could provide a general approach for the synthesis of colloidal semiconductor nanowires.

Mechanically activated solid-phase synthesis of copper(II), zinc(II), and cadmium(II) diethyldithiocarbamates

The mechanically activated solid-phase reaction of copper, zinc, and cadmium chlorides with sodium diethyldithiocarbamate is studied. The course of the process and the extent of reaction are studied as affected by the parameters of the mechanical activati

Kinetic analysis of the decomposition of chelates of di-alkyldithiocarbamate of Cd(II)

The thermal decomposition kinetics of the solid complexes Cd(S2CNR2)2, where R=C2H5, n-C3H7, n-C4H9 or iso-C4H9, was studied by using isothermal and non-isothermal thermogravimetry. The super-imposed TG/DTG/DSC curves revealed that thermal decomposition reactions occur in the liquid phase. The kinetic model that best fitted the experimental isothermal TG data was the one-dimensional phase-boundary reaction-controlled process R1. The thermal analysis data suggested the thermal stability sequence Cd(S2CNBu2n)2>Cd(S2CNPr2n)2 >Cd(S2CNBu2i)2>Cd(S2CNEt2)2, which accords with the sequence of stability of the apparent activation energies.

Kinetic study of the thermal decomposition on bis(dialkyldithiocarbamate) Cd(II) complexes by isothermal and non-isothermal thermogravimetry

The thermal decomposition kinetics of solid Cd(S2CNR2)2 complexes, where R=C2H5, n-C3H7, n-C4H9 and iso-C4H9, has been studied using i

THE DIRECT ELECTROCHEMICAL SYNTHESIS OF DIALKYLDITHIOCARBAMATE AND DIETHYLDITHIOPHOSPHATE COMPLEXES OF MAIN GROUP AND TRANSITION METALS

Dialkyldithiocarbamate derivatives (R2NCS2)nM of a number of metals (M=Fe, Co, Ni, Cu, Ag, Zn, Cd, In, Tl) have been synthesised in good yield by electrochemical oxidation of appropriate sacrificial anodes in non-aqueous solutions of either the corresponding tetraalkylthiuran disulphide (R2NCS2)2 (R=Me, Et) or a mixture of carbon disulphide plus the secondary amine R2NH (R=Et, i-Pr; R2NH=piperidine).Similar experiments with solutions of (EtO)2P(S)SH (=HL) gave MLn* derivatives (M=Fe, Co, Ni, Cu, Ag, Au, Zn, Cd, Hg, Ga, In, Tl) while in the presence of HL+1,10-phenanthroline, MLn.phen derivatives were obtained for M=V, Mn, Fe, Co, Zn, and Ga.