165035-05-2

Basic information

• Product Name: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate
• Synonyms: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate
• CAS NO: 165035-05-2
• Molecular Formula: C₁₂H₁₃NO₄
• Molecular Weight: 235.23592
• Mol File: 165035-05-2.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate(165035-05-2)
• EPA Substance Registry System: methyl (3,5-dioxo-4-azatricyclo[5.2.1.0~2,6~]dec-8-en-4-yl)acetate(165035-05-2)

Safety Data

• Hazardous Substances Data: 165035-05-2(Hazardous Substances Data)

Upstream product

• 70802-41-4 (Z)-N-(3-carboxy-1-oxo-2-propenyl)-glycine methyl ester 
• 542-92-7 cyclopenta-1,3-diene 
• 164025-07-4 (2,5-dioxo-2,5-dihydro-pyrrol-1-yl)acetic acid methyl ester 
• 67-56-1 methanol 
• 165035-09-6 2-(1,3-dioxo-1,3,3a,4,7,7a-hexahydro-2H-4,7-methanoisoindol-2-yl)acetic acid 
• 5680-79-5 glycine ethyl ester hydrochloride 
• 129-64-6 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride 

Relevant articles and documents

Synthesis of hybrid block copolymers via integrated ring-opening metathesis polymerization and polymerization of NCA

Linear hybrid block copolymers with well controlled molecular weights and narrow polydispersities were synthesized via ring-opening metathesis polymerization (ROMP) followed by ring-opening polymerization of amino acid N-carboxyanhydrides.

Features of reactions between (3,5-dioxo-4-azatricyclo-[5.2.1.0 2-endo,6-endo ]dec-8-en-4-yl)carboxylic acids and p-nitrophenyl azide

Reactions were performed of (3,5-dioxo-4-azatricyclo[5.2.1.0 2-endo,6-endo ]dec-8-en-4-yl)carboxylic acids and their derivatives with p-nitrophenyl azide. A significant fact of the involvement of the carboxy group into the formation of aziridine ring was established and the intermolecular character of this process was confirmed. The structure of compounds synthesized was proved by IR and 1H NMR spectra.

Synthesis and properties of chiral N,N-maleoyl derivatives and Diels-Alder reactions with cyclopentadiene

Maleyl amino acid derivatives were prepared from maleic anhydride and cyclized by reaction with ZnCl2 and hexamethyldisilazane yielding maleoyl derivatives. These derivatives were used as dienophiles in cycloadditions with cyclopentadiene. The

The synthesis of N-norbornenyl-amino acids and esters: Monomers for the preparation of well defined polymers

Two routes to the synthesis of various norbornene containing amino acid derivatives are described. The methodology also allows the preparation of the 7-oxonorbornene analogues, and a kinetics study of the racemisation of one of the monomers is reported.