17156-61-5Relevant articles and documents
Thermolyses of Hexakis(trimethylsilyl)benzene and Pentakis(trimethylsilyl)toluene. The First Unique Trimethylsilyl-Triggered Rupture of Benzene Rings
Sekiguchi, Akira,Ebata, Keisuke,Terui, Yoriko,Sakurai, Hideki
, p. 1417 - 1420 (1991)
Thermolysis of highly distorted hexakis(trimethylsilyl)benzene and pentakis(trimethylsilyl)toluene resulted in the formation of products arising from the ruptures of the aromatic rings.
Synthesis and structure of the silylated benzene radical anion salts [K([18]crown-6){C6H4(SiMe3)2-1,4}] and [K([18]crown-6)(THF)2][C6H2(SiMe 3)4-1,2,4,5]
Hitchcock, Peter B.,Lappert, Michael F.,Protchenko, Andrey V.
, p. 2161 - 2164 (2011)
The crystalline compound [K([18]crown-6){C6H 4(SiMe3)2-1,4}] (1) was prepared by the low-temperature reduction of the para-disilylated benzene with K/[18]crown-6 in toluene followed by recrystallisation from the
5,6-Bis(trimethylsilyl)benzo[c]furan: A versatile building block for linear polycyclic aromatic compounds
Yick, Chung-Yan,Chan, Siu-Hin,Wong, Henry N. C.
, p. 5957 - 5961 (2000)
Benzo[c]furans are a class of interesting compounds. Being very reactive, they readily undergo Diels-Alder cycloaddition with dienophiles to restore their aromaticity. For this reason, they can be utilized to construct six-membered ring compounds which are common building blocks of many natural and non-natural molecules. In connection with our use of silylated furans in the preparation of polysubstituted furans, we sought to extend our work to include silylated benzo[c]furans as well. Herein, we report the synthesis of the title molecule and its further manipulation for the preparation of several silylated linear polynuclear aromatic compounds. (C) 2000 Elsevier Science Ltd.
Interactions in crystals. LXXIII. The structures of 1,2,4,5-tetrakis( trimethylsilyl) benzene and of its solvent-separated radical anion salt(H3COCH2CH2OCH3)3> >
Bock, Hans,Ansari, Manssur,Nagel, Norbert,Havlas, Zdenek
, p. 63 - 72 (1995)
Reduction of 1,2,4,5-tetrakis(trimethylsilyl)benzene at a sodium-metal mirror under aprotic conditions and an argon atmosphere yields red needles of its solvent-separated radical anion salt.The structure, determined in a 150 K cold N2 flow, is discussed i
1,2-bis (methylsilyl triarylboron) or its method of manufacturing cd87 compd. hydroxybenzenesulfonic
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Paragraph 0038; 0042, (2018/10/10)
PROBLEM TO BE SOLVED: To provide a new method for producing 1,2-bis(trimethylsilyl)benzene or its analogous compound at a low cost in high yield under a mild reaction condition by using a safe solvent.SOLUTION: There is provided a method for producing 1,2
Synthesis of 1,2-bis(trimethylsilyl)benzene derivatives from 1,2-dichlorobenzenes using a hybrid metal Mg/CuCl in the presence of LiCl in 1,3-dimethyl-2-imidazolidinone
Kitamura, Tsugio,Gondo, Keisuke,Katagiri, Toshimasa
, p. 3421 - 3424 (2013/06/26)
A practical and safe synthesis of 1,2-bis(trimethylsilyl)benzene from 1,2-dichlorobenzene and Me3SiCl was achieved by use of a hybrid metal of Mg and CuCl in the presence of LiCl in 1,3-dimethyl-2-imidazolidinone (DMI). This method does not req
5,6-Bis(trimethylsilyl)benzo[c]furan: An isolable versatile building block for linear polycyclic aromatic compounds
Chan, Siu-Hin,Yick, Chung-Yan,Wong, Henry N.C
, p. 9413 - 9422 (2007/10/03)
Benzo[c]furans are a class of interesting and highly reactive compounds that readily undergo Diels-Alder cycloaddition with dienophiles to restore their aromaticity. Initially, the s-tetrazine approach established by Warrener was chosen for the synthesis of the title molecule. However, it was discovered that the rate of production of isobenzofuran from this approach was too slow to react with the fugitive arynes. Consequently, an alternative route was employed to realize the title molecule in a neat state. In this way, the reactions between the title molecule and arynes were successfully achieved. Herein, two synthetic approaches towards the title molecule and its further manipulation for the preparation of silylated linear polycyclic aromatic hydrocarbons (PAH) were reported.