17419-98-6

Basic information

• Product Name: 2-Methoxy-N-sulfinylaniline
• Synonyms: 2-Methoxy-N-sulfinylaniline
• CAS NO: 17419-98-6
• Molecular Formula: C₇H₇NO₂S
• Molecular Weight: 0
• Mol File: 17419-98-6.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Methoxy-N-sulfinylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Methoxy-N-sulfinylaniline(17419-98-6)
• EPA Substance Registry System: 2-Methoxy-N-sulfinylaniline(17419-98-6)

Safety Data

• Hazardous Substances Data: 17419-98-6(Hazardous Substances Data)

Upstream product

• 90-04-0 2-methoxy-phenylamine 

Downstream Products

• 1520119-66-7 N-(2-methoxyphenyl)butane-2-sulfinamide 
• 1520120-47-1 2-(2-methoxyphenyl)-1-oxo-1-sec-butyl-1λ⁶-thia-2,6-diazacyclohex-6-en-3-one 
• 1520120-37-9 1-ethyl-2-(4-methoxyphenyl)-1-oxo-1λ⁶-thia-2,6-diazacyclohex-6-en-3-one 
• 1520120-18-6 3-{[(2-methoxyanilino)oxo-sec-butyl-1λ⁶-sulfanylidene]amino}propanoic acid 
• 1520120-08-4 3-{[ethyl(4-methoxyanilino)oxo-1λ⁶-sulfanylidene]amino}propanoic acid 
• 1520119-91-8 ethyl 3-{[(2-methoxyanilino)oxo-sec-butyl-1λ⁶-sulfanylidene]amino}propanoate 
• 1520119-82-7 ethyl 3-{[ethyl(4-methoxyanilino)oxo-1λ⁶-sulfanylidene]amino}propanoate 
• 1520119-57-6 N-(4-methoxyphenyl)ethanesulfinamide 
• 73939-13-6 N-(diphenylmethylene)-N-(2-methoxyphenyl)amine 
• 20768-48-3 2-methoxy-N-(1-phenylethylidene)benzenamine 
• 41855-67-8 (2-Methoxy-phenyl)-[1-pyridin-3-yl-meth-(E)-ylidene]-amine 
• 1344679-94-2 (1R,4S)-N-(2-methoxyphenyl)-4-ethyl-4-phenyl-1,2-thiazetidin-3-one 1-oxide 
• 1344679-93-1 (1S,4R)-N-(2-methoxyphenyl)-4-ethyl-4-phenyl-1,2-thiazetidin-3-one 1-oxide 
• 2103-48-2 N.N-Dimethyl-N'-<2-methoxy-phenyl>-formamidin 

Relevant articles and documents

Synthesis of six-membered cyclic sulfonimidamides

A general synthetic route to six-membered cyclic N-aryl- and N-alkyl-substituted sulfonimidamides via an intramolecular ring closure of suitably functionalised acyclic sulfonimidamides is described. The structure of this new ring system was confirmed by v

N-heterocyclic carbene catalysis: Enantioselective formal [2+2] cycloaddition of ketenes and N-sulfinylanilines

Sultam of swing: Both enantiomers of 1,2-thiazetidin-3-one oxides were obtained in very good yields with excellent enantioselectivities when using N-heterocyclic carbene catalysts (see scheme; M.S.=molecular sieves, TBS=tert-butyldimethylsilyl). The products were easily converted into 3-oxo-β-sultams, α-mercapto amides, and β-mercapto amines through oxidation or reduction. Copyright

Substituted N-aryl alk-1-enesulfinamides: Preparation, properties and conversion into the corresponding indole compounds [1]

Reaction of vinylic organometallic derivatives with N-sulfinyl arenamines 2 affords the title sulfinamides 3. On heating their solutions in selected solvents to 80-124 °C, these sulfinamides are converted into the corresponding indoles 6, probably via a [3.3]-sigmatropic rearrangement to intermediates VIII which undergo an intramolecular carbophilic reaction of the nitrogen atom with the neighboring sulfine group, followed by elimination of HSOH. The triethyloxonium tetrafluoroborate- or boron trifluoride etherate catalyzed conversion 3 → 6 can be carried out at a much lower temperature. Elsevier,.

Heterocyclic Synthesis with Malonyl Dichloride. Part 13. 6-Chloro-4-hydroxy-2-oxypyran-3-carboxanilides from N-Sulphinylanilines and Further Reactions of Malonyl Dichloride with Thiocyanates

N-Sulphinylanilines react with malonyl dichloride to give 6-chloro-4-hydroxy-2-oxopyran-3-carboxanilides with loss of the sulphoxide moiety as thionyl chloride.Milder conditions and electron-withdrawing substituents do not alter the course of the reaction of thiocyanates with malonyl dichloride to give 2-substituted-thio-7-chloro-4H,5H-pyranooxazine-4,5-diones.