2-Methoxy-N-sulfinylaniline

Base Information

• Chemical Name: 2-Methoxy-N-sulfinylaniline
• CAS No.: 17419-98-6
• Molecular Formula: C7H7NO2S
• Molecular Weight: 169.204
• Mol file: 17419-98-6.mol

Synonyms:N-Sulfinyl-o-anisidin;2-Thionylamino-phenol-methylaether;N-sulfinyl-o-anisidine;N-(2-methoxy-phenyl)-sulfur imide oxide;N-sulphinyl-o-anisidine;2-methoxy-N-sulfinyl-aniline;

Chemical Property of 2-Methoxy-N-sulfinylaniline

Chemical Property:

• Melting Point: 30 °C (hexane)
• PSA: 70.75000
• LogP: 2.58900

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Methoxy-N-sulfinylaniline

There total 1 articles about 2-Methoxy-N-sulfinylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

2-methoxy-phenylamine (90-04-0) → N?sulfinyl?2?methoxyaniline (17419-98-6)

Guidance literature:

With hydrogenchloride; thionyl chloride; In benzene; Heating;

Reference yield: 99.0%

N?sulfinyl?2?methoxyaniline (17419-98-6) + vanadium(V) oxychloride (7727-18-6) → (o-methoxyphenylimido)vanadium(V) trichloride

Guidance literature:

In n-heptane; for 72h; Schlenk technique; Reflux;

DOI:10.1016/j.jorganchem.2020.121665

Reference yield: 94.0%

N?sulfinyl?2?methoxyaniline (17419-98-6) + vinyl magnesium bromide (1826-67-1) → N-(2-methoxyphenyl)ethenesulfinamide (105896-38-6)

Guidance literature:

In tetrahydrofuran; -30 gradC then 2 hrs at 18 gradC;

DOI:10.1016/S0040-4039(00)84114-3

upstream raw materials:

2-methoxy-phenylamine

Downstream raw materials:

2-[3-(2-methoxy-phenyl)-2-oxo-2λ⁴-[1,2,3]oxathiazetidin-4-yl]-pyridine

2-[3-(2-methoxy-phenyl)-2-oxo-2λ⁴-[1,2,3]oxathiazetidin-4-yl]-6-methyl-pyridine

N-(2-methoxyphenyl)ethenesulfinamide

di(2-methoxyphenyl)sulfurdiimine