175354-30-0

Basic information

• Product Name: TRIS(3,3,4,4,5,5,6,6,7,7,8,8-TRIDECAFLUOROOCTYL)PHENYLTIN
• Synonyms: TRIS(3,3,4,4,5,5,6,6,7,7,8,8,8-TRIDECAFLUOROOCTYL)PHENYL TIN;TRIS(3,3,4,4,5,5,6,6,7,7,8,8-TRIDECAFLUOROOCTYL)PHENYLTIN;TRIS(2-(PERFLUOROHEXYL)ETHYL)PHENYLTIN;TRIS(1H,1H,2H,2H-PERFLUOROOCTYL)PHENYLTIN;Tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyltin,95%
• CAS NO: 175354-30-0
• Molecular Formula: C30H17F39Sn
• Molecular Weight: 1237.1
• Mol File: 175354-30-0.mol

Chemical Properties

• Boiling Point: 479.5±55.0 °C(Predicted)
• Appearance: /
• Refractive Index: 1.3685-1.3705
• CAS DataBase Reference: TRIS(3,3,4,4,5,5,6,6,7,7,8,8-TRIDECAFLUOROOCTYL)PHENYLTIN(CAS DataBase Reference)
• NIST Chemistry Reference: TRIS(3,3,4,4,5,5,6,6,7,7,8,8-TRIDECAFLUOROOCTYL)PHENYLTIN(175354-30-0)
• EPA Substance Registry System: TRIS(3,3,4,4,5,5,6,6,7,7,8,8-TRIDECAFLUOROOCTYL)PHENYLTIN(175354-30-0)

Safety Data

• Hazard Codes: T
• Statements: 23/24/25
• Safety Statements: 45-36/37
• Hazardous Substances Data: 175354-30-0(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless slightly viscous liquid

Upstream product

• 1124-19-2 phenyltin trichloride 
• 2043-57-4 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane 
• 76598-01-1 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl magnesium iodide 

Downstream Products

• 162611-87-2 [carbonyl-11C]benzophenone 
• 28790-55-8 [¹²⁵I]iodo-benzene 
• 175354-32-2 tris(1H,1H,2H,2H-perfluorooctyl)tin hydride 

Relevant articles and documents

Methods for purifying radiolabelled compounds

One aspect of the present invention relates to a method of purifying radiolabelled compounds comprising a) loading onto a fluorous polymer a radiolabelled compound precursor comprising a fluoroalkyl tin moiety; b) reacting the radiolabelled compound precursor with a radiolabel delivering compound to give a radiolabelled compound, wherein the fluoroalkyl tin moiety is replaced by a radiolabel; and c) eluting the radiolabelled compound from the fluorous polymer.

Fluorous reaction and separation systems

The present invention provides several methods of synthesis and separation in which organic/fluorous phase separation techniques are used to effect separations. The present invention also provides novel compositions of matter comprising fluorous Si, Sn and Ge compounds.

Fluorous reaction systems

The present invention provides a method for carrying out a chemical reaction comprising the steps of forming an organic/fluorous solubilizing liquid phase comprising a solvent system. The solvent system is selected or adapted to substantially solubilize a fluorous reaction component or components (that is, a fluorous reagent, a fluorous catalyst and/or a fluorous reactant). The "fluorous reaction component" is functionalized to comprise at least one fluorous moiety having the formula -(R)d (Rf)e. (Rf)e is at least one fluorous group and e is a whole number. (R)d is an organic (for example, hydrocarbon) spacer group, which may be present or absent, and d is an integer equal to at least zero. The solvent system is also adapted to substantially solubilize an organic reaction component or components. After the reaction occurs in the organic/fluorous solubilizing liquid phase, a phase separation into at least a fluorous phase and an organic phase is effected. The present invention also provides a chemical compound of the formula XM?(R) (Rf)!3, wherein M is Ge or Sn and X is an atom or group selected to react with an organic reaction component or components.