175354-32-2Relevant academic research and scientific papers
Fluorous tin hydrides: A new family of reagents for use and reuse in radical reactions
Curran, Dennis P.,Hadida, Sabine,Kim, Sun-Young,Luo, Zhiyong
, p. 6607 - 6615 (2007/10/03)
Eight members of a new family of highly fluorinated (fluorous) tin hydrides have been synthesized and studied as reagents for radical reactions. Tin hydrides of the general formulas [Rf(CH2)n]3SnH and [Rf-(CH2)
Fluorous reaction and separation systems
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, (2008/06/13)
The present invention provides several methods of synthesis and separation in which organic/fluorous phase separation techniques are used to effect separations. The present invention also provides novel compositions of matter comprising fluorous Si, Sn and Ge compounds.
Fluorous reaction systems
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, (2008/06/13)
The present invention provides a method for carrying out a chemical reaction comprising the steps of forming an organic/fluorous solubilizing liquid phase comprising a solvent system. The solvent system is selected or adapted to substantially solubilize a fluorous reaction component or components (that is, a fluorous reagent, a fluorous catalyst and/or a fluorous reactant). The "fluorous reaction component" is functionalized to comprise at least one fluorous moiety having the formula -(R)d (Rf)e. (Rf)e is at least one fluorous group and e is a whole number. (R)d is an organic (for example, hydrocarbon) spacer group, which may be present or absent, and d is an integer equal to at least zero. The solvent system is also adapted to substantially solubilize an organic reaction component or components. After the reaction occurs in the organic/fluorous solubilizing liquid phase, a phase separation into at least a fluorous phase and an organic phase is effected. The present invention also provides a chemical compound of the formula XM?(R) (Rf)!3, wherein M is Ge or Sn and X is an atom or group selected to react with an organic reaction component or components.
