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  • 20294-39-7 Structure
  • Basic information

    1. Product Name: 6-methylindan-5-ol
    2. Synonyms: 6-methylindan-5-ol;Einecs 243-709-2
    3. CAS NO:20294-39-7
    4. Molecular Formula: C10H12O
    5. Molecular Weight: 148.20168
    6. EINECS: 243-709-2
    7. Product Categories: N/A
    8. Mol File: 20294-39-7.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 270.3°Cat760mmHg
    3. Flash Point: 121.5°C
    4. Appearance: /
    5. Density: 1.112g/cm3
    6. Vapor Pressure: 0.00415mmHg at 25°C
    7. Refractive Index: 1.592
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: 6-methylindan-5-ol(CAS DataBase Reference)
    11. NIST Chemistry Reference: 6-methylindan-5-ol(20294-39-7)
    12. EPA Substance Registry System: 6-methylindan-5-ol(20294-39-7)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 20294-39-7(Hazardous Substances Data)

20294-39-7 Usage

Synthesis Reference(s)

Tetrahedron Letters, 26, p. 2159, 1985 DOI: 10.1016/S0040-4039(00)98950-0Journal of the American Chemical Society, 107, p. 1060, 1985 DOI: 10.1021/ja00290a053

Check Digit Verification of cas no

The CAS Registry Mumber 20294-39-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,0,2,9 and 4 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 20294-39:
(7*2)+(6*0)+(5*2)+(4*9)+(3*4)+(2*3)+(1*9)=87
87 % 10 = 7
So 20294-39-7 is a valid CAS Registry Number.
InChI:InChI=1/C10H12O/c1-7-5-8-3-2-4-9(8)6-10(7)11/h5-6,11H,2-4H2,1H3

20294-39-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 6-methyl-2,3-dihydro-1H-inden-5-ol

1.2 Other means of identification

Product number -
Other names EINECS 243-709-2

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:20294-39-7 SDS

20294-39-7Relevant articles and documents

Molecular complexity from aromatics: A novel, stereoselective route to tricyclo[5.2.2.01,5]undecenones, tricyclo[6.2.2.01,6] dodecenones, and [n.3.3]propellanes

Singh, Vishwakarma,Sahu, Pramod K.,Singh, Raj Bahadur,Mobin, Shaikh M.

, p. 10155 - 10165 (2007)

(Chemical Equation Presented) A general stereoselective route to functionalized and substituted tricyclo [5.2.2.01,5]undecenones, tricyclo-[6.2.2.01,6]dodecenones, and [3.3.3]- and [4.3.3]propellanes from simple aromatic precursors is reported. The methodology involves generation and cycloaddition of annulated cyclohexa-2,4-dienones with various acrylates followed by manipulation of the resulting tricyclic adducts, leading to functionalized tricyclo-[5.2.2.01,5]undecenones and tricyclo[6.2.2.01,6]dodecenones endowed with a β,γ-enone chromophore. Photochemical reaction of the tricyclic chromophoric systems followed by reductive cleavage provided an efficient entry into propellanes.

Gold catalysis: Domino reaction of En-diynes to highly substituted phenols

Hashmi, A. Stephen K.,Haeffner, Tobias,Rudolph, Matthias,Rominger, Frank

supporting information; experimental part, p. 8195 - 8201 (2011/09/12)

By Sonogashira coupling of 1,7-heptadiynes and 1,8-octadiynes with 2-iodoallyl alcohols, various substrates that bear a 2-alkynylallyl alcohol moiety tethered to an additional alkyne were prepared in one step. Subjection to nitrogen acyclic carbene (NAC)/gold(I) catalysts delivered highly substituted phenols in an efficient domino reaction. Furan derivatives were formed as intermediates; this was proven by in situ NMR spectroscopy. The uncommon substitution pattern of these furans opens the way for a selective formation of phenols that contain the hydroxyl group in the meta position to the ring junction, which previously was not possible by gold-catalyzed furan-yne cyclization. Furthermore, interesting mechanistic insights were obtained by products derived from secondary allyl alcohols. In this case, in addition to the phenolic compounds, a ketone is formed by 1,2-alkyl shift.

Synthesis and Thermolysis of Enediynyl Ethyl Ethers as Precursors of Enyne - Ketenes

Tarli, Anna,Wang, Kung K.

, p. 8841 - 8847 (2007/10/03)

Enediynyl ethyl ethers 14/17 were synthesized by using the Pd(PPh3)4-catalyzed cross-coupling factions between enynyl iodides 13/16 and (2-ethoxyethynyl)zinc chloride. Thermolysis of these enediynyl ethyl ethers in refluxing chlorobenzene (132°C) promoted a retro-ene reaction to produce enyne - ketenes, which underwent the Moore cyclization reactions to form the biradicals having a phenyl radical center and a phenoxy radical center. The presence of two radical centers in he same molecule simultaneously provided many opportunities for intramolecular decay through disproportionate, radical - radical combination, and the formation of o-quinone methide.

Alkylations of Tetracarbonyl(phosphine)chromium and Pentacarbonylchromium Carbene Complexes and Their Reactions with Selected Acetylenes

Xu, Yao-Chang,Wulff, William D.

, p. 3263 - 3275 (2007/10/02)

The thermodynamic acidity of (methylmethoxymethylene)tetracarbonyl(tri-n-butylphosphine)chromium (1b) was found to be 6 orders of magnitude less than that of (methylmethoxymethylene)pentacarbonylchromium (1a).The anion 2b is generated from 1b by deprotona

SYNTHESIS OF PHENOLS FROM METAL-CARBYNES AND DIYNES

Sivavec, Timothy M.,Katz, Thomas J.

, p. 2159 - 2162 (2007/10/02)

Metal-carbynes RCM(CO)4Br with diacetylenes give specific phenols in good yield.The reactions take only a few minutes at or below room temperature.

Synthesis and antianxiety activity of (ω-piperazinylalkoxy)indan derivatives

Kikumoto,Tobe,Fukami,Egawa

, p. 246 - 250 (2007/10/02)

A series of (ω-piperazinylalkoxyl)indan derivatives has been synthesized and screened for potential antianxiety activities. The effect of structural modification of these molecules on activities has been systematically examined. Antianxiety activity was displayed by 5-[3-(4-phenyl-1-piperazinyl)propoxy]indan (2), 5-[3-(4-[4-fluorophenyl)-1-piperazinyl]propoxy]indan (8), 6-fluoro-5-[3-(4-phenyl-1-piperazinyl)propoxy]indan (33), and 6-methyl-5-[3-(4-phenyl-1-piperazinyl)propoxy]indan (42), as determined in antifighting and anti-morphine tests. These derivatives in antianxiety tests were equipotent or more potent than chloridazepoxide with less muscle-relaxant effect. They also showed weak neuroleptic-like action.

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