23234-35-7

Basic information

• Product Name: BOC-LYS(Z)-GLY-OME
• Synonyms: BOC-LYS(Z)-GLY-OME
• CAS NO: 23234-35-7
• Molecular Formula: C₂₂H₃₃N₃O₇
• Molecular Weight: 451.51
• Mol File: 23234-35-7.mol

Chemical Properties

• Appearance: /
• Storage Temp.: -15°C
• CAS DataBase Reference: BOC-LYS(Z)-GLY-OME(CAS DataBase Reference)
• NIST Chemistry Reference: BOC-LYS(Z)-GLY-OME(23234-35-7)
• EPA Substance Registry System: BOC-LYS(Z)-GLY-OME(23234-35-7)

Safety Data

• Hazardous Substances Data: 23234-35-7(Hazardous Substances Data)

Upstream product

• 2389-45-9 Boc-Lys(Z)-OH 
• 5680-79-5 glycine ethyl ester hydrochloride 
• 616-34-2 methoxycarbonylmethylamine 
• 2389-46-0 N-α-tert-butyloxycarbonyl-N-ε-benzyloxycarbonyl-lysine p-nitrophenyl ester 
• 34404-36-9 Boc-Lys(Z)-OSu 
• 1280225-81-1 C₂₉H₄₁N₃O₈ 

Downstream Products

• 53613-24-4 N-(N^α-tert-butoxycarbonyl-N^ε-carbobenzoxy-L-lysyl)glycine 
• 33043-27-5 BOC-Lys(Z)-Gly-NH₂ 
• 63276-44-8 TFA*H-Lys(Z)-Gly-OMe 
• 28872-69-7 ((S)-6-Benzyloxycarbonylamino-2-tert-butoxycarbonylamino-hexanoylamino)-acetic acid pentachlorophenyl ester 
• 72724-86-8 N-[N²-acetyl-N⁶-(benzyloxycarbonyl)-L-lysyl]glycine methyl ester 
• 130540-25-9 HCl*H-Amn-Lys(Z)-Gly-OMe 
• 152768-72-4 Boc-Amn-Lys(Z)-Gly-OMe 
• 152769-09-0 Boc-(R)-Amhn-Lys(Z)-Gly-OMe 
• 68803-04-3 Boc-(Lys(Z)-Gly)2-OH 
• 112120-70-4 Boc-(Lys(Z)-Gly)3-ONp 

Relevant articles and documents

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A simple two step procedure for the synthesis of a dipeptide from N-hydroxy-3-azaspiro[5,5]undecane-2,4-dione (HO-ASUD) activated α-amino acids is described. In presence of DCC, N-hydroxy-3-azaspiro[5,5]undecane-2,4- dione readily esterifies the carboxylic acid group of all the N-protected amino acids to yield crystalline N-hydroxy-3-aza spiro[5,5]undecane-2,4-dione activated carboxy ester. The N-hydroxy-3-aza spiro[5,5]undecane-2,4-dione activated carboxy esters of N-protected amino acids readily condensed with other amino acids and gave a dipeptide. This new method is effective for the DCC coupling of a variety of chiral amino acids without loss of enantiomeric purity. Synthesis of fifteen dipeptides including the hitherto unreported Fmoc-l-Orn(Boc)-Val-OMe, Fmoc-l-Cys(trt)-Gly-OEt and Boc-l-Tyr-Gly-OEt is presented.

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Synthesis of a Cyclic Peptide Polyamine: A Comparative Study of Routes to Cyclo-(Lys-Lys-Gly)2

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