315242-23-0

Basic information

• Product Name: 3-(4-methoxyphenyl)-1-phenyl-3-tosylpropan-1-one
• Synonyms: 3-(4-methoxyphenyl)-1-phenyl-3-tosylpropan-1-one;3-(4-Methoxy-phenyl)-1-phenyl-3-(toluene-4-sulfonyl)-propan-1-one
• CAS NO: 315242-23-0
• Molecular Formula: C₂₃H₂₂O₄S
• Molecular Weight: 394.48338
• Mol File: 315242-23-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-(4-methoxyphenyl)-1-phenyl-3-tosylpropan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-methoxyphenyl)-1-phenyl-3-tosylpropan-1-one(315242-23-0)
• EPA Substance Registry System: 3-(4-methoxyphenyl)-1-phenyl-3-tosylpropan-1-one(315242-23-0)

Safety Data

• Hazardous Substances Data: 315242-23-0(Hazardous Substances Data)

Upstream product

• 536-57-2 p-toluene sulfinic acid 
• 959-33-1 3-(4-methoxyphenyl)-1-phenylprop-2-en-1-one 
• 22252-15-9 trans-4-methoxychalcone 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 51608-60-7 N-(benzylidene)-p-methylbenzenesulfonamide 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 98-86-2 acetophenone 
• 123-11-5 4-methoxy-benzaldehyde 

Relevant articles and documents

Catalytic arylsulfonyl radical-triggered 1,5-enyne-bicyclizations and hydrosulfonylation of α,β-conjugates

A catalytic bicyclization reaction of 1,5-enynes anchored by α,β-conjugates with arylsulfonyl radicals generated in situ from sulfonyl hydrazides has been established using TBAI (20 mol%) and Cu(OAc)2 (5 mol%) as co-catalysts under convenient c

Enantioselective sulfonation of enones with sulfonyl imines by cooperative N-heterocyclic-carbene/thiourea/tertiary-amine multicatalysis

Many hands make light work: In an organocatalytic asymmetric sulfonation of enones, the activation of a sulfonyl imine by an N-heterocyclic carbene (NHC) catalyst led to the release of a sulfinic anion, which underwent nucleophilic addition to the enone. The enantioselectivity of the process was controlled by a chiral thiourea/amine co-catalyst through anion recognition and hydrogen-bonding interactions. Tol=p-tolyl. Copyright

FeCl3ATMSCl: An effective catalytic system for the conjugate addition of sodium p-toluenesulfinate to αβ-enones

A new protocol for the β-sulfonation of αβ-unsaturated carbonyl compounds is described. The method employs FeCl3 as catalyst and TMSC1 as additive for conjugate addition of sodiump-toluenesulfinate to enones.

Synthesis, separation and characterisation of diastereomeric mixtures of 3-p-toluenesulfonyl-1,3-diaryl-propan-1-ols

Four diastereomeric mixtures of 3-p-toluenesulfonyl-1, 3-diarylpropan-1-ols were prepared by the reduction of the corresponding β-sulfonyl ketones and the stereochemistry of the individual separated (HPLC) diastereomers was established on the basis of PMR data.

KINETIC STUDIES ON THE ADDITION OF p-TOLUENESULFINIC ACID TO BENZYLIDENEACETOPHENONES

Kinetics of the addition of p-toluenesulfinic acid to p-substituted benzylideneacetophenones has been investigated.The reaction was second order, first order each in the concentration of sulfinic acid and chalcone.Effects of the p-substituents on the reac