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3395-70-8

Benzene, 1-chloro-3-[(phenylmethoxy)methyl]-, also known as 1-chloro-3-(benzyloxy)methylbenzene, is an organic compound with the molecular formula C14H13ClO. It is a colorless liquid with a density of 1.16 g/cm3 and a boiling point of 360°C. Benzene, 1-chloro-3-[(phenylmethoxy)methyl]- is characterized by a benzene ring with a chloro group at the 1-position, a phenylmethoxy group at the 3-position, and a methyl group attached to the phenylmethoxy. It is used as an intermediate in the synthesis of various pharmaceuticals and agrochemicals, particularly in the production of herbicides and insecticides. Due to its potential health and environmental risks, handling and disposal of this chemical should be done with proper safety measures and in accordance with local regulations.

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  • 3395-70-8 Structure

  • Basic information

    1. Product Name: Benzene, 1-chloro-3-[(phenylmethoxy)methyl]-
    2. Synonyms:
    3. CAS NO:3395-70-8
    4. Molecular Formula: C14H13ClO
    5. Molecular Weight: 232.71
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 3395-70-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Benzene, 1-chloro-3-[(phenylmethoxy)methyl]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Benzene, 1-chloro-3-[(phenylmethoxy)methyl]-(3395-70-8)
    11. EPA Substance Registry System: Benzene, 1-chloro-3-[(phenylmethoxy)methyl]-(3395-70-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 3395-70-8(Hazardous Substances Data)

3395-70-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 3395-70-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,3,9 and 5 respectively; the second part has 2 digits, 7 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 3395-70:
(6*3)+(5*3)+(4*9)+(3*5)+(2*7)+(1*0)=98
98 % 10 = 8
So 3395-70-8 is a valid CAS Registry Number.

3395-70-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-chloro-3-(phenylmethoxymethyl)benzene

1.2 Other means of identification

Product number -
Other names 3-benzyloxymethyl-1-chlorobenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3395-70-8 SDS

3395-70-8Relevant articles and documents

Reductive Etherification via Anion-Binding Catalysis

Zhao, Chenfei,Sojdak, Christopher A.,Myint, Wazo,Seidel, Daniel

supporting information, p. 10224 - 10227 (2017/08/10)

Reductive condensations of alcohols with aldehydes/ketones to generate ethers are catalyzed by a readily accessible thiourea organocatalyst that operates in combination with HCl. 1,1,3,3-tetramethyldisiloxane serves as a convenient reducing reagent. This strategy is applicable to challenging substrate combinations and exhibits functional group tolerance. Competing reductive homocoupling of the carbonyl component is suppressed.

Radical substitution with azide: TMSN3-PhI(OAc)2 as a substitute of in3

Pedersen, Christian Marcus,Marinescu, Lavinia Georgeta,Bols, Mikael

, p. 816 - 822 (2007/10/03)

TMSN3 and PhI(OAc)2 were found to promote high-yield azide substitution of ethers, aldehydes and benzal acetals. The reaction is fast and occurs at zero to ambient temperature in acetonitrile. However, it is essential for the reaction that TMSN3 is added subsequent to the mixture of PhI(OAc)2 and the substrate. A primary deuterium kinetic isotope effect was found for the azidonation of benzyl ethers both with TMSN3-PhI(OAc)2 and with IN3. Also a Hammett free energy relationship study of this reaction showed good correlation with σ+ constants giving with ρ-values of -0.47 for TMSN 3-PhI(OAc)2 and -0.39 for IN3. On this basis a radical mechanism of the reaction was proposed. The Rayal Society of Chemistry 2005.

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