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Carbamic acid, (2-methylpropyl)-, 1,1-dimethylethyl ester (9CI) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 365441-87-8 Structure
  • Basic information

    1. Product Name: Carbamic acid, (2-methylpropyl)-, 1,1-dimethylethyl ester (9CI)
    2. Synonyms: Carbamic acid, (2-methylpropyl)-, 1,1-dimethylethyl ester (9CI);tert-butyl isobutylcarbamate
    3. CAS NO:365441-87-8
    4. Molecular Formula: C9H19NO2
    5. Molecular Weight: 173.25266
    6. EINECS: N/A
    7. Product Categories: N-BOC
    8. Mol File: 365441-87-8.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Carbamic acid, (2-methylpropyl)-, 1,1-dimethylethyl ester (9CI)(CAS DataBase Reference)
    10. NIST Chemistry Reference: Carbamic acid, (2-methylpropyl)-, 1,1-dimethylethyl ester (9CI)(365441-87-8)
    11. EPA Substance Registry System: Carbamic acid, (2-methylpropyl)-, 1,1-dimethylethyl ester (9CI)(365441-87-8)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 365441-87-8(Hazardous Substances Data)

365441-87-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 365441-87-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,6,5,4,4 and 1 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 365441-87:
(8*3)+(7*6)+(6*5)+(5*4)+(4*4)+(3*1)+(2*8)+(1*7)=158
158 % 10 = 8
So 365441-87-8 is a valid CAS Registry Number.

365441-87-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name N-isobutyl-tert-butyl carbamate

1.2 Other means of identification

Product number -
Other names Isobutyl-carbamic acid tert-butyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:365441-87-8 SDS

365441-87-8Relevant articles and documents

A strategy for generating alkyl radicals from aliphatic esters and lactones via sequential hydrolysis and photoinduced decarboxylation

Saito, Hikaru,Kanetake, Takayuki,Osaka, Kazuyuki,Maeda, Kousuke,Morita, Toshio,Yoshimi, Yasuharu

supporting information, p. 1645 - 1648 (2015/03/14)

Sequential hydrolysis and photoinduced decarboxylation of methyl aliphatic esters lead to efficient generation of alkyl radicals under mild conditions. The generated alkyl radicals react with a variety of reagents to produce addition, reduction, and substitution products. In addition, the new tin and halogen free process for alkyl radical generation is applicable to a variety of aliphatic esters including those of dipeptides, steroids, saccharides, and lactones.

Ligand-controlled α- And β-arylation of acyclic N-boc amines

Millet, Anthony,Dailler, David,Larini, Paolo,Baudoin, Olivier

supporting information, p. 2678 - 2682 (2014/03/21)

The palladium-catalyzed ligand-controlled arylation of α-zincated acyclic amines, obtained by directed α-lithiation and transmetalation, is described. Whereas PtBu3 gave rise to α-arylated Boc-protected amines, more flexible N-phenylazole-based phosphine ligands induced major β-arylation through migrative cross-coupling. All manner of control: The arylation of α-zincated acyclic Boc-protected amines was selectively performed at the α- or β-position in a ligand-controlled manner. α-Arylation occurs by direct reductive elimination of the α-palladated intermediate whereas β-arylation involves palladium migration along the alkyl chain. Boc=tert-butoxycarbonyl.

Decarboxylative reduction of free aliphatic carboxylic acids by photogenerated cation radical

Yoshimi, Yasuharu,Itou, Tatsuya,Hatanaka, Minoru

, p. 5244 - 5246 (2008/09/19)

The decarboxylation of free carboxylic acids was effected by a photogenerated cation radical of phenanthrene to yield the reduction product in the presence of a thiol, which provides an alternative method to the Barton decarboxylation procedure for aliphatic acids such as N-Boc amino acids. The Royal Society of Chemistry.

Boc-protected amines via a mild and efficient one-pot curtius rearrangement

Lebel, Helene,Leogane, Olivier

, p. 4107 - 4110 (2007/10/03)

(Chemical Equation Presented) The reaction of a carboxylic acid with di-tert-butyl dicarbonate and sodium azide allowed the formation of an acyl azide intermediate, which undergoes a Curtius rearrangement in the presence of tetrabutylammonium bromide and zinc(II) triflate. The trapping of the isocyanate derivative in the reaction mixture led to the desired tert-butyl carbamate in high yields at low temperature. These reaction conditions are compatible with a variety of substrates, including malonate derivatives, which provide access to protected amino acids.

An expedient transformation of alcohols into N-Boc-amines

Sliwinska,Zwierzak

, p. 2127 - 2130 (2007/10/03)

t-Butyl methyl iminodicarbonate (3) can be easily alkylated with primary or secondary alcohols under Mitsunobu conditions (DIAD, TPP) to give the corresponding N-alkyl iminodicarbonates. Partial deprotection of the latter with methanolic potassium hydroxi

Reductive BOC-amination of aldehydes

Bernacka, Elbieta,Klepacz, Anna,Zwierzak, Andrzej

, p. 5093 - 5094 (2007/10/03)

Base-assisted elimination-reduction of α-amidoalkyl sulfones with sodium borohydride proceeds in tetrahydrofuran at room temperature leading to the corresponding BOC-amines in good yields.

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