38267-76-4

Basic information

• Product Name: N-Boc-ethylaMine, 97%
• Synonyms: N-Boc-ethylaMine, 97%;tert-Butyl N-ethylcarbaMate;tert-butyl ethylcarbaMate
• CAS NO: 38267-76-4
• Molecular Formula: C₇H₁₅NO₂
• Molecular Weight: 145
• Mol File: 38267-76-4.mol

Chemical Properties

• Melting Point: 38-41℃
• Appearance: /
• Storage Temp.: 2-8°C
• Solubility: Dichloromethane, THF
• CAS DataBase Reference: N-Boc-ethylaMine, 97%(CAS DataBase Reference)
• NIST Chemistry Reference: N-Boc-ethylaMine, 97%(38267-76-4)
• EPA Substance Registry System: N-Boc-ethylaMine, 97%(38267-76-4)

Safety Data

• Hazardous Substances Data: 38267-76-4(Hazardous Substances Data)

Usage

Uses

N-?Ethyl-?carbamic Acid 1,?1-?Dimethylethyl Ester is an intermediate in synthesizing Ethalfluralin (E917718), a herbicide.

Upstream product

• 507-40-4 tert-butylhypochlorite 
• 38267-75-3 Phenylazocarbonsaeure-(N-ethyl)-amid 
• 41840-28-2 S-tert-butoxycarbonyl-4,6-dimethyl-2-mercaptopyrimidine 
• 75-04-7 ethylamine 
• 216959-38-5 (tert-butoxycarbonyl-ethyl-amino)-oxo-acetic acid ethyl ester 
• 365441-85-6 N-(tert-butoxycarbonyl)-1-tosyleth-1-ylamine 
• 4248-19-5 tert-butyl carbazate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 36016-38-3 tert-Butyl N-hydroxycarbamate 
• 1310366-23-4 tert-butyl propionyloxycarbamate 
• 557-66-4 ethanamine hydrochloride 
• 557-20-0 diethylzinc 
• 462100-44-3 oxaziridine-2,3,3-tricarboxylic acid 2-tert-butyl ester 3,3-diethyl ester 
• 150884-56-3 N-tert-butyloxycarbonyl-3-(4-cyanophenyl)oxaziridine 

Downstream Products

• 120157-98-4 N-(tert-butyloxycarbonyl)glycine 

Relevant articles and documents

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The method is simple and convenient (reaction conditions ;), more stable,atom utilization rate, by-products are only carbon dioxide pollution, and the yield can reach. suitable for industrial production Curtis; and the method, Lossen is suitable for industrial production . The method disclosed by the invention is simple and convenient to operate under the action of a base as, rearrangement, rearrangement reaction of an alkyl, aryl or heterocyclic aromatic carboxylic acid or an ester and hydroxylamine compound, 90%. (by machine translation)

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A general and effective method for the synthesis of alkylamine via intramolecular decarboxylation of alkanoyloxycarbamates is described. The alkanoyloxycarbamates are readily prepared with alkyl carboxylic acids and hydroxylamine. The reaction shows a broad range of substrates (primary and secondary alkyl) with functional tolerance, and the corresponding products were obtained in good yields under mild conditions.

Alpha-oxidation of amine derivatives by bis(2,2,2-tri-chloroethyl) azodicarboxylate and application of its products as iminium ion equivalents

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Electrophilic amination of organozinc reagents by oxaziridines has been studied. Diorganozinc reagents R2Zn (R = alkyl or aryl) react with N-Boc oxaziridine to afford N-Boc protected primary amines BocNHR in moderate to good yields. No additive

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