60565-88-0

Basic information

• Product Name: Bis(4-methylphenyl)iodonium hexafluorophosphate
• Synonyms: iodonium bis(4-methylphenyl)hexafluorophosphate;BIS(4-METHYLPHENYL)IODONIUM HEXAFLUOROPHOSPHATE;bis(p-tolyl)iodonium hexafluorophosphate;Bis (4-methylphenyl)-hexafluoro- phosphate-(1-)-iodonium;IHT-PI 440;Bis(4-Methylphenyl)-Iodonium-Hexafluoro-;Bis(4-methylphenyl)iodonium hexafluorophosphate 98%;bis(4-methylphenyl)iodanium:hexafluorophosphate
• CAS NO: 60565-88-0
• Molecular Formula: C₁₄H₁₄I*F₆P
• Molecular Weight: 454.13
• EINECS: 262-301-5
• Mol File: 60565-88-0.mol

Chemical Properties

• Appearance: /
• BRN: 3581445
• CAS DataBase Reference: Bis(4-methylphenyl)iodonium hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(4-methylphenyl)iodonium hexafluorophosphate(60565-88-0)
• EPA Substance Registry System: Bis(4-methylphenyl)iodonium hexafluorophosphate(60565-88-0)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 1759 8 / PGII
• WGK Germany: 3
• Hazardous Substances Data: 60565-88-0(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
Bis(4-methylphenyl)iodonium hexafluorophosphate is used as a reagent in chemical synthesis for its ability to facilitate specific reactions and improve the yield of desired products. Its unique structure allows it to participate in various chemical transformations, making it a valuable tool in the synthesis of complex organic molecules.
Used in Photochemistry:
In the field of photochemistry, Bis(4-methylphenyl)iodonium hexafluorophosphate is used as a photosensitizer for its strong UV absorption peak at 267nm. This property enables it to absorb light and initiate photochemical reactions, which can be useful in the synthesis of various compounds and materials.
Used in Electrochemistry:
Bis(4-methylphenyl)iodonium hexafluorophosphate is used as an electrolyte in electrochemical applications due to its ability to conduct ions and facilitate charge transfer. Its use in this field can enhance the performance of electrochemical devices, such as batteries and fuel cells.
Used in Analytical Chemistry:
As an analytical reagent, Bis(4-methylphenyl)iodonium hexafluorophosphate is used for the detection and quantification of specific substances in various samples. Its unique UV absorption properties make it a useful tool for spectroscopic analysis and other analytical techniques.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, Bis(4-methylphenyl)iodonium hexafluorophosphate is used as an intermediate in the synthesis of various drugs and drug candidates. Its unique chemical properties allow it to be a key component in the development of new medications with potential therapeutic applications.
Used in Material Science:
In material science, Bis(4-methylphenyl)iodonium hexafluorophosphate is used in the development of novel materials with specific properties. Its unique structure and reactivity can contribute to the creation of advanced materials with applications in various industries, such as electronics, aerospace, and energy.

InChI:InChI=1/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;1-7(2,3,4,5)6/h3-10H,1-2H3;/q+1;-1

Upstream product

• 123726-16-9 bis(4-methylphenyl)iodonium trifluoromethanesulfonate 

Downstream Products

• 624-31-7 4-tolyl iodide 
• 19966-97-3 di(n-butyl)(p-tolyl)phosphine 
• 613-33-2 (4,4'-dimethyl-1,1'-biphenyl) 
• 7383-90-6 3,4'-dimethylbiphenyl 
• 123726-17-0 2-iodo-4’,5-dimethyl-1,1’-biphenyl 
• 123726-18-1 2,4'-dimethyl-5-iodobiphenyl 
• 108-88-3 toluene 
• 1252931-45-5 Michler's Hydrol Blue 
• 7438-46-2 {4-[Bis-(4-dimethylamino-phenyl)-methylene]-cyclohexa-2,5-dienylidene}-dimethyl-ammonium 
• 70197-46-5 2-dimethylamino-4'-methylbiphenyl 
• 141082-00-0 4-dimethylamino-4'-methylbiphenyl 
• 53477-27-3 4-<4-(N,N-Dimethylamino)benzyl>-N-methylaniline 
• 101-61-1 4,4'-methylene-bis(N,N-dimethylaniline) 
• 103-89-9 4-Methylacetanilide 

Relevant articles and documents

Cu-catalyzed arylcarbocyclization of alkynes with diaryliodonium salts through C-c bond formation on inert C(sp3)-H bond

Copper-catalyzed arylcarbocyclization reaction of alkynes was realized with diaryliodonium salts through C-C bond formation on an inert C(sp3)-H bond. This method provides an efficient cyclization of alkyl alkynes to generate carbocycles with good step-economy. Theoretical study revealed an interesting Cu-catalyzed concerted pathway of the C-C bond formation.