Synthesis of 4(5)-Hydroxymethylimidazoles by Hydroxymethylation and Decarboxylation of Imidazole-4(5)-carboxylic Acids
4(5)-Hydroxymethylimidazoles were prepared by hydroxymethylation and decarboxylation of imidazole-4(5)-carboxylic acid esters.The reaction was simply carried out with aqueous formaldehyde solution in the presence of base.
Kim, Choong S.,Lee, Kee J.,Kim, Hong S.,Chae, Yung B.
p. 1417 - 1418
(2007/10/02)
Process for the production of hydroxymethylimidazoles
This invention discloses a process for the production of hydroxymethylimidazoles which comprises reacting imidazolecarboxylic acids, their esters or inorganic salts with a formaldehyde agent in the presence of an alkali in an aqueous medium.
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(2008/06/13)
Imidazole syntheses, XII: On the synthesis of N substituted imidazole 4 (and 5) carbinols
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Stoeck,Schunakc
p. 677 - 679
(2007/10/04)
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