78830-79-2Relevant articles and documents
Zeolite-catalyzed synthesis of 2,3-unsubstituted benzo[b]furans via the intramolecular cyclization of 2-aryloxyacetaldehyde acetals
Sun, Nan,Huang, Peng,Wang, Yifan,Mo, Weimin,Hu, Baoxiang,Shen, Zhenlu,Hu, Xinquan
supporting information, p. 4835 - 4841 (2015/07/27)
An efficient and environmentally benign heterogeneous catalytic process for the synthesis of 2,3-unsubstituted benzo[b]furans has been established via the intramolecular cyclization of 2-aryloxyacetaldehyde acetals. By utilizing tin-exchanged H-β zeolite (Sn-β) as catalyst, a wide range of functionalized 2,3-unsubstituted benzo[b]furans could be prepared in good to excellent yields. The Sn-β zeolite catalyst also exhibited excellent shape selectivity on the cyclization of meta-substituted 2-aryloxyacetaldehyde acetals, and 6-substituted isomers were preferably formed up to 97% regio-selectivity. Moreover, Sn-β zeolite could be easily recovered and reused without any noticeable activity loss.
1,3-Dioxolane Bearing Perfume and Herbicide Aldehyde Residues
Kamogawa, Hiroyoshi,Haramoto, Yuichiro,Nakazawa, Terumi,Sugiura, Harumitsu,Nanasawa, Masato
, p. 1577 - 1578 (2007/10/02)
4-Methacryloyloxymethyl-1,3-dioxolanes substituted at the 2 position with perfume and herbicide aldehyde residues were synthesized either by acetalization or by transacetalization involving 2,3-dihydroxypropyl methacrylate.The effect of the 2-substituent of the dioxolane ring on the rate of hydrolysis was remarkable.