10026-06-9 Usage
Physical Properties
Colorless fuming liquid; corrosive; density 2.234 g/mL; freezes at –33°C; boils at 114.15°C; critical temperature 318.75°C; critical pressure 37.98 atm; critical volume 351 cm3/mol; soluble in cold water, evolving heat; decomposed by hot water; soluble in alcohol, benzene, toluene, chloroform, acetone and kerosene.
The pentahydrate is a yellowish-white crystalline solid or small, fused lumps; faint odor of HCl; density 2.04 g/cm3; decmposes at 56°C; very soluble in water; soluble in ethanol.
Uses
Different sources of media describe the Uses of 10026-06-9 differently. You can refer to the following data:
1. Tin(IV) chloride is a mordant for dying fabrics; a stabilizer for perfume in soap; used in weighting silk; in ceramic coatings; in manufacturing blue print papers; and to produce fuchsin. Also, tin(IV) chloride is used in preparing many organotin compounds.
2. Substitute for anhydrous stannic chloride where the presence of water is not objectionable
3. Tin (IV) Chloride Pentahydrate is a hydrate of Tin (IV) Chloride(T443805), which can induce slight inhibition of the catalytic activity of horse liver alcohol dehydrogenase (HLADH).
Preparation
Tin(IV) chloride is prepared by reacting tin or tin(II) chloride with chlorine:
Sn + 2Cl2 → SnCl4
SnCl2 + Cl2 → SnCl4
Chemical Properties
Different sources of media describe the Chemical Properties of 10026-06-9 differently. You can refer to the following data:
1. White solid. Soluble in water or alcohol.
2. Stannic chloride is a white to yellow powder with a faint odor of HCl.
General Description
Stannic chloride pentahydrate is a white colored solid. Stannic chloride pentahydrate is soluble in water. Stannic chloride pentahydrate is toxic by ingestion, inhalation and skin absorption. Stannic chloride pentahydrate is used to make perfumes and dyes.
Air & Water Reactions
Soluble in water. Reacts with water to form Hydrochloric Acid in dense white fumes [Merck 11th ed. 1989].
Reactivity Profile
Acidic salts, such as STANNIC CHLORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Hazard
Toxic material
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Safety Profile
A poison by
intraperitoneal and intravenous routes.
Mutation data reported. A corrosive liquid.
When heated to decomposition it emits
toxic vapors of tin and Cl-.
Potential Exposure
Hydrated stannic chloride is used for fixing certain textile dyes, and for treating silk to give weight to the fabric.
Shipping
UN2440 Stannic chloride, pentahydrate, Hazard class: 8; Labels: 8-Corrosive material.
Incompatibilities
Reacts violently with water, forming corrosive hydrochloric acid and tin oxide fumes. Reacts with turpentine, alcohols, and amines, causing fire and explosion hazard. Attacks many metals; some forms of plastics, rubber, and coatings. Reacts with moist air to form hydrochloric acid and dense white fume.
Check Digit Verification of cas no
The CAS Registry Mumber 10026-06-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,0,2 and 6 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 10026-06:
(7*1)+(6*0)+(5*0)+(4*2)+(3*6)+(2*0)+(1*6)=39
39 % 10 = 9
So 10026-06-9 is a valid CAS Registry Number.
InChI:InChI=1/4ClH.5H2O.Sn/h4*1H;5*1H2;/q;;;;;;;;;+4/p-4
10026-06-9Relevant articles and documents
Studies on solid state redox reaction of iron(III) oxalate by gas chromatography
Jinhua, Yuan,Xinquan, Xin,Anbang, Dai,Yuchang, Chang
, p. 51 - 60 (1988)
The solid state redox reaction of iron (III) oxalate with sodium nitrate and tin(II) chloride was investigated in hydrogen atmosphere and helium atmosphere by use of a non-isothermal technique. The evolved gases (EG) formed during the reaction were directly detected by gas chromatography, and the solid products were also identified by XRD, Moessbauer spectra and IR. The results show that the solid state redox reaction can go to completion because electron transfer is much easier than mass diffusion along the boundaries of the reactant. The releasing of crystal and coordination water during the redox reaction also facilitates completion of the reaction. The mechanism of the solid state reaction is also discussed.
