124862-79-9Relevant articles and documents
Artefact formation during acid hydrolysis of saponins from Medicago spp.
Tava, Aldo,Biazzi, Elisa,Mella, Mariella,Quadrelli, Paolo,Avato, Pinarosa
, p. 116 - 127 (2017/04/13)
Artefact compounds obtained during acid hydrolysis of saponins from Medicago spp. (Fabaceae), have been monitored and evaluated by GC-FID. Their identification has been performed by GC-MS and 1H and 13C NMR. Saponins with different substituents on the triterpenic pentacyclic aglycones were considered, and their hydrolysis products were detected and quantified during 10?h of time course reaction. From soyasapogenol B glycoside the well known soyasapogenols B, C, D and F were obtained together with a previously undescribed sapogenol artefact identified as 3β,22β,24-trihydroxyolean-18(19)-en and named soyasapogenol H. From a zanhic acid saponin two major artefact compounds identified as 2β,3β,16α-trihydroxyolean-13(18)-en-23,28-dioic acid and 2β,3β,16α-trihydroxyolean-28,13β-olide-23-oic acid were obtained, together with some zanhic acid. Other compounds, detected in very small amount in the reaction mixture, were also tentatively identified based on their GC-MS and UV spectra. The other most characteristic saponins in Medicago spp., hederagenin, bayogenin and medicagenic acid glycosides, under acidic condition of hydrolysis, released instead the correspondent aglycones and generated a negligible amount of artefacts. Nature of artefacts and mechanism of their formation, involving a stable tertiary carbocation, is here proposed and discussed for the first time.
A γ-PYRONYL-TRITERPENOID SAPONIN FROM PISUM SATIVUM
Tsurumi, Seiji,Takagi, Toshihiro,Hashimoto, Tohru
, p. 2435 - 2438 (2007/10/02)
A new triterpenoid saponin was isolated from Pisum sativum and characterized as 3-O-2)-β-D-galactopyranosyl(12)-β-D-glucuronopyranosyl(1)>-22-O-)>-3β,22β,24-trihydroxyolean-12-ene.The name chromosaponin I is proposed.Chromosaponin I yielded soyasaponin I, known as phytochrome inhibitor, during extraction, but the latter was not found in the free form in this plant. Key Word Index - Pisum sativum; Leguminosae; pea: phytochrome inhibitor; triterpenoid saponin; soyasaponin I derivative; chromosaponin I.
Saponin and sapogenol. XL. Structure of sophoraflavoside I, a bisdesmoside of soyasapogenol B, from Sophorae radix, the root of Sophora flavescens Aiton
Yoshikawa,Wang,Kayakiri,et al.
, p. 4267 - 4274 (2007/10/02)
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