142-87-0

Basic information

• Product Name: SODIUM DECYL SULFATE
• Synonyms: DECYL SODIUM SULFATE;DECYLSULFURIC ACID SODIUM SALT;DECYL SULFATE SODIUM SALT;sulfuricacid,decylester,sodiumsalt;Sulfuricacid,monodecylester,sodiumsalt;SODIUM N-DECYL SULFATE;SODIUM N-DECYL SULPHATE;SODIUM DECYL SULFATE
• CAS NO: 142-87-0
• Molecular Formula: C₁₀H₂₁O₄S*Na
• Molecular Weight: 260.33
• EINECS: 205-568-5
• Mol File: 142-87-0.mol

Chemical Properties

• Melting Point: 192°C(lit.)
• Appearance: White to slightly yellow/Powder
• Density: 1.209[at 20℃]
• Vapor Pressure: 0.51Pa at 20℃
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility: It is soluble in H20, poorly soluble in organic solvents.
• Stability: Stable. Incompatible with oxidizing agents, acids.
• BRN: 3576860
• CAS DataBase Reference: SODIUM DECYL SULFATE(CAS DataBase Reference)
• NIST Chemistry Reference: SODIUM DECYL SULFATE(142-87-0)
• EPA Substance Registry System: SODIUM DECYL SULFATE(142-87-0)

Safety Data

• Hazard Codes: Xn
• Statements: 22-38-41
• Safety Statements: 26-36/37/39
• WGK Germany: 2
• RTECS: WS7625000
• F: 3
• TSCA: Yes
• Hazardous Substances Data: 142-87-0(Hazardous Substances Data)

Usage

Uses

Used in the Rubber Industry:
SODIUM DECYL SULFATE is used as an emulsifier for the preparation of super wear-resistant foamed Styrene Butadiene rubber. Its emulsifying properties help in creating a stable mixture of the rubber components, leading to enhanced wear resistance and overall performance of the final product.
If there are additional applications in other industries, they can be listed as follows:
Used in [Application Industry]:
SODIUM DECYL SULFATE is used as [application type] for [application reason].

Purification Methods

Rigorously purify it by continuous Et2O extraction of a 1% aqueous solution for two weeks. [Beilstein 1 IV 1818.]

InChI:InChI=1/C10H22O4S.Na/c1-2-3-4-5-6-7-8-9-10-14-15(11,12)13;/h2-10H2,1H3,(H,11,12,13);/q;+1/p-1

Synthetic route

1-Decanol (112-30-1) → Sulfuric acid, monodecyl ester, sodium salt (142-87-0)

Conditions	Yield
With sodium hydroxide; chlorosulphuric acid 1.) ether, 20 deg C, 2.) up to pH 8; Multistep reaction;
With chlorosulfonic acid; sodium hydroxide 1>) 30 min, 5 deg C, CH2Cl2; Multistep reaction;
With sulfur trioxide In trifluoroacetic acid-methyl ester
With sulfur trioxide In Methyl trichloroacetate
Stage #1: 1-Decanol With pyridine; aminosulfonic acid at 95℃; for 16h; Microwave irradiation; Stage #2: With sodium carbonate In methanol; water at 20℃; for 0.5h; Stage #3: With sodium sulfate In methanol; water at 20℃; for 0.333333h;

β-cyclodextrin, 1:1 complex with NaSO4C10H21 → Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + β-cyclodextrin

Conditions	Yield
In water at 25℃; Equilibrium constant; dissociation;

C44H84N4(2+)*2Br(1-) + Sulfuric acid, monodecyl ester, sodium salt (142-87-0) → C44H84N4(2+)*2C10H21O4S(1-)

Conditions	Yield
In methanol; dichloromethane at 20℃; for 1h;	73%

C64H95N2O6S(1+)*I(1-) + Sulfuric acid, monodecyl ester, sodium salt (142-87-0) → C64H95N2O6S(1+)*C10H21O4S(1-)

Conditions	Yield
In methanol at 60℃; for 2h;	72%

C48H92N4(2+)*2Br(1-) + Sulfuric acid, monodecyl ester, sodium salt (142-87-0) → C48H92N4(2+)*2C10H21O4S(1-)

Conditions	Yield
In methanol; dichloromethane at 20℃; for 1h;	52%

1,6-bis(1'-tetradecylimidazolium-3'-yl)hexane dibromide + Sulfuric acid, monodecyl ester, sodium salt (142-87-0) → C40H76N4(2+)*2C10H21O4S(1-)

Conditions	Yield
In methanol; dichloromethane at 20℃; for 1h;	49%

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) → 1-Decanol (112-30-1)

Conditions	Yield
With water-d2 at 50 - 105℃; Kinetics; variation of pH;

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + β-cyclodextrin → β-cyclodextrin, 1:1 complex with NaSO4C10H21

Conditions	Yield
In water at 25℃; Equilibrium constant; Thermodynamic data; association;

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + terbium(III) chloride (10042-88-3) → Tb(III) decylsulfate

Conditions	Yield
In ethanol byproducts: NaCl; equimolar amts. of sodium alkylsulfate and TbCl3 were mixed at -20°C; ppt. of NaCl filtered off, filtrate evapd., dried in vacuo over P2O5; elem. anal.;

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + iron(II) sulfate → Fe(C10H21OSO3)2*6H2O

Conditions	Yield
In water (ar); stirring for 1 h at room temp.; filtration, washing (water);

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + iron(II) chloride → Fe(C10H21OSO3)2*6H2O

Conditions	Yield
In water (ar); stirring for 1 h at room temp.; filtration, washing (water);

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + water (7732-18-5) + 1,2-diaminoethane dihydrochloride (333-18-6) + copper dichloride → bis(ethylenediamine)bis(decyl sulfato)copper(II)-diaquabis(ethylenediamine)copper(II) bis(decyl sulfate)

Conditions	Yield
In water Na decyl sulfate added to aq. soln. of CuCl2 and ethylene diamine*2HCl; pH 6-7; crystd. for 1 d; filtered; washed with distd. water; elem. anal.;

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + manganese (II) acetate tetrahydrate (6156-78-1) + 2-(2-benzimidazolyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-3-oxide-1-oxyl (189248-23-5) → 2Mn(2+)*3C7H4N2C3O2N2(CH3)4(1-)*C10H21SO4(1-)=Mn2(C7H4N2C3O2N2(CH3)4)3C10H21SO4

Conditions	Yield
In methanol soln. of ligand in CH3OH treated with 0.66 equiv. of Mn salt in CH3OH, stirred for 15 min, treated slowly with NaC10H21SO4 (0.66 equiv.) in CH3OH, pptd.; suspn. centrifuged, soln. removed, treated with CH3OH, suspn. stirred, centrifuged, solvent removed, operation repeated several times, filtered,washed (CH3OH), elem. anal.;

europium hydroxynitrate hydrate + Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + water (7732-18-5) → europium hydroxy(decylsulfate) sesquihydrate

Conditions	Yield
In water heated at 60°C for 1-10 h in air; filtered off, washed (water), dried at40°C for 1 d, elem. anal.;

2La(3+)*5OH(1-)*NO3(1-)*1.5H2O=La2(OH)5(NO3)*1.5H2O + Sulfuric acid, monodecyl ester, sodium salt (142-87-0) → Nd2(OH)5(decyl sulfate)*1.5H2O

Conditions	Yield
In water Nd compd. treated with aq. soln. of ligand (1:3 molar ratio) at room temp. for 10 h with stirring; XRD;

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + alpha-cyclodextrin (186043-87-8) → C10H21O4S(1-)*C36H60O30*Na(1+)

Conditions	Yield
In water-d2 at 25℃;

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + alpha-cyclodextrin (186043-87-8) → C10H21O4S(1-)*2C36H60O30*Na(1+)

Conditions	Yield
In water-d2 at 25℃;

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + dimethyldiallylammonium chloride (7398-69-8) → diallyldimethylammonium decylsulfate (1311273-84-3)

Conditions	Yield
In water

C62H95N2O2S(1+)*I(1-) + Sulfuric acid, monodecyl ester, sodium salt (142-87-0) → C62H95N2O2S(1+)*C10H21O4S(1-)

Conditions	Yield
In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran

Sulfuric acid, monodecyl ester, sodium salt (142-87-0) + cinnarizine hydrochloride (880764-36-3) → cinnarizine 1-decyl sulfate

Conditions	Yield
In dichloromethane; water at 20℃;

lumefantrine hydrochloride + Sulfuric acid, monodecyl ester, sodium salt (142-87-0) → lumefantrine 1-decyl sulfate

Conditions	Yield
In dichloromethane; water at 20℃; Darkness;

Upstream product

• 112-30-1 1-Decanol 

Downstream Products

• 112-30-1 1-Decanol 

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