1462367-26-5Relevant articles and documents
Intramolecular arylation of amino acid enolates
Atkinson, Rachel C.,Leonard, Daniel J.,Maury, Julien,Castagnolo, Daniele,Volz, Nicole,Clayden, Jonathan
, p. 9734 - 9736 (2013/10/21)
Dianionic enolates formed from N′-aryl urea derivatives of amino acids undergo intramolecular C-arylation by attack of the enolate anion on the N′-aryl ring, leading to a hydantoin derivative of a quaternary amino acid. In situ IR studies allow identification of four intermediates on the reaction pathway.