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1829-25-0

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1829-25-0 Usage

Chemical compound

1-Methoxy-1,2-benziodoxol-3-(1H)-one is a chemical compound.

Appearance

It is a white solid.

Use as a reagent

It is commonly used as a hypervalent iodine reagent in organic synthesis.

Electrophilic iodinating agent

1-Methoxy-1,2-benziodoxol-3-(1H)-one is known for its ability to act as an electrophilic iodinating agent.

Chemical reactions

It is useful for various chemical reactions, including halogenations, oxidations, and functional group transformations.

Preparation of organic molecules

1-Methoxy-1,2-benziodoxol-3-(1H)-one is often utilized in the preparation of organic molecules.

Value in synthetic chemistry

It is considered a valuable tool in synthetic chemistry.

Stability and reactivity

The methoxy group in the compound provides stability and enhanced reactivity, making it a versatile reagent for a wide range of applications in organic synthesis.

Check Digit Verification of cas no

The CAS Registry Mumber 1829-25-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,2 and 9 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1829-25:
(6*1)+(5*8)+(4*2)+(3*9)+(2*2)+(1*5)=90
90 % 10 = 0
So 1829-25-0 is a valid CAS Registry Number.

1829-25-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-methoxy-1H-1λ3-benzo[d][1,2]iodoxol-3-one

1.2 Other means of identification

Product number -
Other names 1-Methoxy-1,2-benziodoxolin-3-on

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1829-25-0 SDS

1829-25-0Relevant articles and documents

CHEMISTRY OF AN ACYLOXYIODINANE, THE INTERMEDIATE IN IODOSOBENZOATE CATALYZED CLEAVAGE OF ACTIVE ESTERS

Moss, Robert A.,Scrimin, Paolo,Rosen, Robert T.

, p. 251 - 254 (1987)

The 1-acetoxy-1,2-benziodoxol-3(1H)-one intermediate in the o-iodosobenzoate cleavage of p-nitrophenyl acetate can be directly observed in dimethyl sulfoxide.

Synthesis of polycyclic aminal heterocycles via decarboxylative cyclisation of dipeptide derivatives

Le Du, Eliott,Robert, Emma G. L.,Waser, Jerome

, p. 3473 - 3476 (2022/03/31)

An oxidative-decarboxylative intramolecular cyclisation of dipeptide derivatives is reported. This transformation is promoted by phenyl iodine(iii) diacetate (PIDA) in combination with BF3·OEt2. The reaction gives access to a variety of valuable polycyclic N-heterocyclic scaffolds containing 5-, 6-, or 7-membered rings.

Synthesis of Diverse Aryliodine(III) Reagents by Anodic Oxidation?

Zu, Bing,Ke, Jie,Guo, Yonghong,He, Chuan

supporting information, p. 627 - 632 (2021/02/12)

An anodic oxidation enabled synthesis of hypervalent iodine(III) reagents from aryl iodides is demonstrated. Under mild electrochemical conditions, a range of aryliodine(III) reagents including iodosylarenes, (difunctionaliodo)arenes, benziodoxoles and diaryliodonium salts can be efficiently synthesized and derivatized in good to excellent yields with high selectivity. As only electrons serve as the oxidation reagents, this method offers a more straightforward and sustainable manner avoiding the use of expensive or hazardous chemical oxidants.

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