1829-25-0Relevant articles and documents
CHEMISTRY OF AN ACYLOXYIODINANE, THE INTERMEDIATE IN IODOSOBENZOATE CATALYZED CLEAVAGE OF ACTIVE ESTERS
Moss, Robert A.,Scrimin, Paolo,Rosen, Robert T.
, p. 251 - 254 (1987)
The 1-acetoxy-1,2-benziodoxol-3(1H)-one intermediate in the o-iodosobenzoate cleavage of p-nitrophenyl acetate can be directly observed in dimethyl sulfoxide.
Synthesis of polycyclic aminal heterocycles via decarboxylative cyclisation of dipeptide derivatives
Le Du, Eliott,Robert, Emma G. L.,Waser, Jerome
, p. 3473 - 3476 (2022/03/31)
An oxidative-decarboxylative intramolecular cyclisation of dipeptide derivatives is reported. This transformation is promoted by phenyl iodine(iii) diacetate (PIDA) in combination with BF3·OEt2. The reaction gives access to a variety of valuable polycyclic N-heterocyclic scaffolds containing 5-, 6-, or 7-membered rings.
Synthesis of Diverse Aryliodine(III) Reagents by Anodic Oxidation?
Zu, Bing,Ke, Jie,Guo, Yonghong,He, Chuan
supporting information, p. 627 - 632 (2021/02/12)
An anodic oxidation enabled synthesis of hypervalent iodine(III) reagents from aryl iodides is demonstrated. Under mild electrochemical conditions, a range of aryliodine(III) reagents including iodosylarenes, (difunctionaliodo)arenes, benziodoxoles and diaryliodonium salts can be efficiently synthesized and derivatized in good to excellent yields with high selectivity. As only electrons serve as the oxidation reagents, this method offers a more straightforward and sustainable manner avoiding the use of expensive or hazardous chemical oxidants.