2050-60-4Relevant articles and documents
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Yakhontov et al.
, (1979)
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Method for synthesizing symmetric oxalate by using dimethyl oxalate and alcohols in one step
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Paragraph 0039; 0040, (2019/01/06)
The invention relates to a method for synthesizing symmetric oxalate, in particular to a method for synthesizing the symmetric oxalate by using dimethyl oxalate and alcohols in one step. The symmetricoxalate is synthesized by using the dimethyl oxalate and the high carbon alcohols such as ethanol, propanol, butanol and pentanol as reaction raw materials and by adopting a one-step synthesis method. A catalyst used in the method is a mesoporous-microporous composite multifunctional basic catalyst, and has the advantages that mesopores significantly improve the mass transfer efficiency, while micropores significantly enlarge the specific surface area of a carrier and improve the dispersion of an active center. 10% MgO-5% Al2O3-8% Fe2O3/Na-meso-Y is used as the catalyst, the raw material ethanol and the dimethyl oxalate are enabled to be subjected to reaction under the atmospheric pressure at the temperature of 100 DEG C under the condition that the space velocity is 2 h-1, wherein the molar ratio of the raw material ethanol to the dimethyl oxalate is equal to 20 to 1; the selectivity of the product diethyl oxalate is stabilized to be about 82%, and the steady state operation is performed for 1000h; the catalytic activity and the product selectivity are basically unchanged. The whole reaction path has the characteristics of being short in synthetic route, simple in process flow and high in raw material conversion rate and product selectivity, and enabling the catalyst to be stable and non-deactivated.
A kind of preparation method of succinic acid diester
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Paragraph 0063-0066, (2017/01/09)
Disclosed is a method for preparing succinic acid diester, in which levulinic acid or levulinate esters are used as raw materials, molecular oxygen is used as oxygen source, and succinic acid diester is produced by catalytic selective oxidation and esterification reaction. The levulinic acid or levulinate esters used as raw materials in the method can be obtained from biomass such as cellulose, starch, agricultural and forestry residues or the like. The method is a new route for preparing succinic acid diester that does not rely on fossil resourse. As the reaction condition in the process is moderate and has a high succinic acid diester selectivity, it has important application prospect.
