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2-phenyl-1-(piperidin-1-yl)ethanethione is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 24815-46-1 Structure
  • Basic information

    1. Product Name: 2-phenyl-1-(piperidin-1-yl)ethanethione
    2. Synonyms: 2-Phenyl-1-(piperidin-1-yl)ethanethione; ethanethione, 2-phenyl-1-(1-piperidinyl)-
    3. CAS NO:24815-46-1
    4. Molecular Formula: C13H17NS
    5. Molecular Weight: 219.3458
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 24815-46-1.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 335.4°C at 760 mmHg
    3. Flash Point: 156.6°C
    4. Appearance: N/A
    5. Density: 1.111g/cm3
    6. Vapor Pressure: 0.00012mmHg at 25°C
    7. Refractive Index: 1.6
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: 2-phenyl-1-(piperidin-1-yl)ethanethione(CAS DataBase Reference)
    11. NIST Chemistry Reference: 2-phenyl-1-(piperidin-1-yl)ethanethione(24815-46-1)
    12. EPA Substance Registry System: 2-phenyl-1-(piperidin-1-yl)ethanethione(24815-46-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 24815-46-1(Hazardous Substances Data)

24815-46-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 24815-46-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,4,8,1 and 5 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 24815-46:
(7*2)+(6*4)+(5*8)+(4*1)+(3*5)+(2*4)+(1*6)=111
111 % 10 = 1
So 24815-46-1 is a valid CAS Registry Number.

24815-46-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-phenyl-1-piperidin-1-ylethanethione

1.2 Other means of identification

Product number -
Other names N,N-pentamethylenephenylthioacetamide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:24815-46-1 SDS

24815-46-1Relevant articles and documents

Transition-Metal-Free, General Construction of Thioamides from Chlorohydrocarbon, Amide and Elemental Sulfur

Chen, Xinzhi,Ge, Xin,Jin, Hao,Qian, Chao,Zhou, Shaodong

supporting information, p. 3403 - 3406 (2021/06/25)

A general method for one-pot synthesis of thioamides is developed through a three-component reaction involving chlorohydrocarbon, amide and elemental sulfur. Such a strategy does not only avoid residual transition metal in the product but also prevent the generation of C?N coupling by-product. The latter is prone to be generated when alkane halide and amine are present. With the protocol proposed in this work, both alkyl and aryl thioamides can be obtained in moderate to excellent yields with a high tolerance of various functional groups. External oxidants are not required in the reaction. In addition, the reaction mechanisms are addressed using a combination of controlling experiments and quantum chemical calculations.

Rapid and efficient protocol for Willgerodt–Kindler’s thioacetamides catalyzed by sulfated polyborate

Rekunge, Deelip S.,Khatri, Chetan K.,Chaturbhuj, Ganesh U.

, p. 2091 - 2095 (2017/10/06)

Abstract: A simple and efficient method for the synthesis of one-pot, three-component thioacetamides via Willgerodt–Kindler reaction was developed using a sulfated polyborate catalyst. The method described the reaction of ketones, sulfur, and secondary am

A study of the Willgerodt-Kindler reaction to obtain thioamides and α-ketothioamides under solvent-less conditions

Valdez-Rojas, Jose Ernesto,Rios-Guerra, Hulme,Ramirez-Sanchez, Alma Leticia,Garcia-Gonzalez, Guadalupe,Alvarez-Toledano, Cecilio,Lopez-Cortes, Jose Guadalupe,Toscano, Ruben A.,Penieres-Carrillo, Jose Guillermo

supporting information; experimental part, p. 567 - 573 (2012/08/08)

In this paper, the results obtained in the synthesis of thioamides and α-ketothioamides by a modification of the Willgerodt-Kindler reaction, under solvent-free and noncatalyst conditions using IR energy as a source of activation, are presented. The use of IR energy in these reactions has been shown to lead to a mixture of thioamide and α-ketothioamide as the main products in most cases, with the latter predominating. The yields of α-ketothioamides from most of these reactions are better than those reported previously. To the best of our knowledge, this is the first time that IR energy has been applied to promote the Willgerodt-Kindler reaction.

Ultrasound-mediated willgerodt-kindler reactions: Non-thermal synthesis of thioacetamides

Mojtahedi, Mohammad M.,Alishiri, Tooba,Abaee, M. Saeed

experimental part, p. 1910 - 1915 (2011/10/08)

Non-thermal, solvent-free condensation of several aryl methyl ketones with amines and elemental sulfur is efficiently conducted using ultrasonic irradiation within short time periods. Consequently, various thioacetamides are conveniently synthesized. Simi

A convenient one-pot preparation of N-substituted thioamides

Pandey, Lokesh Kumar,Pathak, Uma,Mazumder, Avik,Mathura, Sweta

experimental part, p. 1225 - 1228 (2010/12/20)

A convenient one-pot preparation of N-substituted thioamides from acyl halides, amines and H2O/PSCl3/Et3N in good to excellent yield has been reported through a solvent-free, microwave assisted method.

Reactions of N,N-(dialkyl)arylthioacetamides with dialkyl acetylenedicarboxylates

Kosterina, M. F.,Morzherin, Yu. Yu.,Tkachev, A. V.,Rybalova, T. V.,Gatilov, Yu. V.,Bakulev, V. A.

, p. 653 - 658 (2007/10/03)

2-(Alkoxycarbonylmethylidene)-4-aryl-5-(dialkylamino)thiophen-3(2H)-ones were synthesized by condensation of N,N-(dialkyl)arylthioacetamides with dialkyl acetylenedicarboxylates. Intermediate substituted vinylic sulfides were isolated. When heated or in t

1,2,3-Thiadiazoles. I. Synthesis of Sodium (or Potassium) 1,2,3-Thiadiazole-4-thiolates via Thiocarbazonate Esters and N-Acylthiohydrazonate Esters

Lee, Ving J.,Curran, William V.,Fields, Thomas F.,Learn, Keith

, p. 1873 - 1891 (2007/10/02)

A general synthesis of 1,2,3-thiadiazole-4-thiolates 1 and their derivatives 2-3 by an extension of the Hurd-Mori 1,2,3-thiadiazole synthesis is described.Treatment of methyl (or ethyl) hydrazinocarboxylates 11 (thiocarbazonate es

Optimum Conditions for the Willgerodt-Kindler Reaction. 3. Amine Variation

Lunstedt, Torbjoern,Carlson, Rolf,Shabana, Rashad

, p. 157 - 163 (2007/10/02)

Optimum conditions for the synthesis of phenylacetic acid thioamids by the joint action of elemental sulfur and amines on acetophenons have been studied with the following amines: Morpholine, pyrrolidine, 4-methylpiperidine, isopropylamine, 2-butylamine,

A convenient method for the selective reduction of amides to amines

Raucher, Stanley,Klein, Peter

, p. 4061 - 4064 (2007/10/02)

A variety of amides have been selectively reduced to the corresponding amines via conversion to their thioamides and treatment with triethyloxonium tetrafluoroborate followed by sodium borohydride. This procedure is compatible with isolated and conjugated double bonds, esters, intro groups, and sulfonamides.

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