26042-64-8

Basic information

• Product Name: Silver hexafluoroantimonate
• Synonyms: silver hexafluoroantimonate(1-);Silverhexafluoroantimonate(V),98%;Silver hexafluoroantimonate 98%;Silverhexafluoroantimonate98%;hexafluoro-, silver, (OC-6-11)-Antimonate;Silver hexafluoroantimonate,99%;Silver hexafluorosilicate ,99%;Silver(I) hexafluoroantimonate(V) 98%
• CAS NO: 26042-64-8
• Molecular Formula: Ag.F6Sb
• Molecular Weight: 343.62
• EINECS: 247-429-1
• Product Categories: Sb (Antimony) Compounds;Ag (Silver) Compounds;Classes of Metal Compounds;Semimetal Compounds;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Gold Catalysis;Salts;Silver AdditivesMetal and Ceramic Science;Silver Salts;SilverCatalysis and Inorganic Chemistry;halometallate salts
• Mol File: 26042-64-8.mol
• Article Data: 6

Chemical Properties

• Appearance: White to pale yellow/Powder/Lump
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Water Solubility: Soluble in water.
• Sensitive: Hygroscopic
• Stability: hygroscopic
• CAS DataBase Reference: Silver hexafluoroantimonate(CAS DataBase Reference)
• NIST Chemistry Reference: Silver hexafluoroantimonate(26042-64-8)
• EPA Substance Registry System: Silver hexafluoroantimonate(26042-64-8)

Safety Data

• Hazard Codes: Xn,N,C
• Statements: 20/22-51/53
• Safety Statements: 61
• RIDADR: UN 3260 8/PG 2
• WGK Germany: 2
• F: 3-8-10
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 26042-64-8(Hazardous Substances Data)

Usage

Chemical Properties

white to pale yellow crystalline powder

Uses

Silver Hexafluoroantimonate(V) is used as a catalyst in the synthesis of isocoumarins through benzothiadiazine-fused.

InChI:InChI=1/Ag.6FH.Sb/h;6*1H;/q+1;;;;;;;+5/p-6/rAg.F6Sb/c;1-7(2,3,4,5)6/q+1;-1

Upstream product

• 7783-92-8 silver(I) chlorate 
• 17856-92-7 nitronium hexafluoroantimonate 
• 7732-18-5 water 
• 7664-39-3 hydrogen fluoride 
• 7783-70-2 antimony pentafluoride 
• 7787-71-5 bromine trifluoride 
• 7783-56-4 antimony(III) fluoride 
• 7782-41-4 fluorine 
• 13863-88-2 silver(I) azide 
• 51681-88-0 dioxygenyl hexafluoroantimonate 
• 11113-87-4 silver fluoride 
• 14104-20-2 silver tetrafluoroborate 
• 623171-37-9 [AgP(C₆H₅)3]⁽¹⁺⁾*SbF₆^(1-)=[AgP(C₆H₅)3](SbF₆) 
• 19379-47-6 BrF₂⁽¹⁺⁾*SbF₆^(1-)=(BrF₂)SbF₆ 

Downstream Products

• 127761-96-0 {cis,cis-1,3,5-tris((diphenylphosphino)methyl)cyclohexane}rhodium(III) hexafluoroantimonate 
• 128389-53-7 trans-bis{(1,4-dioxane-2-ylmethyl)diphenylphosphane-O',P'}palladium(II) bis{hexafluoroantimonate(V) 
• 89411-55-2 trans-bis[1,2-bis(diphenylphosphino)ethane]carbonylchloroosmium(II) hexafluoroantimonate 
• 560071-91-2 (diphenyl phosphite-κO)(5,10,15,20-tetraphenylporphyrinato-κ4N)manganese(III) hexafluoroantimonate(V) 
• 865532-94-1 [Rh(CO)(PPh₃)2(3-picoline)][SbF₆] 
• 59714-74-8 (C₆H₅)4C₄Si(CH₃)FFe(CO)3 
• 886034-55-5 [Ag(bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole)(SbF₆)]*unknown solvate 
• 886034-56-6 [Ag(bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole)(SbF₆)]*C₆H₆*THF 

Relevant articles and documents

The volume-based thermodynamics (VBT) and attempted preparation of an isomeric salt, nitryl chlorate: [NO2][ClO3]

Nitrosyl perchlorate, [NO][ClO4], is a known and stable salt. In this contribution we describe the attempt to synthesize the isomeric compound nitryl chlorate, [NO2][ClO3]. The results are discussed on the basis of volume-based thermodynamics (VBT).

Silver(I) Undecafluorodiantimonate(V)

The reaction between AgBF4 and excess of SbF5 in anhydrous hydrogen fluoride (aHF) yields the white solid AgSb2F 11 after the solvent and the excess of SbF5 have been pumped off. Reaction between equimolar amounts of AgSb2F 11 and AgBF4 yields AgSbF6. Meanwhile, oxidation of solvolyzed AgSb2F11 in aHF by elemental fluorine yields a clear blue solution of solvated Ag(II) cations and SbF 6- anions. AgSb2F11 is orthorhombic, at 250 K, Pbca, with a = 1091.80(7) pm, b = 1246.28(8) pm, c = 3880.2(3) pm, V = 5.2797(6) nm3, and Z = 24. The crystal structure of AgSb2F 11 is related to the already known crystal structure of H 3OSb2F11. Vibrational spectra of AgSb 2F11 entirely match the literature-reported vibrational spectra of β-Ag(SbF6)2, for which a formulation of a mixed-valence Ag(I)/Ag(III) compound was suggested (AgIAg III(SbF6)4). On the basis of obtained results it can be concluded that previously reported β-Ag(SbF6) 2 is in fact Ag(I) compound with composition AgSb2F 11.