13863-88-2Relevant articles and documents
A μ-1,1,1,3,3,3 azide anion inside a trigonal prism of silver centers
Guo, Guo-Cong,Mak, Thomas C. W.
, p. 3268 - 3270 (1998)
Layers of face- and edge-sharing trigonal Ag6 prisms, of which half are filled with azide units, are contained in the novel compound AgN3 · 2AgNO3 (see structure). Pendant η1-nitrate groups are attached to both sides of each layer.
Turrentine, J. W.,Moore, R. L.
, p. 382 (1912)
Synthesis and characterization of N,N′,C-bound organotellurium(IV) and organomercury(II) derivatives
Singh, Puspendra,Gupta, Anand K.,Sharma, Sagar,Singh, Harkesh B.,Butcher, Ray J.
, p. 218 - 228 (2018)
We report the synthesis and characterization of the first examples of organotellurium (IV)/organomercury(II) derivatives of N,N′,C-chelating aryldiamine ligand, 2-{Me2NCH2CH2N(Me)CH2}C6H4Br (20). The dichalcogenides, [2-{Me2NCH2CH2N(Me)CH2}C6H4Se]2 (24) and [2-{Me2NCH2CH2N(Me)CH2}C6H4Te]2 (25), were prepared by treatment of the corresponding Grignard reagent (21)/organolithium reagent (22) in THF with selenium or tellurium, respectively. Compounds [2-{Me2NCH2CH2N(Me)CH2}C6H4]2Se (26) and [2-{Me2NCH2CH2N(Me)CH2}C6H4]Te(S2CN(CH2CH3)2 (27) were synthesized by the reaction of 21/22 with Se(dtc)2 in 2:1 or Te(dtc)2 (dtc = diethyldithiacarbamate) in 1:1 ratio at room temperature. In contrast, the reaction of 21 with TeI2 afforded an unexpected protonated derivative, [2-{(Me2NH)CH2CH2N(Me)CH2}C6H4TeI]+(I)? (28a). Similarly, the halogenation reactions of 25 with chlorine gas or a solution of bromine in THF afforded protonated derivatives, [2-{(Me2NH)CH2CH2N(Me)CH2}C6H4TeCl3]+(Cl)? (29a) and [2-{(Me2NH)CH2CH2N(Me)CH2}C6H4TeBr3]+(Br) ? (30a), respectively. The organomercury precursors; 2-{Me2NCH2CH2N(Me)CH2}C6H4HgCl0.54/Br0.46 (31) and 2-{Me2NCH2CH2N(Me)CH2}C6H4HgBr (32), were obtained by the reaction of 21 with HgCl2 and HgBr2 in dry THF, respectively. The metathetical reaction of 31with silver azide afforded air- and moisture-stable organomercury azide, 2-{Me2NCH2CH2N(Me)CH2}C6H4HgN3 (33) in 87% yield. The transmetallation reaction of 31 with TeBr4 led to isolation of known o-formylphenyltellurenyl bromide. All the derivatives were characterized by various spectroscopic techniques such as 1H, 13C, 77Se, 125Te, 199Hg NMR spectroscopy, elemental analysis, ES-MS and HRMS studies.
Alexander, R.,Ko, E. C. F.,Mac, Y. C.,Parker, A. J.
, p. 3703 - 3712 (1967)
Hitch, A. R.
, p. 1195 - 1204 (1918)
Solid state structure of Bi(N3)3, Bi(N 3)3·solvates and the structural dynamics in the [Bi(N3)6]3- anion
Rosenstengel, Kati,Schulz, Axel,Villinger, Alexander
supporting information, p. 6110 - 6126 (2013/07/05)
The highly explosive bismuth triazide, Bi(N3)3, was obtained in pure form by the reaction of BiF3 with Me 3SiN3 in acetonitrile under solvothermal conditions at temperatures between 90 and 100 °C. X-ray, 14N NMR, infrared, and Raman spectra are discussed along with the data for the acetonitrile, acetone, and dmso adducts. The influence of the solvent on the purity of the azide products is studied in detail for Bi(N3)3 and the [Bi(N3)6]3- ion. Moreover, temperature dependent structural dynamics in the [Bi(N3)6] 3- ion, which is caused by small changes in the local environment around the [Bi(N3)6]3- ion in the solid state, was studied by temperature variable single crystal X-ray and Raman studies. The azido-chlorido ligand back exchange was studied in detail by NMR techniques in [Bi(N3)6]3- and Bi(N3)3 when chlorinated solvents such as CH2Cl2 were utilized leading to the formation of CH2(N3)Cl and/or HN 3 along with partially chlorinated bismuth azides.