Welcome to LookChem.com Sign In|Join Free

CAS

  • or

13863-88-2

Post Buying Request

13863-88-2 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

13863-88-2 Usage

Chemical Description

Silver azide is a reagent used in the synthesis of the organosulfonium azides.

Chemical Properties

orthorhombic, a=0.559 nm, b=0.591 nm, c=0.610nm; can be prepared by reacting silver nitrate solution with hydrazine or hydrazoic acid; sensitive to shock [KIR83] [CIC73]

Uses

It is used as a primary explosive, often as areplacement for lead azide. It may be usedin smaller quantities than lead azide as ainitiator.

Health Hazard

Silver azide is a highly toxic substance. Thetoxic effects have not been reported.

Fire Hazard

It is a primary explosive. It explodes violently upon thermal and mechanical shock. It requires lesser energy for initiation than lead azide and also fires with a shorter time delay. The heats of combustion and detonation are 1037 and 454 cal/g, respectively (i.e., 156 and 68 kcal/mol, respectively). The detonation velocity is 6.8 km/sec (at the crystal density 5.1 g/cm3). The pure compound explodes at 340°C (644°F) (Mellor 1967). The detonation can occur at much lower temperatures in an electric field when initiated by irradiation. Also, the presence of impurities can lower down the temperature of detonation. Such impurities include oxides, sulfides, and selenides of copper and other metals. It reacts with halogens forming halogen azides, often producing explosions. It reacts explosively with chlorine dioxide, most interhalogen compounds, and many dyes. It reacts with acids forming heat- and shock-sensitive hydrazoic acid. When mixed with salt solutions of heavy metals, their azides are formed, which are sensitive to heat, impact and electric charge.

Safety Profile

Explodes when heated above 270°C or on impact. Pure silver azide explodes at 340℃. An electric field or irradiation by electron pulses can explode the crystals. Shock-sensitive when dry and has detonated @ 250℃. Solutions in aqueous ammonia explode above 100°C. Reacts to form more explosive products with iodine (forms iodine azide); bromine and other halogens. The presence of metal oxides or metal sulfides increases the azide's sensitivity to explosion. lMixtures with sulfur dioxide are explosive. When heated to decomposition it emits toxic fumes of NOx. See also AZIDES and SILVER COMPOUNDS.

Check Digit Verification of cas no

The CAS Registry Mumber 13863-88-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,8,6 and 3 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 13863-88:
(7*1)+(6*3)+(5*8)+(4*6)+(3*3)+(2*8)+(1*8)=122
122 % 10 = 2
So 13863-88-2 is a valid CAS Registry Number.
InChI:InChI=1/Ag.N3/c;1-3-2/q+1;-1

13863-88-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name Silver(1+) azide

1.2 Other means of identification

Product number -
Other names acrylic acid,silver (I)-compound

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13863-88-2 SDS

13863-88-2Synthetic route

sodium azide

sodium azide

silver nitrate

silver nitrate

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In water addn. of aq. NaN3 to aq. AgNO3; pptn.; washing (water, alcohol, ether); drying over H2SO4 in vac.; elem. anal.;83%
In water>99
In water addition of a solution of NaN3 in H2O to a diluted solution of AgNO3 in H2O at 60-70°C under stirring;; washing with H2O, alcohol (95 %) and absolute ether, drying and storing over H2SO4;;
sodium azide

sodium azide

silver(I) acetate
563-63-3

silver(I) acetate

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In water
In water
In water addition of equivalent amounts of Ag acetate and NaN3 in H2O into a column and introduction of air from below; continuous reaction;;
In water
In water addition of equivalent amounts of Ag acetate and NaN3 in H2O into a column and introduction of air from below; continuous reaction;;
silver nitrate

silver nitrate

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In not given
In not given
sodium azide

sodium azide

tetrahydroxyargentate(III)

tetrahydroxyargentate(III)

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In water Kinetics; solns. in doubly distd. water of Ag(OH)4(1-) and alkaline NaN3 (moderate concns. of reactants) were mixed at 25°C, ionic strength 1.2 M (NaClO4);
silver (I) ion
14701-21-4

silver (I) ion

benzoyl azide
582-61-6

benzoyl azide

A

sodium benzoate
532-32-1

sodium benzoate

B

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
With sodium hydroxide byproducts: H2O; 60-70 °C; distn. with steam to soln. of Ag-salt;
With NaOH byproducts: H2O; 60-70 °C; distn. with steam to soln. of Ag-salt;
hippuroyl azide
57461-31-1

hippuroyl azide

silver (I) ion
14701-21-4

silver (I) ion

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
With sodium hydroxide byproducts: H2O; 60-70 °C; distn. with steam to soln. of Ag-salt;
With NaOH byproducts: H2O; 60-70 °C; distn. with steam to soln. of Ag-salt;
silver (I) ion
14701-21-4

silver (I) ion

diazoguanidinium nitrate

diazoguanidinium nitrate

A

silver(I) azide
13863-88-2

silver(I) azide

B

silver cyanamide

silver cyanamide

Conditions
ConditionsYield
In ammonia without NH3 excess; filtering;
In ammonia aq. ammonia=NH3; without NH3 excess; filtering;
silver (I) ion
14701-21-4

silver (I) ion

azide(1-)
14343-69-2

azide(1-)

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In water solution of Ag(1+) and N3(1-) in water;;
In water
hydrogen azide
916329-38-9

hydrogen azide

silver (I) ion
14701-21-4

silver (I) ion

silver(I) azide
13863-88-2

silver(I) azide

diazoguanidinium nitrate

diazoguanidinium nitrate

A

silver(I) azide
13863-88-2

silver(I) azide

B

hydrogen azide
916329-38-9

hydrogen azide

C

silver cyanamide

silver cyanamide

Conditions
ConditionsYield
With sodium hydroxide; sulfuric acid In ammonia with ammoniacal soln. of Ag-salt, without NH3 excess; pptn. obtd., filtrate traiting with NaOH contains HN3; distn. with H2SO4;A n/a
B >99
C n/a
With NaOH; H2SO4 In ammonia aq. ammonia=NH3; with ammoniacal soln. of Ag-salt, without NH3 excess; pptn. obtd., filtrate traiting with NaOH contains HN3; distn. with H2SO4;A n/a
B >99
C n/a
silver(I) nitrite
7783-99-5

silver(I) nitrite

hydrazinium sulfate
10034-93-2

hydrazinium sulfate

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In water formation from a cold saturated solution of AgNO2 in H2O;;
In water formation from a cold saturated solution of AgNO2 in H2O;;
silver(I) nitrite
7783-99-5

silver(I) nitrite

hydrazonium sulfate
10034-93-2

hydrazonium sulfate

silver(I) azide
13863-88-2

silver(I) azide

silver(I) nitrite
7783-99-5

silver(I) nitrite

hydrazine
302-01-2

hydrazine

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
With sulfuric acid In not given reaction of N2H4 (saturated solution) in presence of H2SO4;;
potassium azide
20762-60-1

potassium azide

silver nitrate

silver nitrate

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In water
In water precipitation from a solution of NaNO3 in H2O;;
In water precipitation from a solution of NaNO3 in H2O;;
In water mixed pseudohalides and aq. soln. of AgNO3;
hydrogen azide

hydrogen azide

silver nitrate

silver nitrate

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In not given reaction of a solution of AgNO3 (4%) and HNO3 (small excess) in coldness;; washing of the precipitate with cold H2O and drying in darkness on air at 110°C;;>99
In not given reaction of a solution of AgNO3 (4%) and HNO3 (small excess) in coldness;; washing of the precipitate with cold H2O and drying in darkness on air at 110°C;;>99
ammonia
7664-41-7

ammonia

silver nitrate

silver nitrate

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In water addition of a solution of AgNO3 in H2O to aq. NH3;;>99
In water addition of a solution of AgNO3 in H2O to aq. NH3;;>99
ammonium azide

ammonium azide

silver
7440-22-4

silver

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In ammonia NH3 (liquid); Electrolysis; electrolysis of a solution of NH4N3 in liquid NH3 at -67°C, Ag anode;;
Tollen's reagent
23606-32-8

Tollen's reagent

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In not given byproducts: NH4NO3, NH3; at higher concn. (>0.1n) explosion due to decompn. of AgN3;
azidoargentate (I) (1-)

azidoargentate (I) (1-)

silver (I) ion
14701-21-4

silver (I) ion

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In N,N-dimethyl-formamide precipitation from a solution in DMF;;
In water precipitation from a solution in water;;
In further solvent(s) precipitation from a solution in n-methyl-pyrrolidone-(2);;
carbamoyl azide
13125-56-9

carbamoyl azide

silver nitrate

silver nitrate

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
With ammonia In not given
With NH3 In not given
sulfonyl Azide
72250-07-8

sulfonyl Azide

silver(I) azide
13863-88-2

silver(I) azide

Conditions
ConditionsYield
In ethanol decompn. in alc. soln.;;
In ethanol decompn. in alc. soln.;;
silver(I) azide
13863-88-2

silver(I) azide

tris(tetraphenylphosphonium) hexaiodobismuthate

tris(tetraphenylphosphonium) hexaiodobismuthate

tris(tetraphenylphosphonium) hexaazidobismuthate

tris(tetraphenylphosphonium) hexaazidobismuthate

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1h; Inert atmosphere;100%
silver(I) azide
13863-88-2

silver(I) azide

silver nitrate

silver nitrate

3Ag(1+)*N3(1-)*2NO3(1-)=AgN3*2AgNO3

3Ag(1+)*N3(1-)*2NO3(1-)=AgN3*2AgNO3

Conditions
ConditionsYield
In water stirring; filtering, crystn. (dessicator, over P2O5);99%
silver(I) azide
13863-88-2

silver(I) azide

dimethylammonium tetrachloroaurate(III)
873203-89-5

dimethylammonium tetrachloroaurate(III)

dimethylammonium tetraazidoaurate(III)
873203-87-3

dimethylammonium tetraazidoaurate(III)

Conditions
ConditionsYield
In methanol addn. of silver salt to a soln. of gold complex in methanol, stirring for 24 h; slow evapn.;99%
silver(I) azide
13863-88-2

silver(I) azide

triphenylsulfonium bromide
3353-89-7

triphenylsulfonium bromide

A

triphenylsulfonium diazidoargentate(I)

triphenylsulfonium diazidoargentate(I)

B

triphenylsulfonium azide
1095937-01-1

triphenylsulfonium azide

Conditions
ConditionsYield
In dichloromethane byproducts: AgBr; (Ar); Schlenk techniques; AgN3 added to an CH2Cl2 soln. of Ph3SBr at 0°C; stirred for 30 min; stirred at ambient temp. for 2 h; filtered; concd. in vac.; recrystd. from CH2Cl2/hexane;A n/a
B 99%
silver(I) azide
13863-88-2

silver(I) azide

trimethylsulphonium iodide
2181-42-2

trimethylsulphonium iodide

trimethylsulfonium azide
7364-15-0

trimethylsulfonium azide

Conditions
ConditionsYield
In water byproducts: AgI; (Ar); Schlenk techniques; AgN3 added to an aq. soln. of Me3SI at 0°C; stirred for 30 min; stirred at ambient temp. for 2 h; filtered; crystd. by concn. in vac.;99%
silver(I) azide
13863-88-2

silver(I) azide

[2-((dimethylamino)methyl)phenyl]diiodobismuthane

[2-((dimethylamino)methyl)phenyl]diiodobismuthane

[2-((dimethylamino)methyl)phenyl]diazidobismuthane
1262035-55-1

[2-((dimethylamino)methyl)phenyl]diazidobismuthane

Conditions
ConditionsYield
In tetrahydrofuran byproducts: AgCl; (Ar); std. Schlenk technique; Ag salt was added to stirred soln. of Bi compd. in THF at ambient temp.; stirred for 12 h; filtered; evapd. (vac.); elem. anal.;98%
silver(I) azide
13863-88-2

silver(I) azide

phenylmercury(II) chloride
100-56-1

phenylmercury(II) chloride

phenylmercury(II) azide

phenylmercury(II) azide

Conditions
ConditionsYield
In acetone byproducts: AgCl; in darkness; into soln. of PhHgCl added AgN3 at ambient temp.; stirred for 24 h; ppt. filtered off, solvent removed in vacuo;96%
silver(I) azide
13863-88-2

silver(I) azide

sulfur
7704-34-9

sulfur

silver sulfide

silver sulfide

Conditions
ConditionsYield
In tetrahydrofuran byproducts: N2; High Pressure; AgN3 mixed with sulfur, loaded inro reactor with THF, heated to 150°C, held overnight, raised to 190°C and held overnight; filtration, washing (Et3N), drying under vac., XRD;95%
silver(I) azide
13863-88-2

silver(I) azide

iodine
7553-56-2

iodine

iodine azide

iodine azide

Conditions
ConditionsYield
In trichlorofluoromethane byproducts: AgI; rect. at 0°C for 1 h; decanting, drying at 0°C;95%
silver(I) azide
13863-88-2

silver(I) azide

methylmercury(II) iodide
143-36-2

methylmercury(II) iodide

methylmercury(II) azide

methylmercury(II) azide

Conditions
ConditionsYield
In acetone byproducts: AgI; in darkness; into soln. of CH3HgI added AgN3 at ambient temp.; stirred for 24 h; ppt. filtered off, solvent removed in vacuo;94%
silver(I) azide
13863-88-2

silver(I) azide

lithium N,N'-bis(2,6-di-isopropylphenyl)tert-butylamidinate

lithium N,N'-bis(2,6-di-isopropylphenyl)tert-butylamidinate

C29H43BiN8
1417338-48-7

C29H43BiN8

Conditions
ConditionsYield
In dichloromethane at 20℃; for 168h; Inert atmosphere; Schlenk technique;92%
silver(I) azide
13863-88-2

silver(I) azide

(2,3,4-trimethoxy)-6-((naphthalene-1-ylimino)phenyl)mercury(II) chloride

(2,3,4-trimethoxy)-6-((naphthalene-1-ylimino)phenyl)mercury(II) chloride

((2,3,4-trimethoxy)-6-((naphthalene-1-ylimino)methyl)phenyl)mercury azide

((2,3,4-trimethoxy)-6-((naphthalene-1-ylimino)methyl)phenyl)mercury azide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 4h; Inert atmosphere; Schlenk technique;92%
silver(I) azide
13863-88-2

silver(I) azide

C11H23BiI2N2

C11H23BiI2N2

C11H23BiN8

C11H23BiN8

Conditions
ConditionsYield
In dichloromethane at 20℃; for 168h; Inert atmosphere; Schlenk technique;91%
silver(I) azide
13863-88-2

silver(I) azide

((2,3,4-trimethoxy)-6-((p-tolylimino)methyl)phenyl)mercury(II) chloride

((2,3,4-trimethoxy)-6-((p-tolylimino)methyl)phenyl)mercury(II) chloride

((2,3,4-trimethoxy)-6-((p-tolylimino)methyl)phenyl)mercury azide

((2,3,4-trimethoxy)-6-((p-tolylimino)methyl)phenyl)mercury azide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 4h; Inert atmosphere; Schlenk technique;90%
silver(I) azide
13863-88-2

silver(I) azide

tetraphenyl phosphonium chloride
2001-45-8

tetraphenyl phosphonium chloride

manganese(ll) chloride

manganese(ll) chloride

[PPh4]2[Mn(N3)4]

[PPh4]2[Mn(N3)4]

Conditions
ConditionsYield
With Na2SO4 In dichloromethane byproducts: AgCl; dissolving MnCl2 in a suspn. of PPh4Cl in CH2Cl2; addn. of a suspn. of AgN3 and Na2SO4 in CH2Cl2; stirring for 12 h; filtration; concg.; addn. of CCl4; cooling for 12 h to 5°C; filtration; washing (CH2Cl2/CCl4); drying in vacuo; elem. anal.;89.3%
silver(I) azide
13863-88-2

silver(I) azide

2-thienylmercury chloride
5857-39-6

2-thienylmercury chloride

2-thiophenemercuric azide
80095-78-9

2-thiophenemercuric azide

Conditions
ConditionsYield
In dichloromethane; benzene byproducts: AgCl; room temp., 12 h; AgCl was filtered off, the solvent was evapd.; elem. anal.;89%
silver(I) azide
13863-88-2

silver(I) azide

C18H20ClHgNO3

C18H20ClHgNO3

6-((3,4-dimethylphenylimino)methyl)-2,3,4-(trimethoxyphenyl)mercury azide

6-((3,4-dimethylphenylimino)methyl)-2,3,4-(trimethoxyphenyl)mercury azide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 3h; Inert atmosphere; Schlenk technique;88%
silver(I) azide
13863-88-2

silver(I) azide

bis[2-((dimethylamino)methyl)phenyl]iodobismuthane
1027802-43-2

bis[2-((dimethylamino)methyl)phenyl]iodobismuthane

bis[2-((dimethylamino)methyl)phenyl]azidobismuthane
1262035-54-0

bis[2-((dimethylamino)methyl)phenyl]azidobismuthane

Conditions
ConditionsYield
In tetrahydrofuran byproducts: AgCl; (Ar); std. Schlenk technique; Ag salt was added to stirred soln. of Bi compd. in THF at ambient temp.; stirred for 15 h; filtered; concd. (vac.); slowly cooled to -25°C; decanted; dried (vac.); elem. anal.;87%
silver(I) azide
13863-88-2

silver(I) azide

0.54C12H19ClHgN2*0.46C12H19BrHgN2

0.54C12H19ClHgN2*0.46C12H19BrHgN2

C12H19HgN5

C12H19HgN5

Conditions
ConditionsYield
In methanol; chloroform at 20℃; for 12h;87%
silver(I) azide
13863-88-2

silver(I) azide

tetraphenyl phosphonium chloride
2001-45-8

tetraphenyl phosphonium chloride

copper dichloride

copper dichloride

2(P(C6H5)4)(1+)*Cu(N3)4(2-)=(P(C6H5)4)2{Cu(N3)4}

2(P(C6H5)4)(1+)*Cu(N3)4(2-)=(P(C6H5)4)2{Cu(N3)4}

Conditions
ConditionsYield
In dichloromethane addn. of PPh4Cl to CuCl2 soln., dropwise addn. to AgN3 suspn. (contg. a small amt. of dry Na2SO4), stirred for 12 h; filtered, added CCl4, cooled for several hours at 5°C, filtered, washed with CH2Cl2/CCl4, dried in vac.; elem. anal.;86.3%
silver(I) azide
13863-88-2

silver(I) azide

C17H18ClHgNO4

C17H18ClHgNO4

((2,3,4-trimethoxy)-6-((4-methoxyphenylimino)methyl)phenyl)mercury azide

((2,3,4-trimethoxy)-6-((4-methoxyphenylimino)methyl)phenyl)mercury azide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h; Inert atmosphere; Schlenk technique;86%
silver(I) azide
13863-88-2

silver(I) azide

A

hydrogen azide

hydrogen azide

B

silver
7440-22-4

silver

Conditions
ConditionsYield
In toluene byproducts: N2; High Pressure; AgN3 loaded into reactor with solvent, pressurized to 1 atm with N2, heated to 130°C and held overnight, then raised to 200°C and held for 1 d; filtration, washing, drying under vac.;A n/a
B 85%
With hydrogen
With H2
silver(I) azide
13863-88-2

silver(I) azide

silver
7440-22-4

silver

Conditions
ConditionsYield
In tetrahydrofuran byproducts: N2; High Pressure; AgN3 loaded into reactor with solvent, pressurized to 1 atm with N2, heated to 130°C and held overnight, then raised to 200°C and held for 1 d; filtration, washing, drying under vac.;85%
In further solvent(s) byproducts: N2; suspn. of AgN3 in trioctylamine stirred under N2 purge at 170°C for 1 d, cooled for anal., heated at 220°C for 1 d, raised to 250°C and held overnight; filtration, washing (Et3N), drying under vac.;85%
In melt byproducts: N2; other Radiation; electron-beam-induced decomposition of AgN3 on carbon;; ultra-fine Ag particles, electron microscopy;;
silver(I) azide
13863-88-2

silver(I) azide

cis-[RuNO(S2CN(CH3)2)2I]
72076-02-9

cis-[RuNO(S2CN(CH3)2)2I]

cis-[RuNO(S2CN(CH3)2)2N3]
72120-76-4

cis-[RuNO(S2CN(CH3)2)2N3]

Conditions
ConditionsYield
In methanol 5 min refluxing; cooling; filtering; ppt. (from filtrate) dissolved in CH2Cl2, passing through alumina column, eluting with CH2Cl2; pptn. by methanol addn. on standing; elem. anal.;85%
silver(I) azide
13863-88-2

silver(I) azide

[CeIV(Co(η5-C5H5){PO(OEt)2}3)2Cl2]

[CeIV(Co(η5-C5H5){PO(OEt)2}3)2Cl2]

[Ce(Co(η5-C5H5){P(O)(OEt)2}3)2(N3)2]

[Ce(Co(η5-C5H5){P(O)(OEt)2}3)2(N3)2]

Conditions
ConditionsYield
In acetonitrile at 20℃; for 0.0833333h; Inert atmosphere; Schlenk technique;85%
silver(I) azide
13863-88-2

silver(I) azide

2As(C6H5)4(1+)*(VCl3(N3S2))2(2-)=(As(C6H5)4)2[VCl3(N3S2)]2

2As(C6H5)4(1+)*(VCl3(N3S2))2(2-)=(As(C6H5)4)2[VCl3(N3S2)]2

2As(C6H5)4(1+)*(V(N3)3(N3S2))2(2-)*CH2Cl2=(As(C6H5)4)2[V(N3)3(N3S2)]2*CH2Cl2

2As(C6H5)4(1+)*(V(N3)3(N3S2))2(2-)*CH2Cl2=(As(C6H5)4)2[V(N3)3(N3S2)]2*CH2Cl2

Conditions
ConditionsYield
With sodium sulfate In dichloromethane byproducts: AgCl; under exclusion of moisture, addn. of complex to AgN3 suspn. in CH2Cl2,stirred for 20 h (presence of Na2SO4), resulted in a dark red soln.; filtered, dropwise addn. of CCl4 until beginning turbidity, allowed to stand for some hours at room temp., pptn., filtered, dried in vac. for short time; elem. anal.;80%
silver(I) azide
13863-88-2

silver(I) azide

[Ce(Co(η5-C5H5){P(O)(OEt)2}3)Cl3]

[Ce(Co(η5-C5H5){P(O)(OEt)2}3)Cl3]

oxygen
80937-33-3

oxygen

benzene
71-43-2

benzene

[Ce4(Co(η5-C5H5){P(O)(OEt)2}3)4(μ4-O)(μ2-O)2(μ2-N3)6]*hexane

[Ce4(Co(η5-C5H5){P(O)(OEt)2}3)4(μ4-O)(μ2-O)2(μ2-N3)6]*hexane

Conditions
ConditionsYield
In acetonitrile at 20℃; for 0.0833333h; Inert atmosphere; Schlenk technique;80%
silver(I) azide
13863-88-2

silver(I) azide

dimethylantimony bromide
53234-94-9

dimethylantimony bromide

dimethyl antimony azide
103678-15-5

dimethyl antimony azide

Conditions
ConditionsYield
In benzene byproducts: AgBr; exclusion of moisture and O2, excess of AgN3; mixed at 20°C; stirred for 1 wk in the dark; filtered off; solvent removed in vac.; sublimated (1E-3 Torr, 20°C - -78°C); elem. anal.;75%
silver(I) azide
13863-88-2

silver(I) azide

(4-(tert-butyl)-2,6-bis((dimethylamino)methyl)phenyl)mercury(II) bromide

(4-(tert-butyl)-2,6-bis((dimethylamino)methyl)phenyl)mercury(II) bromide

(4-(tert-butyl)-2,6-bis((dimethylamino)methyl)phenyl)mercury azide

(4-(tert-butyl)-2,6-bis((dimethylamino)methyl)phenyl)mercury azide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 5h; Inert atmosphere; Schlenk technique;75%

13863-88-2Relevant articles and documents

A μ-1,1,1,3,3,3 azide anion inside a trigonal prism of silver centers

Guo, Guo-Cong,Mak, Thomas C. W.

, p. 3268 - 3270 (1998)

Layers of face- and edge-sharing trigonal Ag6 prisms, of which half are filled with azide units, are contained in the novel compound AgN3 · 2AgNO3 (see structure). Pendant η1-nitrate groups are attached to both sides of each layer.

Turrentine, J. W.,Moore, R. L.

, p. 382 (1912)

Synthesis and characterization of N,N′,C-bound organotellurium(IV) and organomercury(II) derivatives

Singh, Puspendra,Gupta, Anand K.,Sharma, Sagar,Singh, Harkesh B.,Butcher, Ray J.

, p. 218 - 228 (2018)

We report the synthesis and characterization of the first examples of organotellurium (IV)/organomercury(II) derivatives of N,N′,C-chelating aryldiamine ligand, 2-{Me2NCH2CH2N(Me)CH2}C6H4Br (20). The dichalcogenides, [2-{Me2NCH2CH2N(Me)CH2}C6H4Se]2 (24) and [2-{Me2NCH2CH2N(Me)CH2}C6H4Te]2 (25), were prepared by treatment of the corresponding Grignard reagent (21)/organolithium reagent (22) in THF with selenium or tellurium, respectively. Compounds [2-{Me2NCH2CH2N(Me)CH2}C6H4]2Se (26) and [2-{Me2NCH2CH2N(Me)CH2}C6H4]Te(S2CN(CH2CH3)2 (27) were synthesized by the reaction of 21/22 with Se(dtc)2 in 2:1 or Te(dtc)2 (dtc = diethyldithiacarbamate) in 1:1 ratio at room temperature. In contrast, the reaction of 21 with TeI2 afforded an unexpected protonated derivative, [2-{(Me2NH)CH2CH2N(Me)CH2}C6H4TeI]+(I)? (28a). Similarly, the halogenation reactions of 25 with chlorine gas or a solution of bromine in THF afforded protonated derivatives, [2-{(Me2NH)CH2CH2N(Me)CH2}C6H4TeCl3]+(Cl)? (29a) and [2-{(Me2NH)CH2CH2N(Me)CH2}C6H4TeBr3]+(Br) ? (30a), respectively. The organomercury precursors; 2-{Me2NCH2CH2N(Me)CH2}C6H4HgCl0.54/Br0.46 (31) and 2-{Me2NCH2CH2N(Me)CH2}C6H4HgBr (32), were obtained by the reaction of 21 with HgCl2 and HgBr2 in dry THF, respectively. The metathetical reaction of 31with silver azide afforded air- and moisture-stable organomercury azide, 2-{Me2NCH2CH2N(Me)CH2}C6H4HgN3 (33) in 87% yield. The transmetallation reaction of 31 with TeBr4 led to isolation of known o-formylphenyltellurenyl bromide. All the derivatives were characterized by various spectroscopic techniques such as 1H, 13C, 77Se, 125Te, 199Hg NMR spectroscopy, elemental analysis, ES-MS and HRMS studies.

Alexander, R.,Ko, E. C. F.,Mac, Y. C.,Parker, A. J.

, p. 3703 - 3712 (1967)

Hitch, A. R.

, p. 1195 - 1204 (1918)

Solid state structure of Bi(N3)3, Bi(N 3)3·solvates and the structural dynamics in the [Bi(N3)6]3- anion

Rosenstengel, Kati,Schulz, Axel,Villinger, Alexander

supporting information, p. 6110 - 6126 (2013/07/05)

The highly explosive bismuth triazide, Bi(N3)3, was obtained in pure form by the reaction of BiF3 with Me 3SiN3 in acetonitrile under solvothermal conditions at temperatures between 90 and 100 °C. X-ray, 14N NMR, infrared, and Raman spectra are discussed along with the data for the acetonitrile, acetone, and dmso adducts. The influence of the solvent on the purity of the azide products is studied in detail for Bi(N3)3 and the [Bi(N3)6]3- ion. Moreover, temperature dependent structural dynamics in the [Bi(N3)6] 3- ion, which is caused by small changes in the local environment around the [Bi(N3)6]3- ion in the solid state, was studied by temperature variable single crystal X-ray and Raman studies. The azido-chlorido ligand back exchange was studied in detail by NMR techniques in [Bi(N3)6]3- and Bi(N3)3 when chlorinated solvents such as CH2Cl2 were utilized leading to the formation of CH2(N3)Cl and/or HN 3 along with partially chlorinated bismuth azides.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 13863-88-2