27904-70-7Relevant articles and documents
1,2-H shift in copper-chlorocarbenoid intermediate during CuCl/bpy-promoted stereoselective dechlorination of 2,2,2-trichloroethyl alkyl ethers to (Z)-1-alkoxy-2-chloroethenes
Ram, Ram N.,Manoj
supporting information; experimental part, p. 2243 - 2246 (2009/05/11)
(Chemical Equation Presented) Reaction of 2,2,2-trichloroethyl alkyl ethers with 2 molar equiv of CuCl/bpy in refluxing DCE yielded (Z)-1-alkoxy-2- chloroethenes stereoselectively as the major product via 1,2-H shift in copper-chlorocarbenoid intermediate. 2,2,2-Trichloroethyl carboxylates undergo a radical 1,2-acyloxy shift under similar conditions.
NOVEL SELECTIVE SYNTHESIS OF α-CHLOROMETHYL, α,α-DICHLOROMETHYL, AND α,α,α-TRICHLOROMETHYL KETONES FROM ALDEHYDE UTILIZING ELECTROREDUCTION AS KEY REACTIONS
Shono, Tatsuya,Kise, Naoki,Yamazaki, Akira,Ohmizu, Hiroshi
, p. 1609 - 1612 (2007/10/02)
A variety of α-chloromethyl, α,α-dichloromethyl, and α,α,α-trichloromethyl ketones were synthesized from aldehyde utilizing cathodic reduction as key reactions.
Photo-CIDNP Observed in O-Methylbenzoin-Carbon Tetrachloride System
Maruyama, Kazuhiro,Furuta, Hiroyuki,Otsuki, Tetsuo
, p. 2421 - 2422 (2007/10/02)
Photo-induced decomposition of O-methylbenzoin in carbon tetrachloride was investigated.A reaction scheme is proposed with the aid of photo-CIDNP technique and product analysis.