33561-46-5

Basic information

• Product Name: N-(2-Hydroxy-2-methylpropyl)benzamide
• Synonyms: 1-Benzoylamino-2-methyl-2-propanol;N-(2-Hydroxy-2-methylpropyl)benzamide
• CAS NO: 33561-46-5
• Molecular Formula: C₁₁H₁₅NO₂
• Molecular Weight: 0
• Mol File: 33561-46-5.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-(2-Hydroxy-2-methylpropyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-Hydroxy-2-methylpropyl)benzamide(33561-46-5)
• EPA Substance Registry System: N-(2-Hydroxy-2-methylpropyl)benzamide(33561-46-5)

Safety Data

• Hazardous Substances Data: 33561-46-5(Hazardous Substances Data)

Upstream product

• 21384-58-7 2,2-dimethylaziridin-1-yl-phenylmethanone 
• 769-68-6 2-phenylbutanenitrile 
• 86-29-3 Diphenylacetonitrile 
• 120-12-7 anthracene 
• 98-88-4 benzoyl chloride 
• 104-47-2 p-methoxybenzylnitrile 
• 92-83-1 xanthene 
• 2854-16-2 1-Amino-2-methyl-propan-2-ol 
• 65-85-0 benzoic acid 

Downstream Products

• 88413-34-7 N-(2-methylpropenyl)thiobenzamide 
• 37950-61-1 5,5-Dimethyl-2-phenyl-thiazoline 
• 33561-48-7 5,5-dimethyl-2-phenyl-4,5-dihydrooxazole 

Relevant articles and documents

Remote C(sp3)-H Oxygenation of Protonated Aliphatic Amines with Potassium Persulfate

This letter describes the development of a method for selective remote C(sp3)-H oxygenation of protonated aliphatic amines using aqueous potassium persulfate. Protonation serves to deactivate the proximal C(sp3)-H bonds of the amine substrates and also renders the amines soluble in the aqueous medium. These reactions proceed under relatively mild conditions (within 2 h at 80 °C with amine as limiting reagent) and do not require a transition metal catalyst. This method is applicable to a variety of types of C(sp3)-H bonds, including 3°, 2°, and benzylic C-H sites in primary, secondary, and tertiary amine substrates.

Isomerisation catalysee par le gel de silice et L'argile activee de N-Acyl-2,2-Dimethylaziridines: Approche mecanistique

Silica gel and activated clay, behaving as Lewis acids, reacted with N-acyl-2,2-dimethylaziridines 1 to lead to pentacoordinated aziridinium silicate ions. The regiospecific ring opening on the CMe2 carbon side of the intermediate I involves, after remova

Regiospecific ring opening of N-acylaziridines by neutral hydrolysis

The neutral hydrolysis of N-acyl-2,2-dimethylaziridines gave rise to the amidoalcohols in 76-91% overall yields. These products resulted from the specific cleavage of the C-2-N bond.